Fe(II) adsorption on hematite (0 0 0 1)

The surface structure of α-Fe₂O₃(0 0 0 1) was studied using crystal truncation rod (CTR) X-ray diffraction before and after reaction with aqueous Fe(II) at pH 5. The CTR results show the unreacted α-Fe₂O₃(0 0 0 1) surface consists of two chemically distinct structural domains: an O-layer terminated domain and a hydroxylated Fe-layer terminated domain. After exposing the α-Fe₂O₃(0 0 0 1) surface to aqueous Fe(II), the surface structure of both co-existing structural domains was modified due to adsorption of Fe at crystallographic lattice sites of the substrate, resulting in six-coordinated adsorbed Fe at the surface. The average Fe-O bond lengths of the adsorbed Fe are consistent with typical Fe(III)-O bond lengths (in octahedral coordination), providing evidence for the oxidation of Fe(II) to Fe(III) upon adsorption. These results highlight the important role of substrate surface structure in controlling Fe(II) adsorption. Furthermore, the molecular scale structural characterization of adsorbed Fe provides insight into the process of Fe(II) induced structural modification of hematite surfaces, which in turn aids in assessing the effective reactivity of hematite surfaces in Fe(II) rich environments.     

Toward a radiometric ice clock: uranium ages of the Dome C ice core

Ice sheets and deep ice cores have yielded a wealth of paleoclimate information based on continuous dating methods while independent radiometric ages of ice have remained elusive. Here we demonstrate the application of (²³⁴U/²³⁸U) measurements to dating the EPICA Dome C ice core based on the accumulation of ²³⁴U in the ice matrix from recoil during ²³⁸U decay out of dust bound within the ice. Measured (²³⁴U/²³⁸U) activity ratios within the ice generally increase with depth while the surface areas of the dust grains are relatively constant. Using a newly designed device for measuring surface area for small samples, we were able to estimate reliably the recoil efficiency of nuclides from dust to ice. The resulting calculated radiometric ages range between 80 ka and 870 ka. Measured samples in the upper 3100 m fall on the previously published age-depth profile. Samples in the 3200–3255 m section show a marked change from 723–870 ka to 85 ka indicating homogenization of the deep ice prior to resetting of the (²³⁴U/²³⁸U) age in the basal layers. The mechanism for homogenization is likely enhanced lateral ice flow due to high basal melting and geothermal heat flux.     

Writing difference differently

This paper investigates the writing of situated knowledge and explores the possibilities of enacting difference by writing differently. We present a selection of research stories in which carrier bags, sounds, baskets, gardens and potatoes are interpreted less as objects of research or metaphors to aid in analysing phenomena, than as mediators of the stories. Our stories emphasise the ontological politics of engaging with and representing the relational, the messy, the spontaneous, the unpredictable, the non‐human and bodily experiences. These stories demonstrate how writing is performative and how it is integral to the production of knowledge.     

Triggering transformative change: a development path approach to climate change response in communities

While climate change action plans are becoming more common, it is still unclear whether communities have the capacity, tools, and targets in place to trigger the transformative levels of change required to build fundamentally low-carbon, resilient, healthy communities. Evidence increasingly supports the finding that this transformation is not triggered by climate policy alone, but rather is shaped by a broad array of decisions and practices that are rooted in underlying patterns of development. Even so, these findings have rarely penetrated the domain of practice, which often remains squarely focused on a relatively narrow set of climate-specific policies. This article builds a conceptual framework for understanding the dynamics of community-level development path transformations that may both dramatically reduce GHG emissions and significantly enhance community resilience. This framework illuminates eight critical enablers of innovation on climate change, each of which is illustrated by compelling examples of community-level experimentation on climate change across the province of British Columbia, Canada. It is concluded that community-based climate (or sustainability) policy might be more likely to trigger development path shifts if it employs a longer time horizon, recognition of adaptability and feedbacks, integrated decision making, and systems thinking.     

Acoustic mapping of fish aggregation areas to improve fisheries management in Las Perlas Archipelago,Pacific Panama

The purpose of this study was to investigate, characterize and map areas of the seabed of Las Perlas Archipelago (LPA), Republic of Panama using swath-bathymetry acoustic sonar techniques and to assess these methods as tools for feeding information into management zoning policy. In 2007 the LPA was granted conservation protection under national legislation. However, detailed management plans are still pending. Seabed mapping plays a fundamental role in identifying areas which should be prioritized within the management framework. Visual representation of habitat maps provides an effective medium for involving stakeholders in a co-management arena. In this survey, acoustically mapped areas of the seabed were ground-truthed using a combination of benthic grab samples, drop-down video and diver observations. The resulting mapped areas were then incorporated into a Geographic Information System (GIS) for further analysis. The output was a physical characterization of the seabed at three locations selected for being areas of high rugosity (habitat complexity) and, therefore, their potential importance as valuable fish aggregation sites. The rocky reefs and rhodolith beds identified in this survey represent particularly important fish aggregation and nursery habitats which should be considered priorities for protection under the management plans. This survey demonstrated the use of acoustic techniques to spatially resolve topographic features and physical characteristics of the seabed, illustrating their potential value as tools for fisheries management and marine reserve zoning in Las Perlas Archipelago and elsewhere.     

