Late Palaeozoic hydrocarbon migration through the Clair field, West of Shetland, UK Atlantic margin

Geochemical analysis of bitumen- and hydrocarbon-bearing fluid inclusions from the Devonian-Carboniferous Clair field indicates that the reservoirs contain a mixture of oils from different marine and lacustrine sources. Reconstruction of the Clair field oil-charge history using fluid inclusion petrography show that oil-charging occurred at times of K-feldspar, quartz and calcite cementation. Temperature–composition–time data yielded from the integration of fluid inclusion microthermometry with high-resolution Ar–Ar dating, date hydrocarbon-bearing K-feldspar overgrowths at 247 ± 3.3 Ma. These data show that in order for oil to be trapped within primary fluid inclusions in K-feldspar overgrowths, hydrocarbon migration throughout the UK Atlantic margin must have been taking place during the Late Palaeozoic and as such, current industry oil-play models based solely on oil charging from Jurassic-Cretaceous marine sources are clearly incomplete and need revision. Apatite fission track analysis and vitrinite reflectance data were used to reconstruct thermal burial histories and assess potential oil generation from Middle Devonian lacustrine source rocks. Thermal history data from wells along The Rona Ridge adjacent to the Clair field show that the Palaeozoic section was heated to greater than 100 °C at some time between 270 and 230 Ma, confirming that Devonian source rocks were mature and expelling oil during the Late Palaeozoic at the time that authigenic K-feldspar overgrowths were growing in the Clair field.     

Isotopic mapping of groundwater perchlorate plumes

Analyses of stable isotope ratios of chlorine and oxygen in perchlorate can, in some cases, be used for mapping and source identification of groundwater perchlorate plumes. This is demonstrated here for large, intersecting perchlorate plumes in groundwater from a region having extensive groundwater perchlorate contamination and a large population dependent on groundwater resources. The region contains both synthetic perchlorate derived from rocket fuel manufacturing and testing activities and agricultural perchlorate derived predominantly from imported Chilean (Atacama) nitrate fertilizer, along with a likely component of indigenous natural background perchlorate from local wet and dry atmospheric deposition. Most samples within each plume reflect either a predominantly synthetic or a predominantly agricultural perchlorate source and there is apparently a minor contribution from the indigenous natural background perchlorate. The existence of isotopically distinct perchlorate plumes in this area is consistent with other lines of evidence, including groundwater levels and flow paths as well as the historical land use and areal distribution of potential perchlorate sources.     

Determining effective wellbore permeability from a field pressure test: a numerical analysis of detection limits

We propose a simple pressure test that can be used in the field to determine the effective permeability of existing wellbores. Such tests are motivated by the need to understand and quantify leakage risks associated with geological storage of CO₂ in mature sedimentary basins. If CO₂ is injected into a deep geological formation, and the resulting CO₂ plume encounters a wellbore, leakage may occur through various pathways in the “disturbed zone” surrounding the well casing. The effective permeability of this composite zone, on the outside of the well casing, is an important parameter for models of leakage. However, the data that exist on this key parameter do not exist in the open literature, and therefore specific field tests need to be done in order to reduce the uncertainty inherent in the leakage estimates. The test designed and analyzed herein is designed to measure effective wellbore permeability within a low-permeability caprock, bounded above and below by permeable reservoirs, by pressurizing the reservoir below and measuring the response in the reservoir above. Alternatively, a modified test can be performed within the caprock without directly contacting the reservoirs above and below. We use numerical simulation to relate pressure response to effective well permeability and then evaluate the range of detection of the effective permeability based on instrument measurement error and limits on fracture pressure. These results can guide field experiments associated with site characterization and leakage analysis.     

Nontidal circulation and mixing processes in the lower Potomac estuary

An analysis of the vertical structure of nontidal longitudinal currents and salinity in a reach of the lower Potomac River Estuary suggests that values for vertical eddy viscosity and eddy diffusivity scale with water depth H, tidal current amplitude U and bulk Richardson number according to conventional empirical formulas. However, the constant which relates the vertical eddy coefficients under conditions of neutral stability to UH is found to be an order of magnitude less than that expected for tidal conditions. Analyses also suggest that the degree of enhancement of longitudinal dispersion by the shear effect associated with the nontidal currents is a strong function of bulk Richardson number.     

