A Comparative Study of Five Reference Materials and the Lombard Meteorite for the Determination of the Platinum‐Group Elements and Gold by LA‐ICP‐MS

A range of independently characterised reference materials (RMs) for LA‐ICP‐MS, used for the determination of the platinum‐group elements (PGE) and Au in a sulfide matrix, were analysed and compared: 8b, PGE‐A, NiS‐3, Po727‐T1, Po724‐T and the Lombard meteorite. The newly developed RM NiS‐3 was used as the RM for the calibration of all LA‐ICP‐MS analyses and the measured concentrations of the other RMs compared against their published concentrations. This data were also used to assess the consistency of concentrations calibrated against the different RMs. It was found that Po727‐T1 and 8b produced results that were comparable, within uncertainty, for all elements. Po727‐T1 also produced consistent results with NiS‐3 for all elements. All other RMs showed differences for some elements, especially Ru in Po724‐T, and Os, Ir and Au in PGE‐A. The homogeneity of the PGE and Au in each RM was assessed, by comparing the precision of multiple LA‐ICP‐MS spot analyses with the average uncertainty of the signal. Po724‐T, Po727‐T1 and the Lombard meteorite were found to be homogeneous for all elements, but 8b, PGE‐A and NiS‐3 were heterogeneous for some elements. This is the first direct comparison between a range of independently characterised PGE and Au LA‐ICP‐MS RMs.     

Measurement of soluble reactive phosphorus concentration profiles and fluxes in river-bed sediments using DET gel probes

DET (diffusive equilibrium in thin films) gel probes were used for sampling river-bed sediment porewaters, to characterise in situ soluble reactive phosphorus (SRP) concentration profiles and fluxes. DET probes were deployed in three contrasting rural streams: (1) a headwater ‘pristine’ stream, with minimal P inputs from low intensity grassland and no point sources, (2) an intensively cultivated arable catchment, and (3) a stream subject to high P loadings from sewage effluent and intensive arable farming. The DET results showed highly enriched porewater SRP concentrations of between ca. 400 and 5000 μg-P l⁻¹ in the sewage-impacted stream. In contrast, the arable and pristine streams had porewater SRP concentrations <70 μg-P l⁻¹ and <20 μg-P l⁻¹, respectively. Porewater SRP concentration profiles in both the sewage-impacted and arable-impacted streams showed well-defined vertical structure, indicating internal sources and sinks of SRP within the sediment. However, there was little variability in porewater SRP concentrations in the pristine stream. The DET porewater profiles indicated net diffusion of SRP (a) from the overlying river water into the surface sediment and (b) from subsurface sediment upwards towards the sediment–water interface. A mass balance for the sewage-impacted site showed that the influx of SRP into the surface sediments from the overlying river water was small (ca. 1% of the daily river SRP load). The DET results indicated that, in the arable and sewage-impacted streams, the surface ‘cap’ of fine sediment may play an important role in inhibiting upward movement of SRP from subsurface porewaters into the overlying river water, under steady-state, low-flow conditions.     

Insights into syndepositional fault movement in a foreland basin; trends in seismites of the Upper Cretaceous,Wahweap Formation,Kaiparowits Basin,Utah, USA

The Upper Cretaceous Wahweap Formation accumulated in the active Cordilleran foreland basin of Utah. Soft‐sediment deformation structures are abundant in the capping sandstone member of the Wahweap Formation. By comparing with well‐established criteria, a seismogenic origin was determined for the majority of structures, which places these soft‐sediment deformation features in a class of sedimentary features referred to as seismites. A systematic study of the seismite trends included their vertical and horizontal distribution and a semi‐quantitative intensity analysis using a scale from 1 to 5 that is based on magnitude, sedimentary structure type, and the predominance of inferred process of hydroplastic deformation, liquefaction or fluidization. In addition, orientations of soft‐sediment fold axes were recorded. Construction of a northwest‐to‐southeast stratigraphic and seismite intensity cross‐section demonstrates: (1) reduction in stratigraphic thickness and percentage of conglomerates to the southeast, (2) the presence of lower seismite, middle nonseismite, and upper seismite zones within the capping sandstone (permitting subdivision of the capping sandstone member), and (3) elimination of the nonseismite zone and amalgamation of the lower and upper seismite zones to the southeast. Regional isoseismal contour maps generated from the semi‐quantitative analysis indicate a decrease in overall intensity from northwest to southeast in the upper and lower seismic zones and in sandstone within 5 m stratigraphically of the contact between the upper and capping sandstone members. In addition, cumulative seismite fold orientations support a west–northwest direction towards regional epicentres. Isoseismal maps are used to distinguish the effects of intrabasinal normal faulting from those of regional orogenic thrusting. Thus, this study demonstrates the utility of mapping seismites to separate the importance of regional vs. local tectonic activity influencing foreland basin sedimentation by identifying patterns that delineate palaeoepicentres associated with specific local intrabasinal normal faults vs. regional trends in soft‐sediment deformation related to Sevier belt earthquakes.     

