Relations of hydrogeologic factors, groundwater reduction-oxidation conditions, and temporal and spatial distributions of nitrate, Central-Eastside San Joaquin Valley, California, USA

In a 2,700-km² area in the eastern San Joaquin Valley, California (USA), data from multiple sources were used to determine interrelations among hydrogeologic factors, reduction-oxidation (redox) conditions, and temporal and spatial distributions of nitrate (NO₃), a widely detected groundwater contaminant. Groundwater is predominantly modern, or mixtures of modern water, with detectable NO₃ and oxic redox conditions, but some zones have anoxic or mixed redox conditions. Anoxic conditions were associated with long residence times that occurred near the valley trough and in areas of historical groundwater discharge with shallow depth to water. Anoxic conditions also were associated with interactions of shallow, modern groundwater with soils. NO₃ concentrations were significantly lower in anoxic than oxic or mixed redox groundwater, primarily because residence times of anoxic waters exceed the duration of increased pumping and fertilizer use associated with modern agriculture. Effects of redox reactions on NO₃ concentrations were relatively minor. Dissolved N₂ gas data indicated that denitrification has eliminated >5 mg/L NO₃–N in about 10% of 39 wells. Increasing NO₃ concentrations over time were slightly less prevalent in anoxic than oxic or mixed redox groundwater. Spatial and temporal trends of NO₃ are primarily controlled by water and NO₃ fluxes of modern land use.     

Comprehensive Chemical and Isotopic Analyses of Basalt and Sediment Reference Materials

Geochemical studies of geological samples require the precise determination of their major and trace element contents and, when measured, of their isotopic compositions. It is now commonly accepted that the accuracy and precision of geochemical analyses are best estimated by the concomitant analysis of international reference materials run as unknown samples. Although the composition of a wide selection of basalts is relatively well constrained, this is far from being the case for sedimentary materials. We present here a comprehensive set of major and trace element data as well as Nd, Hf, Sr and Pb isotopic compositions for thirteen commonly used international reference materials – eight magmatic rocks (BHVO‐2, BR, BE‐N, BR 24, AGV‐1, BIR‐1, UB‐N, RGM‐1) and five sediments (JLk‐1, JSd‐1, JSd‐2, JSd‐3, LKSD‐1). We determined the concentrations of over forty elements in the magmatic rocks together with Sr, Nd, Hf and Pb isotopic compositions. Our trace element results were both accurate (difference ≤ 3%) and precise (reproducibility at 1s ≤ 3%) and the isotopic results were very similar to other published values. In contrast, we observed a significant chemical and isotopic variability in the sedimentary materials, which we attribute to mineral heterogeneities in the powders. Despite the limitation imposed by this heterogeneity, our work presents a complete set of data determined with a precision not yet achieved in the literature for sedimentary material. We also provide the first Nd, Hf and Pb isotopic measurements for the five sediments, which are commonly used by the geochemical community. Our study of both basalt and sediment reference materials represents a comprehensive and self‐consistent set of geochemical data and can therefore be considered as a reference database for the community.     

Data sharing and retrieval using OAI-PMH

There is a growing consensus for the need to store and archive digital data, particularly for publicly funded research. Long-term preservation of that data generally requires some form of institutional archive, such as those directed to particular scientific communities of practice. Given that data is often of use to multiple communities of practice, which may have differing norms for data and metadata structure and semantics, effective standards for data and metadata exchange are important factors for users to be able to find and retrieve data. Toolsets that provide a coherent presentation of information across multiple standards are important for data search and access. One such toolset, Mercury, is a open-source metadata harvesting, data discovery, and access system, built for researchers to search for, share and obtain spatiotemporal data used across a range of climate and ecological sciences. Mercury is used across multiple projects to provide a coherent search interface for spatiotemporal data described in any of several metadata formats. Mercury has recently been extended to enable harvesting and distribution of metadata using the Open Archive Initiative Protocol for Metadata Handling (OAI-PMH). In this paper we describe Mercury’s capabilities with multiple metadata formats, in general, and, more specifically, the results of our OAI-PMH implementations and the lessons learned.     