Holocene paleoecology of a wild rice (Zizania sp.) lake in Northwestern Ontario, Canada

Whitefish Lake is a large (11-km-long), shallow, basin in Northwestern Ontario, Canada. The presence of extensive stands of wild rice (Zizania sp.) in combination with high archaeological site density suggests that this lake was ecologically important to regional precontact populations. Collection and analysis of sediment from Whitefish Lake was initiated in 2008 in order to reconstruct changes in lake depth, climate, and vegetation throughout the Holocene. In general, the upper 4.5 m of basinal sediment is composed of ~1.5+ m of varves, which is overlain by a 1.5-m-thick unit with ped-like structures, and ~1.5 m of lacustrine sediment. This sequence documents an early proglacial lake phase, followed by a dry interval before 4,300 (4,900 cal) BP when the lake was significantly shallower, and the establishment of the modern lake during the late Holocene. Plant microfossil (phytolith) evidence indicates that wild rice had colonized the basin ~5,300 (6,100 cal) BP as the lake level rose in response to climate change. Beginning ~4,000 (4,500 cal) BP, changes in elemental data suggest a sharp increase in lake productivity and a switch to anaerobic depositional conditions as the rate of organic sedimentation increased. Recent archaeological research confirms that wild rice was locally processed and consumed during the Middle and Late Woodland periods (~300 BC–AD 1700) although it was evidently growing in the lake well before this time.     

Development of large‐scale seismites in Upper Cretaceous fluvial sandstones in a fault‐proximal setting

Large‐scale soft‐sediment deformation structures occur within fluvial sandstone bodies of the Upper Cretaceous Wahweap Formation in the Kaiparowits basin, southern Utah, USA. These structures represent an exceptional example of metre‐scale fault‐proximal, seismogenic load structures in nearly homogenous sandstones. The load structures consist of two types: large‐scale load casts and wedge‐shaped load structures. Large‐scale load casts penetrate up to 4·5 m into the underlying sandstone bed. Wedge‐shaped load structures include metre‐scale, parallel, sub‐vertical features and decimetre‐scale features along the periphery of the large‐scale load casts or other wedge‐shaped load structures. Wedge‐shaped load structures contain well‐developed, medial cataclastic shear deformation bands. All load structures contain pervasive well‐defined millimetre‐thick to centimetre‐thick internal laminae, oriented parallel to the outside form of the load structures and asymptotic to deformation bands. Both types of load structures formed because of an inverted density profile, earthquake‐triggered liquefaction and growth of irregularities (a Rayleigh–Taylor instability) on the sandstone–sandstone erosional contact. The internal laminae and deformation bands formed during deformation and clearly demonstrate polyphase deformation, recording a transition from liquefied to hydroplastic to brittle modes of deformation. Decimetre‐scale wedge‐shaped load structures on the edge of the large‐scale load casts probably formed towards the end of a seismic event after the sediment dewatered and increased the frictional contact of grains enough to impart strength to the sands. Metre‐scale wedge‐shaped load structures were created as the tips of downward foundering sediments were driven into fractures, which widened incrementally with seismic pulsation. With each widening of the fracture, gravity and a suction effect would draw additional sediment into the fracture. Superimposed laminae indicate a secondary syndeformational origin for internal laminae, probably by flow‐generated shearing and vibrofluidization mechanisms. Large‐scale and wedge‐shaped load structures, polyphase deformation and secondary laminae may characterize soft‐sediment deformation in certain fault‐proximal settings.     

