BVOC emissions from mechanical wounding of leaves and branches of <Emphasis Type="Italic">Eucalyptus sideroxylon</Emphasis> (red ironbark)

Emissions of biogenic volatile organic compounds (BVOCs) from mechanical wounding of leaves and branches of plants can contribute to the atmospheric burden of volatile organic compounds (VOCs) in both (a) urban airsheds (from urban garden maintenance) and (b) the global atmosphere (from large scale forest harvesting). These emissions of BVOCs are poorly understood and quantified, and their role in urban and global emissions inventories neglected. This paper presents measurements of the magnitude, duration and composition of emissions of BVOCs, carbon dioxide (CO₂) and methane (CH₄) from freshly cut leaf mulch and wood chips derived from a common eucalypt tree, Eucalyptus sideroxylon (red ironbark), found in southeastern Australian forests and gardens. The emissions of BVOCs from freshly cut and shredded leaves and wood of E. sideroxylon were found to be 2.3 ± 0.6 and 0.05 ± 0.04 mg g^-1 DM (Dry Mass) from leaf mulch and wood chips respectively and to last typically for 1 day following cutting. Three sampling techniques were used for VOC speciation and the 12 most abundant BVOCs released from the mulch materials were identified. The specific BVOCs emitted in order of decreasing abundance from leaf mulch are: (a) stored plant oils, 1,8-cineole, α–pinene and o-cymene which make up the major part of the emissions, (b) a minor contribution from chemicals associated with environmental stress and wound defence, (Z)–3–hexenyl acetate, (E)-2-hexenal and (Z)-3-hexen-1-ol, and (c) a second minor contribution from metabolic products, acetaldehyde and acetone. The observed integrated emissions of BVOCs from leaves following mulching are equivalent to more than half and perhaps all of the likely stored plant oils in the leaves. For the two comparable studies available, one of a plant with stored oils (this study) and one of a plant without stored plant oils, the emissions of leaf wound defence BVOCs are in the same range for both plants. In the plant with stored plant oils, the plant oil emissions are about a factor of 11 larger in emission rate than the plant wound defence BVOCs. A compilation of available leaf wounding BVOC emission studies indicates that for plants with stored plant oils, plant oil emissions dominate, whereas with other plants, leaf wound defence BVOCs dominate the emissions.     

A scoping review on the multiplicity of scale in spatial analysis

Journal of Geographical Systems - Scale is a central concept in the geographical sciences and is an intrinsic property of many spatial systems. It also serves as an essential thread in the fabric...     

Surveillance for previously unmonitored organic contaminants in the San Francisco Estuary

The San Francisco Estuary Regional Monitoring Program initiated surveillance monitoring to identify previously unmonitored synthetic organic contaminants in the San Francisco Estuary. Organic extracts of water samples were analyzed using gas chromatography-mass spectrometry in full scan mode. The major contaminant classes identified in the samples were fire retardants, pesticides, personal care product ingredients, and plasticizers. Evidence from the literature suggests that some of these contaminants can persist in the environment, induce toxicity, and accumulate in marine biota and in higher food chain consumers. The major sources of these contaminants into the marine environment are the discharge of municipal and industrial wastewater effluents, urban stormwater, and agricultural runoff. As a proactive effort, it is suggested that surveillance studies be used routinely in monitoring programs to identify and prevent potential problem contaminants from harming the marine environment.     

Root properties of vegetation communities and their impact on the erosion resistance of river dikes

Predicted climate change and the associated sea level rise poses an increased threat of flooding due to wave overtopping events at sea and river dikes. To safeguard the land from flooding it is important to keep the soil erosion resistance at the dikes high. As plant roots can be very effective in reducing soil erosion rates by concentrated flow, the main goal of this study is to explore the variability in root system characteristics of five dike vegetation communities along the Scheldt River (Belgium) and to assess their effectiveness in controlling soil erosion rates during concentrated flow. This study is the first one to investigate systematically the erosion‐reducing potential of the root properties of representative dike vegetation communities in a temperate humid climate. Results show that the presence of Urtica dioica resulted in large differences in root length density (RLD) among dike vegetation communities. Observed RLD values in the topsoil ranged from 129 to 235 km m^‐3 for dike vegetation communities without U. dioica, while smaller values ranging from 22 to 58 km m^?3 were found for vegetation communities with U. dioica. The erosion‐reducing effect of the dike vegetation communities was estimated based on a global Hill curve model, linking the RLD to the soil detachment ratio (SDR; i.e. the ratio of the soil detachment rate for root‐permeated topsoils to the soil detachment rate for root‐free topsoils). Concentrated flow erosion rates are likely to be reduced to 13–16% of the erosion rates for root‐free topsoils if U. dioica is absent compared to 22–30% for vegetation communities with U. dioica. Hence, to maintain a high resistance of the soil against concentrated flow erosion it is important to avoid the overgrowth of grassland by U. dioica through an effective vegetation management. Copyright © 2016 John Wiley & Sons, Ltd.     