Can UV radiation affect benthic deposit-feeders through biochemical alteration of food resources? An experimental study with juveniles of the benthic polychaete Eupolymnia nebulosa

The growth, tentacle development and feeding activity of the benthic polychaete Eupolymnia nebulosa were examined to determine whether UV might affect marine deposit-feeders indirectly through the modification of the nutritional quality of their resources. Since marine invertebrates have higher nutritional requirements during the period following settlement, we tested the effect of UV-altered phytodetritus on freshly settled juveniles of E. nebulosa. Phytodetritus was prepared from cultures of the diatom Skeletonema costatum either grown under or sheltered from UVB radiation. Sterol content of phytodetritus was unmodified by UV radiation. Conversely, phytodetritus was noticeably depleted in polyunsaturated fatty acids. Growth and tentacle development of juveniles fed on altered phytodetritus were reduced by 35% and 15% respectively, suggesting potential deficiencies in essential nutrients. In response to the lower quality of the phytodetritus, juveniles explored a wider area as they search for food, a strategy that could compensate for low food quality.     

Trace elements in magnetite as petrogenetic indicators

We have characterized the distribution of 25 trace elements in magnetite (Mg, Al, Si, P, Ca, Sc, Ti, V, Cr, Mn, Co, Ni, Cu, Zn, Ga, Ge, Y, Zr, Nb, Mo, Sn, Hf, Ta, W, and Pb), using laser ablation ICP-MS and electron microprobe, from a variety of magmatic and hydrothermal ore-forming environments and compared them with data from the literature. We propose a new multielement diagram, normalized to bulk continental crust, designed to emphasize the partitioning behavior of trace elements between magnetite, the melt/fluid, and co-crystallizing phases. The normalized pattern of magnetite reflects the composition of the melt/fluid, which in both magmatic and hydrothermal systems varies with temperature. Thus, it is possible to distinguish magnetite formed at different degrees of crystal fractionation in both silicate and sulfide melts. The crystallization of ilmenite or sulfide before magnetite is recorded as a marked depletion in Ti or Cu, respectively. The chemical signature of hydrothermal magnetite is distinct being depleted in elements that are relatively immobile during alteration and commonly enriched in elements that are highly incompatible into magnetite (e.g., Si and Ca). Magnetite formed from low-temperature fluids has the lowest overall abundance of trace elements due to their lower solubility. Chemical zonation of magnetite is rare but occurs in some hydrothermal deposits where laser mapping reveals oscillatory zoning, which records the changing conditions and composition of the fluid during magnetite growth. This new way of plotting all 25 trace elements on 1 diagram, normalized to bulk continental crust and elements in order of compatibility into magnetite, provides a tool to help understand the processes that control partitioning of a full suit of trace elements in magnetite and aid discrimination of magnetite formed in different environments. It has applications in both petrogenetic and provenance studies, such as in the exploration of ore deposits and in sedimentology.     

An ichthyosaur (Reptilia: Ichthyosauria) specimen from the Lower Cretaceous (Berriasian) Spilsby Sandstone Formation of Nettleton,Lincolnshire, UK

A fragmentary ichthyosaur specimen collected in situ at Castle Top Quarry in Nettleton, Lincolnshire, UK from exposures of the Lower Cretaceous (Berriasian) Spilsby Sandstone Formation (Subcraspedites ?preplicomphalus Zone) is reported. In general, Early Cretaceous ichthyosaurs from the Berriasian to Barremian are poorly understood. Despite the fragmentary nature of the described specimen, it is the first ichthyosaur reported from this specific zone and adds to the literature another rare ichthyosaur from the Berriasian.     