Vulnerability and adaptation to climate-related fire impacts in rural and urban interior Alaska

This paper explores whether fundamental differences exist between urban and rural vulnerability to climate-induced changes in the fire regime of interior Alaska. We further examine how communities and fire managers have responded to these changes and what additional adaptations could be put in place. We engage a variety of social science methods, including demographic analysis, semi-structured interviews, surveys, workshops and observations of public meetings. This work is part of an interdisciplinary study of feedback and interactions between climate, vegetation, fire and human components of the Boreal forest social–ecological system of interior Alaska. We have learned that although urban and rural communities in interior Alaska face similar increased exposure to wildfire as a result of climate change, important differences exist in their sensitivity to these biophysical, climate-induced changes. In particular, reliance on wild foods, delayed suppression response, financial resources and institutional connections vary between urban and rural communities. These differences depend largely on social, economic and institutional factors, and are not necessarily related to biophysical climate impacts per se. Fire management and suppression action motivated by political, economic or other pressures can serve as unintentional or indirect adaptation to climate change. However, this indirect response alone may not sufficiently reduce vulnerability to a changing fire regime. More deliberate and strategic responses may be required, given the magnitude of the expected climate change and the likelihood of an intensification of the fire regime in interior Alaska.     

The price of spice: Ethnic minority livelihoods and cardamom commodity chains in upland northern Vietnam

The northern uplands of Vietnam are witness to rapidly developing commodity markets for a range of forest and agricultural products. Since the early 1990s the cultivation of black cardamom (Amomum aromaticum) has become a source of cash income for a growing number of ethnic minority households in these uplands. Drawing on ethnographic fieldwork, and utilizing a commodity chain and livelihoods approach, this article investigates the contemporary dynamics surrounding the cultivation, harvesting and trade of dried cardamom fruit from Hmong cultivators in Lao Cai province to consumers elsewhere in Vietnam and beyond to China and the global market. We analyse the spatial and social structures of these commodity chains, drawing attention to a range of mechanisms of access. We find that these mechanisms are reliant upon specific ethnic relations as well as different forms of capital that together sustain economic advantages for particular actors. While focusing on the ethnic minority cultivators active in these commodity chains, we also call for more nuanced understandings of how the trade in forest products fits within local agricultural systems and household livelihood decision making processes in the Vietnam uplands.     

Political economies of corruption beyond liberalism: An interpretative view of Zimbabwe

This paper models the political economy of corruption in the 'space beyond' the corruption discourse, using a case study of Zimbabwe. While a critical body of writers have examined the relationship between global neoliberal governance and the anti-corruption agenda within aid-recipient states, there is less critical work about the political economy of corruption in pariah and failing states. This paper asks how far political corruption can be identified and understood in spaces beyond the neoliberal paradigm, when instead of existing as a normative aberration, it is a central moment of instrumental state power.     

Next stop: the Moon

Andrew J Ball, Sarah K Dunkin and David J Heather report on optimistic and innovative ideas raised at the Fourth International Conference on Exploration and Utilisation of the Moon, which resulted in a declaration reviewing the current state of lunar exploration and setting targets for future work.     

Potential mechanistic causes of increased baseflow across northern Eurasia catchments underlain by permafrost