Application of a New Vertical Profiling Tool (ESASS) for Sampling Groundwater Quality During Hollow‐Stem Auger Drilling

A new tool called ESASS (Enhanced Screen Auger Sampling System) was developed by the U.S. Geological Survey. The use of ESASS, because of its unique U.S. patent design (U.S. patent no. 7,631,705 B1), allows for the collection of representative, depth‐specific groundwater samples (vertical profiling) in a quick and efficient manner using a 0.305‐m long screen auger during hollow‐stem auger drilling. With ESASS, the water column in the flights above the screen auger is separated from the water in the screen auger by a specially designed removable plug and collar. The tool fits inside an auger of standard inner diameter (82.55 mm). The novel design of the system constituted by the plug, collar, and A‐rod allows the plug to be retrieved using conventional drilling A‐rods. After retrieval, standard‐diameter (50.8 mm) observation wells can be installed within the hollow‐stem augers. Testing of ESASS was conducted at one waste‐disposal site with tetrachloroethylene (PCE) contamination and at two reference sites with no known waste‐disposal history. All three sites have similar geology and are underlain by glacial, stratified‐drift deposits. For the applications tested, ESASS proved to be a useful tool in vertical profiling of groundwater quality. At the waste site, PCE concentrations measured with ESASS profiling at several depths were comparable (relative percent difference <25%) to PCE concentrations sampled from wells. Vertical profiling with ESASS at the reference sites illustrated the vertical resolution achievable in the profile system; shallow groundwater quality varied by a factor of five in concentration of some constituents (nitrate and nitrite) over short (0.61 m) distances.     

Numerical Modeling of the Near‐Field Hydraulics of Water Wells

Numerical flow models can be a useful tool for dimensioning water wells and to investigate the hydraulics in their near‐field. Fully laminar flow can be assumed for all models calculated up to the screen. Therefore models can be used to predict—at least qualitatively, neglecting turbulent losses inside the well—the spatial distribution of inflow into the well and the overall hydraulic performance of different combinations of aquifer parameters and technical installations. Models for both horizontal (plan view) and vertical flow (cross section) to wells were calculated for a variety of setups. For the latter, this included variations of hydraulic conductivity of the screen, pump position, and aquifer heterogeneity. Models of suction flow control devices showed that they indeed can homogenize inflow, albeit at the cost of elevated entrance losses.     

Isotopic mapping of groundwater perchlorate plumes

Analyses of stable isotope ratios of chlorine and oxygen in perchlorate can, in some cases, be used for mapping and source identification of groundwater perchlorate plumes. This is demonstrated here for large, intersecting perchlorate plumes in groundwater from a region having extensive groundwater perchlorate contamination and a large population dependent on groundwater resources. The region contains both synthetic perchlorate derived from rocket fuel manufacturing and testing activities and agricultural perchlorate derived predominantly from imported Chilean (Atacama) nitrate fertilizer, along with a likely component of indigenous natural background perchlorate from local wet and dry atmospheric deposition. Most samples within each plume reflect either a predominantly synthetic or a predominantly agricultural perchlorate source and there is apparently a minor contribution from the indigenous natural background perchlorate. The existence of isotopically distinct perchlorate plumes in this area is consistent with other lines of evidence, including groundwater levels and flow paths as well as the historical land use and areal distribution of potential perchlorate sources.     

Generalisation of a Nonlinear Dynamo Model

In order to gain a better understanding of the physical processes underlying fast dynamo action it is instructive to investigate the structure of both the magnetic field and the velocity field after the dynamo saturates. Previously, computational results have been presented (Cattaneo, Hughes and Kim, 1996) that indicate, in particular, that Lagrangian chaos is suppressed in the dynamical regime of the dynamo. Here we extend their model by removing the assumption of neglecting the inertial term. This allows for an investigation into the effect of this term on the evolution of the dynamo via a comparison of the two models. Our results indicate that this term plays a crucial role in the physics of the dynamo.     

Assessment of flow–ecology relationships for environmental flow standards: a synthesis focused on the southeast USA

ABSTRACT

Environmental flow standards are a management tool that can help to protect the ecosystem services sustained by rivers. Although environmental flow requirements can be assessed using a variety of methods, most of these methods require establishing relationships between flow and habitat of species of concern. Here, we conducted a synthesis of past flow–ecology studies in the southeast USA. For each state or interstate river basin, we used the published data to determine the flow metrics that resulted in the greatest changes in ecological metrics, and the ecological metrics that were most sensitive to hydrologic alteration. The flow metrics that were most important in preserving ecological metrics were high-flow duration and frequency, 3-day maximum and minimum, and number of reversals. The ecological metrics most sensitive to hydrologic alteration were mostly related to presence or absence of key indicator species.     

Compartmentalisation and groundwater–surface water interactions in a prospective shale gas basin: Assessment using variance analysis and multivariate statistics on water quality data

An environmental concern with hydraulic fracturing for shale gas is the risk of groundwater and surface water contamination. Assessing this risk partly involves the identification and understanding of groundwater–surface water interactions because potentially contaminating fluids could move from one water body to the other along hydraulic pathways. In this study, we use water quality data from a prospective shale gas basin to determine: if surface water sampling could identify groundwater compartmentalisation by low-permeability faults; and if surface waters interact with groundwater in underlying bedrock formations, thereby indicating hydraulic pathways. Variance analysis showed that bedrock geology was a significant factor influencing surface water quality, indicating regional-scale groundwater–surface water interactions despite the presence of an overlying region-wide layer of superficial deposits averaging 30–40 m thickness. We propose that surface waters interact with a weathered bedrock layer through the complex distribution of glaciofluvial sands and gravels. Principal component analysis showed that surface water compositions were constrained within groundwater end-member compositions. Surface water quality data showed no relationship with groundwater compartmentalisation known to be caused by a major basin fault. Therefore, there was no chemical evidence to suggest that deeper groundwater in this particular area of the prospective basin was reaching the surface in response to compartmentalisation. Consequently, in this case compartmentalisation does not appear to increase the risk of fracking-related contaminants reaching surface waters, although this may differ under different hydrogeological scenarios.