Local perceptions of glacial retreat and livelihood impacts in the At-Bashy Range of Kyrgyzstan

Glaciers are critical water reservoirs in Central Asia, and their retreat has been the subject of scientific inquiry and regional water policy discourse in recent years. In the case of Kyrgyzstan, the total glaciated area has decreased approximately 25–35 % over the past 100 years—a statistic that has raised serious national security and economic development concerns. Scant research has addressed the topic of deglaciation from the perspective of local populations living in close proximity to glaciers. This paper reports on an effort to document local perceptions of, and relationships to, glaciers in the unique physical and socio-cultural context of the At-Bashy Range of Kyrgyzstan’s Tien Shan Mountains. The analysis draws upon data collected over an 11 month period through interviews with Kyrgyz herders, focus group interviews with diverse community members, and extensive field observations and interactions in high-elevation pastures and sub-basins. The analysis suggests that interview participants are unanimous in recognizing the economic, cultural, and symbolic roles of glaciers and mountain environments in sustaining semi-nomadic, livestock-based livelihood systems. Nevertheless, wide ranging and often contradictory opinions emerged about glacial retreat-related vulnerabilities and impacts. Further, extant and pressing political, economic and institutional challenges influence and mediate the extent to which glacial retreat is perceived and assessed as a local priority.     

A geochemical study of the impact of irrigation and aquifer lithology on groundwater in the Upper Yakima River Basin,Washington, USA

The Yakima River, a major tributary of the Columbia River, is currently overallocated in its surface water usage in part because of large agricultural water use. As a result, groundwater availability and surface water/groundwater interactions have become an important issue in this area. In several sub-basins, the Yakima River water is diverted and applied liberally to fields in the summer creating artificial recharge of shallow groundwater. Major ion, trace element, and stable isotope geochemistry of samples from 26 groundwater wells from a transect across the Yakima River and 24 surface waters in the Kittitas sub-basin were used to delineate waters with similar geochemical signatures and to identify surface water influence on groundwater. Major ion chemistry and stable isotope signatures combined with principal component analysis revealed four major hydrochemical groups. One of these groups, collected from shallow wells within the sedimentary basin fill, displays temporal variations in NO₃ and SO₄ along with high δ¹⁸O and δD values, indicating significant contribution from Yakima River and/or irrigation water. Two other major hydrochemical groups reflect interaction with the main aquifer lithologies in the basin: the Columbia River basalts (high-Na groundwaters), and the volcaniclastic rocks of the Ellensburg Formation (Ca–Mg–HCO₃ type waters). The fourth major group has interacted with the volcaniclastic rocks and is influenced to a lesser degree by surface waters. The geochemical groupings constrain a conceptual model for groundwater flow that includes movement of water between underlying Columbia River basalt and deeper sedimentary basin fill and seasonal input of irrigation water.     

Organohalogens and metals in marine fish and mussels and some relationships to biological variables at reference localities in Norway

The main goals of this study were to define, for the Norwegian coast, "high background" levels of micropollutants routinely monitored within the the Oslo and Paris Commission Joint Assessment and Monitoring Programme, and to reassess the present Norwegian reference levels used as the basis for a classification of environmental quality. The indicator organisms analysed as bulked/individual samples were cod (Gadus morhua, n approximately 1170; n approximately 240 for organochlorines), dab (Limanda limanda, n approximately 75), plaice (Pleuronectes platessa, n approximately 55) lemon sole (Microstomus kitt, n approximately 13). and blue mussels (Mytilus edulis, n approximately 200) collected between 1991-2000. Based on the 90-95 percentiles of measurements at localities far from point sources, we propose for liver of cod a reference level for SigmaPCB(7) (CBs 28, 52, 101, 118, 138, 153 and 180) of 500 microg kg(-1) w.w. and further for DDE 200 microg kg(-1), SigmaHCHs 30 microg kg(-1), HCB 20 and OCS 5 microgkg(-1) w.w. In the same order the proposed reference levels for liver of dab are: 150, 60, 15, 5, and 2 microgkg(-1) w.w.; and for the soft body of mussels: 3, 1, 1, 0.1 and 0.1 microg kg(-1) wet weight. Reference levels of metals are 0.1 mgHg kg(-1) w.w. in fish fillet, and for Hg, Cd, Pb, Zn, Cu in mussels 0.2, 2, 3, 200 and 10 mg kg(-1) d.w., respectively. Hg in fillet of cod and dab were positively correlated with length and weight. PCB levels in liver of cod and dab showed a positive but weak correlation with length, whereas no co-variation was found between PCBs and liver fat. The results of introductory recordings of polychlorinated dibenzo-p-dioxins/dibenzofurans, polychlorinated naphtalenes, Toxaphene and brominated flame retardants in liver of cod from reference sites are also presented.