Optical absorption and mössbauer spectra of purple and green yoderite,a kyanite-related mineral

Mössbauer and polarized optical absorption spectra of the kyanite-related mineral yoderite were recorded. Mössbauer spectra of the purple (PY) and green yoderite (GY) from Mautia Hill, Tanzania, show that the bulk of the iron is Fe³⁺ in both varieties, with Fe²⁺/(Fe²⁺+Fe³⁺) ratios near 0.05. Combining this result with new microprobe data for PY and with literature data for GY gives the crystallochemical formulae: $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.95}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{0}}{\text{.01}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.34}}}^{{\text{3 + }}} {\text{Mn}}_{{\text{0}}{\text{.07}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.57}}} )_{5.97}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.98}}} {\text{P}}_{{\text{0}}{\text{.03}}} ){\text{O}}_{{\text{18}}{\text{.02}}} ({\text{OH)}}_{{\text{1}}{\text{.98}}} ] \hfill \\ \end{gathered}$$ and PY and $$\begin{gathered} ({\text{Mg}}_{{\text{1}}{\text{.98}}} {\text{Fe}}_{{\text{0}}{\text{.02}}}^{{\text{2 + }}} {\text{Mn}}_{{\text{< 0}}{\text{.001}}}^{{\text{2 + }}} {\text{Fe}}_{{\text{0}}{\text{.45}}}^{{\text{3 + }}} {\text{Ti}}_{{\text{0}}{\text{.01}}} {\text{Al}}_{{\text{3}}{\text{.56}}} )_{6.02}^{[5,6]} \hfill \\ {\text{Al}}_{{\text{2}}{\text{.00}}}^{{\text{[5]}}} [({\text{Si}}_{{\text{3}}{\text{.91}}} {\text{O}}_{{\text{17}}{\text{.73}}} {\text{(OH)}}_{{\text{2}}{\text{.27}}} ] \hfill \\ \end{gathered}$$ for GY. The Mössbauer spectra at room temperature contain one main doublet with isomer shifts and quadrupole splittings of 0.36 (PY), 0.38 (GY) and 1.00 (PY), 0.92 (GY) mm s^?1, respectively. These values correspond to Fe³⁺ in six or five-fold coordination. The doublet components have anomalously large half widths indicating either accomodation of Fe³⁺ in more than one position (e.g., octahedraA1 and five coordinatedA2) or the yet unresolved superstructure. Besides strong absorption in the ultraviolet (UV) starting from about 25,000 cm^?1, the polarized optical absorption spectra are dominated by strong bands around 16,500 and 21,000 cm^?1 (PY) and a medium strong band at around 13,800 cm^?1 (GY). Position and polarization of these bands, in combination with the UV absorption, explain the colour and pleochroism of the two varieties. The bands in question are assigned to homonuclear metal-to-metal charge transfer transitions: Mn²⁺(A1) Mn³⁺(A1′) ? Mn³⁺(A1) Mn²⁺(A1′) and Mn²⁺(A1) Mn³⁺(A2 ? Mn³⁺(A1) Mn²⁺(A2) in PY and Fe²⁺(A1) Fe³⁺(A1′) ? Fe³⁺(A1) Fe²⁺(A1′) in GY. The evidence for homonuclear Mn²⁺ Mn³⁺ charge transfer (CTF) is not quite clear and needs further study. Heteronuclear FeTi CTF does not contribute to the spectra. In PY, additional weak bands were resolved at energies around 17,700, 18,700, 21,000, and 21,900 cm^?1 and assigned to Mn³⁺ in two positions. Weak bands around 10,000 cm^?1 in both varieties are assigned to Fe²⁺ spin-alloweddd-transitions. Very weak and sharp bands, around 15,400, 16,400, 21,300, 22,100, 23,800, and 25,000 cm^?1 are identified in GY and assigned to Fe³⁺ spin-forbiddendd-transitions.     

Phobos-grunt soil sampling device

The main objective of the Phobos-Grunt spacecraft mission is to sample Phobos soil and delivery it to Earth. Soil sampling is performed by means of a soil sampling device. The article covers the structure of the soil sampling device, its main functions and operation cyclogram.     

Mid-infrared, spatially resolved spectroscopy of the nucleus of the Circinus galaxy

High spatial resolution spectroscopy at 8–13 μm with T-ReCS on Gemini-S has revealed striking variations in the mid-infrared emission and absorption in the nucleus of the Circinus galaxy (hereafter Circinus) on subarcsecond scales. The core of Circinus is compact and obscured by a substantial column of cool silicate dust. Weak extended emission to the east and west coincides with the coronal line region and arises from featureless dust grains which are probably heated by line emission in the coronal emission zone. The extended emission on the east side of the nucleus displays a much deeper silicate absorption than that on the west, indicating significant columns of cool material along the line of sight and corresponding to an additional extinction of   A_V ∼ 25 mag  . Emission bands from aromatic hydrocarbons are not subject to this additional extinction, are relatively weak in the core and in the coronal line region, and are much more spatially extended than the continuum dust emission; they presumably arise in the circumnuclear star-forming regions. These data are interpreted in terms of an inclined disc-like structure around the nucleus extending over tens of parsecs and possibly related to the inner disc found from observations of water masers by Greenhill et al..     