Sensitivity of reflection seismic data to oil-column height in high-porosity sandstones

Tuning is the effect of interference between the reflections from the top and bottom of a thin layer on the amplitude of the composite reflection. For a homogeneous sandstone reservoir containing an oil column overlying brine, interference between the reflection from the top reservoir and the oil/water contact is a function of the height of the oil column. If the properties of the sandstone do not vary across the oil/water contact, the SS, PS and SP reflection coefficients from the oil/water contact are small in comparison to the PP reflection coefficient. This allows analytic expressions for the effective PP and PS reflection coefficients from the reservoir to be derived that include all P‐wave multiples within the oil column. For a given source/receiver offset, the component of the wavevector inside the oil column normal to the interface is larger for the PPPP reflection than for the PPPS reflection, due to the asymmetry in the raypath for the PPPS reflection. The PPPS reflection is therefore useful for determining oil‐column heights larger than that discriminated by the PPPP reflection, especially when used at wider offsets. A convenient classification of the AVO response of hydrocarbon‐bearing sandstone reservoirs overlain by shale is the scheme of Rutherford and Williams. Class 1 sands have higher acoustic impedance for normal incidence than the overlying shale, Class 2 sands have nearly the same acoustic impedance as the shale and Class 3 sands have lower acoustic impedance. Synthetic shot gathers calculated for these three classes as a function of oil‐column height show that a combination of the PPPP and the PPPS amplitudes can be plotted as a tuning trajectory, which can be used to determine the oil‐column height. This method is most sensitive for reservoirs that belong to AVO classes 1 and 2, and therefore may be useful in AVO analysis of Class 1 and 2 reservoirs where the traditional AVO indicators (developed for Class 3 reservoirs) do not work very well. These results demonstrate the usefulness of shear waves recorded in the marine environment at wide offsets.     

A critique of the UK’s JNCC seismic survey guidelines for minimising acoustic disturbance to marine mammals: Best practise?

The United Kingdom’s statutory conservation agency, the Joint Nature Conservation Committee (JNCC), developed guidelines in 1995 to minimise acoustic disturbance of marine mammals by oil and gas industry seismic surveys. These were the first national guidelines to be developed and have subsequently become the standard, or basis, of international mitigation measures for noise pollution during seismic surveys. However, relatively few aspects of these measures have a firm scientific basis or proven efficacy. Existing guidelines do not offer adequate protection to marine mammals, given the complex propagation of airgun pulses; the difficulty of monitoring in particular the smaller, cryptic, and/or deep-diving species, such as beaked whales and porpoises; limitations in monitoring requirements; lack of baseline data; and other biological and acoustical complications or unknowns. Current guidelines offer a ‘common sense’ approach to noise mitigation, but in light of recent research and ongoing concerns, they should be updated, with broader measures needed to ensure adequate species protection and to address data gaps.     

Last glacial ice‐rafted debris off southwestern Europe: the role of the British–Irish Ice Sheet

Ice‐rafted debris (IRD) seeded into the ocean from Northern Hemisphere ice sheets is found in ocean cores along the southwestern European margin through the last glacial period. It is known that the origin of this IRD, especially off Iberia, can vary between North America and western Europe during short‐lived episodes of greatly enhanced iceberg flux, known as Heinrich events, although in most Heinrich events the IRD has a North American source. During the longer times of much lower IRD fluxes between Heinrich events, use of an intermediate complexity climate model, coupled to an iceberg dynamic and thermodynamic model, shows that background levels of IRD most likely originate from western Europe, particularly the British–Irish Ice Sheet. Combining modelling with palaeoceanographic evidence supports reconstructions of a short‐lived, but substantial, Celtic and Irish Sea Ice Stream around 23 ka. Copyright © 2010 John Wiley & Sons, Ltd.     

Origin of post‐Minoan caves and volcaniclastic cave fill,Thera (Santorini), Greece

The Aegean island of Thera (Santorini) was covered by tephra from its cataclysmic Late Bronze Age (ca. 3600 yr B.P.) eruption. Vertical exposures of the eruptive sequence show secondary, nonvolcanic, circular (in cross section) features composed of stratified sediment. Many are inaccessible from the floors of modern quarries and appear to be caves filled with younger sediment, but show no connection to the land surface. A filled cave was found in the wall of a modern gully outside the modern quarries, and a filled cave was found in a terrace scarp, well above the modern gully. Natural (and probably rapid) incision by gullies into the thick tephra deposit left many locations with lateral access to tephra. Inhabitants from post‐Minoan to recent times excavated tephra for materials and buildings, and caves were subsequently filled by sporadic (possibly seasonal) flood events that deposited sediment. These gullies may have provided access for modern tephra removal that isolated the filled caves high on the modern quarry walls. © 2003 Wiley Periodicals, Inc.     

Thin section petrography of northern Lesser Antilles ceramics

Thin sections from 44 sherds representing eight prehistoric sites on four islands (Barbuda, Montserrat, Anguilla, St. Martin) in the northern Lesser Antilles (West Indies) were examined using a petrographic microscope. Point counting distinguished three temper associations: (1) exclusively volcanic,(2) volcanic and carbonate, and (3) volcanic, carbonate, and grog. Exclusively volcanic or dominantly volcanic (with low carbonate) temper associations occur in all Saladoid and many post-Saladoid sherds, with plagioclase feld-spar and volcanic rock fragments being most abundant. Thin sections with significant carbonate content or with grog were restricted to post-Saladoid sherds from Barbuda and to a lesser extent Anguilla. the presence of volcanic grains in sherds from the limestone islands of Barbuda and Anguilla indicates that volcanic islands in the region served as sources of pottery (or volcanic temper) for these two islands.