Photobleaching of chromophoric dissolved organic matter (CDOM) in rainwater

Significant photodegradation of chromophoric dissolved organic matter (CDOM) in rainwater was observed after exposure to simulated sunlight. Fluorescence excitation emission spectra (EEMS) of precipitation revealed the presence of four major peaks all of which degraded upon photolysis with the greatest loss in the region characteristic of marine CDOM. Photobleaching of absorbance also occurred in the wavelength region between 250 and 375 nm with the greatest loss of absorbance in the upper end of the UV-A region near 275 nm. There was a strong positive correlation between absorbance loss and total integrated fluorescence loss suggesting these optical properties and the degree to which they are photobleached in rainwater are directly related. The quantum yield of CDOM photodegradation in rainwater decreased dramatically with increasing wavelength and decreasing energy of incoming radiation with the average quantum yield at 325 nm approximately an order of magnitude greater than at 460 nm. The similarity of photolytic response between rainwater and Cape Fear estuarine CDOM indicates that some fraction of the compounds that make up rainwater CDOM may be derived from surface sources and/or that the processes that produce or modify humic-like substances in the atmosphere result in similar types of compounds as non-atmospheric processes.     

Applying an optimized proxy-based workflow for fast history matching

History matching is still one of the main challenging parts of reservoir study especially in giant brown oil fields with lots of wells. In these cases, history matching with conventional manual technique needs many runs and takes months to get a match. In this work, an innovative approach was suggested for fast history matching in a real brown field. The workflow was employed based on an optimized proxy model for history matching of a field consisting of 14 active wells with multiple responses (which are production rate and pressure data) in the south part of Iran. The main important features of the proposed algorithm were defining a proxy model which is response surface method in which 21 model parameters were incorporated based on cubic centered face method. The proxy model was then optimized by one of the most famous algorithms which is genetic algorithm. Proxy model was successfully performed using 256 samples leading into p- value of 0.531 and R ² of 0.91 dataset. As a result, the proposed workflow and algorithm showed good and acceptable results for history matching of studied real model.     

A new tectonic model for Abu-Dabbab seismogenic zone (Eastern Desert,Egypt): evidence from field-structural,EMR and seismic data

Abu-Dabbab area is the most active seismic zone in the central Eastern Desert of Egypt, where seismic activities are daily recorded. The reported earthquakes are microearthquakes of local magnitudes (ML < 2.0). A spatial distribution of these microearthquakes shows that the earthquakes of the area follow an ENE–WSW trending pattern, which is nearly perpendicular to the Red Sea Rift. Focal mechanisms of different fault styles were recognized with dominant normal faulting (with a strike-slip component) events characterized by focal depths greater than 7 km and reverse ones of shallower focal depths. Several lines of evidence indicating that the brittle-ductile transition zone underlies the Abu-Dabbab area occurs at a relatively shallow depth (10–12 km) and it is acting as a low-angle normal shear zone (LANF). Field-structural, EMR and seismic data (this study) reveal that the maximum compressive stress (σ1) in the area is perturbed from the regional NW–SE direction to ENE–WSW orientation. This stress rotation is evidently akin to the reactivation of the crustal scale Najd Fault System (NFS), where such reactivation is attributed to the ongoing activity/opening of the Red Sea. Our tectonic model proposes that the continuous activity on the brittle-ductile transition zone including the LANF led to stress localization, which triggering a brittle deformation in the upper crustal-levels and associated shallow dipping thrusts. Such bimodal tectonic model suggests that the deep earthquakes are owing to the tectonic movement on the LANF (transtension), whereas the shallow earthquakes are related to a brittle deformation inside the fault blocks of the upper crust (transpression). Deformation creep along this zone didn’t permit continuous accumulation of strain and hence reduce the possible occurrence of large earthquakes.     

Exploiting historical rainfall and landslide data in a spatial database for the derivation of critical rainfall thresholds

Critical rainfall thresholds for landslides are powerful tools for preventing landslide hazard. The thresholds are commonly estimated empirically starting from rainfall events that triggered landslides in the past. The creation of the appropriate rainfall–landslide database is one of the main efforts in this approach. In fact, an accurate agreement between the landslide and rainfall information, in terms of location and timing, is essential in order to correctly estimate the rainfall–landslide relationships. A further issue is taking into account the average moisture conditions prior the triggering event, which reasonably may be crucial in determining the sufficient amount of precipitation. In this context, the aim of this paper is exploiting historical landslide and rainfall data in a spatial database for the derivation of critical rainfall thresholds for landslide occurrence in Sicily, southern Italy. The hourly rainfall events that caused landslides occurred in the twentieth century were specifically identified and reconstructed. A procedure was proposed to automatically convert rain guages charts recorded on paper tape into digital format and then to provide the cumulative rainfall hyetograph in digital format. This procedure is based on a segmentation followed by signal recognition techniques which allow to digitalize and to recognize the hyetograph automatically. The role of rainfall prior to the landslide events was taken into account by including in the analysis the rainfall occurred 5, 15 and 30 days before each landslide. Finally, cumulated rainfall duration thresholds for different exceedance probability levels were determined. The obtained thresholds resulted in agreement with the regional curves proposed by other authors for the same area; antecedent rainfall turned out to be particularly important in triggering landslides.     

Effect of modified Chaplygin gas in anisotropic universe

In this work, we have studied the model of modified Chaplygin gas and its role in accelerating phase of the universe for anisotropic model. We have assumed that the equation of state of this modified model is valid from the radiation era to ΛCDM model. We have obtained the possible relation between the hessence and the modified Chaplygin gas. We have also use the statefinder parameters for characterize different phase of the universe diagrammatically.     

What is responsible for increasing flood risks? The case of Gangwon Province,Korea

We examined the anthropogenic and natural causes of flood risks in six representative cities in the Gangwon Province of Korea. Flood damage per capita is mostly explained by cumulative upper 5% summer precipitation amount and the year. The increasing flood damage is also associated with deforestation in upstream areas and intensive land use in lowlands. Human encroachment on floodplains made these urban communities more vulnerable to floods. Without changes in the current flood management systems of these cities, their vulnerability to flood risks will remain and may even increase under changing climate conditions.