Warming in the Arctic is occurring at twice the rate of the global average, resulting in permafrost thaw and a restructuring of the Arctic hydrologic cycle as indicated by increased stream discharge during low-flow periods. In these cold regions, permafrost thaw is postulated to increase low-flow discharge, or baseflow, through either: (a) localized increases in groundwater storage and discharge to streams due to increased aquifer transmissivity from thickening of the freeze–thaw layer above permafrost known as the active layer or (b) long-term increases in regional groundwater circulation via enhancement of groundwater–surface water interactions due to extensive permafrost loss over decades. While increasing baseflow has been observed throughout northern Eurasia, the precise mechanistic causes remain elusive. In this study, we differentiate between where these two subsurface physical mechanisms of baseflow increase are occurring by performing a baseflow recession analysis using daily streamflow records from 1913 to 2003 for 139 stations in northern Eurasia underlain by varying permafrost areal extents. Results indicate that from 1913 to 2003, the majority of catchments underlain by continuous permafrost have an increasing trend in their recession flow intercepts, a proxy for increasing active layer thickness. Alternatively, the majority of catchments underlain by permafrost types that are less spatially extensive (e.g., discontinuous, sporadic, isolated, or no permafrost) have decreasing trends in their recession flow intercepts, indicating that a potential increase in active layer thickness is not the driving factor of baseflow variations in these catchments. This may indicate that in catchments underlain by continuous permafrost, active layer thickening correlates with increases in baseflow, whereas, in other catchments with less extensive permafrost, increases in baseflow may be caused by wholesale permafrost loss and vertical talik expansion that enhances regional groundwater circulation. The results of this work may inform our understanding of the subsurface mechanisms responsible for the changing Arctic hydrologic cycle.     

Catchment chemostasis revisited: Water quality responds differently to variations in weather and climate

Solute concentrations in streamflow typically vary systematically with stream discharge, and the resulting concentration–discharge relationships are important signatures of catchment biogeochemical processes. Solutes derived from mineral weathering often exhibit decreasing concentrations with increasing flows, suggesting dilution of a kinetically limited weathering flux by a variable flux of water. However, previous work showed that concentration–discharge relationships of weathering‐derived solutes in 59 headwater catchments were much weaker than this simple dilution model would predict. Instead, catchments behaved as chemostats, with rates of solute production and/or mobilization that were nearly proportional to water fluxes, on both event and interannual timescales. Here, we re‐examine these findings using data for a wider range of solutes from 2,186 catchments, ranging from ~10 to >1,000,000 km² in drainage area and spanning a wide range of lithologic and climatic settings. Concentration–discharge relationships among this much larger set of larger catchments are broadly consistent with the previously described chemostatic behaviour, at least on event and interannual timescales for weathering‐derived solutes. Among these same catchments, however, site‐to‐site variations in mean concentrations of weathering‐derived solutes exhibit strong negative correlations with long‐term average precipitation and discharge, reflecting strong climatic control on long‐term leaching of the critical zone. We use multiple regression of site characteristics including discharge to identify potential controls on long‐term mean concentrations and find that lithologic and land cover controls are significant predictors for many analytes. The picture that emerges is one in which, on event and interannual timescales, weathering‐derived stream solute concentrations are chemostatically buffered by groundwater storage and fast chemical reactions, but each catchment's chemostatic “set point” reflects site‐to‐site differences in climatically driven evolution of the critical zone. In contrast to these weathering products, some nutrients and particulates are often near‐chemostatic across all timescales, and their long‐term mean concentrations correlate more strongly with land use than climatic characteristics.     

Ice processes on medium‐sized north‐temperate lakes

Lake ice supports a range of socio‐economic and cultural activities including transportation and winter recreational actives. The influence of weather patterns on ice‐cover dynamics of temperate lakes requires further understanding for determining how changes in ice composition will impact ice safety and the range of ecosystem services provided by seasonal ice cover. An investigation of lake ice formation and decay for three lakes in Central Ontario, Canada, took place over the course of two winters, 2015–2016 and 2016–2017, through the use of outdoor digital cameras, a Shallow Water Ice Profiler (upward‐looking sonar), and weekly field measurements. Temperature fluctuations across 0°C promoted substantial early season white ice growth, with lesser amounts of black ice forming later in the season. Ice thickening processes observed were mainly through meltwater, or midwinter rain, refreezing on the ice surface. Snow redistribution was limited, with frequent melt events limiting the duration of fresh snow on the ice, leading to a fairly uniform distribution of white ice across the lakes in 2015–2016 (standard deviations week to week ranging from 3 to 5 cm), but with slightly more variability in 2016–2017 when more snow accumulated over the season (5 to 11 cm). White ice dominated the end‐of‐season ice composition for both seasons representing more than 70% of the total ice thickness, which is a stark contrast to Arctic lake ice that is composed mainly of black ice. This research has provided the first detailed lake ice processes and conditions from medium‐sized north‐temperate lakes and provided important information on temperate region lake ice characteristics that will enhance the understanding of the response of temperate lake ice to climate and provide insight on potential changes to more northern ice regimes under continued climate warming.