Observations of the compact group of galaxies Shahbazian 130

Byurakan Astrophysical Observatory and Special Astrophysical Observatory, Academy of Sciences. Translated fromAstrofizika, Vol. 35, No. 1, pp. 67–75, July–August, 1991.     

Measurement of Kodaikanal White-Light Images – II. Rotation Comparison and Merging with Mount Wilson Data

Sunspot umbral positions and areas were measured for 82 years (1906–1987) of daily, full-disk photoheliogram observations at the Kodaikanal station of the Indian Institute of Astrophysics. The measurement technique and reduction procedures used were nearly identical to those used earlier for the reduction of Mount Wilson daily full-disk photoheliograms, covering an overlapping interval of 69 years. In this paper we compare the differential rotation of the Sun from the analysis of the Kodaikanal data with the Mount Wilson results. In addition, we analyze the data set formed by combining the data from the two sites for differential rotation. While doing this, it has become apparent to us that small, subtle optical effects at both sites produce systematic errors that have an influence on rotation (and other) results from these data. These optical effects are analyzed here, and corrections are made to the positional data of the sunspots from both sites. A data set containing the combined positional data of sunspots from both sites, corrected for these optical aberrations, has been constructed. Results for both sunspot groups and individual sunspots are presented. It is pointed out that optical aberrations similar to those found in the Kodaikanal data may also exist in the Greenwich photoheliograph data, because these two sets of solar images were made with similar telescopes.     

Crop residue effects on surface radiation and energy balance — review

Summary Crop residues alter the surface properties of soils. Both shortwave albedo and longwave emissivity are affected. These are linked to an effect of residue on surface evaporation and water content. Water content influences soil physical properties and surface energy partitioning. In summary, crop residue acts to soil as clothing acts to skin. Compared to bare soil, crop residues can reduce extremes of heat and mass fluxes at the soil surface. Managing crop residues can result in more favorable agronomic soil conditions. This paper reviews research results of the quantity, quality, architecture, and surface distribution of crop residues on soil surface radiation and energy balances, soil water content, and soil temperature.With 6 Figures     

Observations of Low-Latitude Coronal Plumes

Using Fe ix/x 17.1 nm observations from the Extreme-Ultraviolet Imaging Telescope (EIT) on the Solar and Heliospheric Observatory (SOHO), we have identified many coronal plumes inside low-latitude coronal holes as they transited the solar limb during the late declining phase of cycle 23. These diffuse, linear features appear to be completely analogous to the familiar polar plumes. By tracking them as they rotate from the limb onto the disk (or vice versa), we confirm that EUV plumes seen against the disk appear as faint, diffuse blobs of emission surrounding a brighter core. When the EIT images are compared with near-simultaneous magnetograms from the SOHO Michelson Doppler Imager (MDI), the low-latitude, on-disk plumes are found to overlie regions of mixed polarity, where small bipoles are in contact with unipolar flux concentrations inside the coronal hole. The birth and decay of the plumes are shown to be closely related to the emergence of ephemeral regions, their dispersal in the supergranular flow field, and the cancellation of the minority-polarity flux against the dominant-polarity network elements. In addition to the faint polar and nonpolar plumes associated with ephemeral regions, we note the existence of two topologically similar coronal structures: the giant plume-like features that occur above active regions inside coronal holes, and the even larger scale “pseudostreamers” that separate coronal holes of the same polarity. In all three cases, the basic structure consists of open field lines of a given polarity overlying a photospheric region of the opposite polarity; ongoing interchange reconnection at the X-point separating the open field domains from the underlying double-arcade system appears to result in the steady evaporation of material from the closed into the open region.     

Timing and intensity of groundwater movement during Egyptian Sahara pluvial periods by U-series analysis of secondary U in ores and carbonates

Wet climatic episodes are known to have prevailed in the Egyptian Sahara several times during the late Quaternary, most recently during the Holocene 8000 yr ago. Earlier wet episodes have been recognized as having occurred during the past 300,000 yr and have been dated by U-series methods in speleothems and in lake travertines. We show here that the times of enhanced groundwater movement can also be determined by ²³⁰Th/²³⁴U dating of secondary U in ores of uranium, iron, and phosphate. We also present evidence that such acceleration of groundwater movements is indicated by relatively low ²³⁴U/²³⁸U activity ratios in the secondary uranium. Our new data show that pluvial periods in Egypt occurred during marine oxygen isotope stages 4, 5, 6, and 7 and therefore are consistent with the view that the wet episodes are the results of migration of the tropical monsoonal belt driven primarily by the 23,000-yr precession cycle of the Milankovich curve, modulated by the 100,000-yr eccentricity cycle.