Phase Equilibria Constraints on the Chemical and Physical Evolution of the Campanian Ignimbrite

The Campanian Ignimbrite is a > 200 km³ trachyte–phonolitepyroclastic deposit that erupted at 39·3 ± 0·1ka within the Campi Flegrei west of Naples, Italy. Here we testthe hypothesis that Campanian Ignimbrite magma was derived byisobaric crystal fractionation of a parental basaltic trachyandesiticmelt that reacted and came into local equilibrium with smallamounts (5–10 wt%) of crustal rock (skarns and foid-syenites)during crystallization. Comparison of observed crystal and magmacompositions with results of phase equilibria assimilation–fractionationsimulations (MELTS) is generally very good. Oxygen fugacitywas approximately buffered along QFM + 1 (where QFM is the quartz–fayalite–magnetitebuffer) during isobaric fractionation at 0·15 GPa ( 6km depth). The parental melt, reconstructed from melt inclusionand host clinopyroxene compositions, is found to be basaltictrachyandesite liquid (51·1 wt% SiO₂, 9·3 wt%MgO, 3 wt% H₂O). A significant feature of phase equilibria simulationsis the existence of a pseudo-invariant temperature, 883 °C,at which the fraction of melt remaining in the system decreasesabruptly from 0·5 to < 0·1. Crystallizationat the pseudo-invariant point leads to abrupt changes in thecomposition, properties (density, dissolved water content),and physical state (viscosity, volume fraction fluid) of meltand magma. A dramatic decrease in melt viscosity (from 1700Pa s to 200 Pa s), coupled with a change in the volume fractionof water in magma (from 0·1 to 0·8) and a dramaticdecrease in melt and magma density acted as a destabilizingeruption trigger. Thermal models suggest a timescale of 200kyr from the beginning of fractionation until eruption, leadingto an apparent rate of evolved magma generation of about 10^–3km³/year. In situ crystallization and crystal settling in density-stratifiedregions, as well as in convectively mixed, less evolved subjacentmagma, operate rapidly enough to match this apparent volumetricrate of evolved magma production. KEY WORDS: assimilation; Campanian Ignimbrite; fractional crystallization; magma dynamics; phase equilibria     

Emerging trends in urbanizing Palestine: neglected city-builders beyond the occupation

In this article, we draw attention to trends in land transformation in the West Bank since the Second Intifada, after which a surge of investment from Gulf countries entered Palestine, almost exclusively in the West Bank. The occupied Palestinian territories have attracted a great deal of attention from media and academics, yet the vast majority of scholarship focuses on the conflict and the variety of social, economic, and political repercussions of the on-going Israeli occupation. While the occupation has undeniably serious impacts on every aspect of life for Palestinians, the near-exclusive focus on the conflict means that significant new trends, such as urban mega-developments and emerging market-based urbanisation processes, have been largely overlooked. We outline three directions for future research: the assemblage of “neglected city-builders” shaping current urbanization processes in Palestine; the ideas, policies, and norms circulating in the West Bank; and the social, spatial, economic, and other impacts of these new urban developments.     

The impact of over 100 years of wildfires on mercury levels and accumulation rates in two lakes in southern California,USA

In southern California, USA, wildfires may be an important source of mercury (Hg) to local watersheds. Hg levels and Hg accumulation rates were investigated in dated sediment cores from two southern California lakes, Big Bear Lake and Crystal Lake, located approximately 40-km apart. Between 1895 and 2006, fires were routinely minimized or suppressed around Big Bear Lake, while fires regularly subsumed the forest surrounding Crystal Lake. Mean Hg concentrations and mean Hg accumulation rates were significantly higher in Crystal Lake sediments compared to Big Bear Lake sediments (Hg levels: Crystal Lake 220 ± 93 ng g⁻¹, Big Bear Lake 92 ± 26 ng g⁻¹; Hg accumulation: Crystal Lake 790 ± 1,200 μg m⁻² year⁻¹, Big Bear 240 ± 54 μg m⁻² year⁻¹). In Crystal Lake, the ratio between post-1965 and pre-1865 Hg concentrations was 1.1, and several spikes in Hg levels occurred between 1910 and 1985. Given the remote location of the lake, the proximity of fires, and the lack of point sources within the region, these results suggested wildfires (rather than industrial sources) were a continuous source of Hg to Crystal Lake over the last 150 years.