Stabilization of fuel oil contaminated soil—A case study

Fuel oil contamination brings adverse effect on basic geotechnical properties of foundation soil. The present study pertains to one such case, from the petrochemical complex near Vadodara City in Gujarat State, India. Here, the fuel oil contaminated soil samples exhibit drastic changes in their geotechnical parameters. Noteworthy among such deleterious changes are: decrease in maximum dry density (–4%), cohesion (–66%), angle of internal friction (–23%) and unconfined compressive strength (UCS) (–35%) and increase in liquid limit (+11%). An attempt has been made to stabilize the contaminated soil using various additives viz., lime, fly ash and cement independently as well as an admixture of different combinations. It is apparent from the test results that the stabilization agents improved the geo-technical properties of the soil by way of cation exchange, agglomeration, and pozzuolanic actions. The best results were observed when a combination of 10% lime, 5% fly ash and 5% cement was added to the contaminated soil. The improvement in unconfined compressive strength (UCS), cohesion and angle of internal friction can be attributed to neo-formations such as Calcium Silicate Hydrates (CSH, CSH-1) that coats and binds the soil particles. Formation of stable complex between oil and metallic cations, results in reduction of leachableoil.     

The use of buffers to measure the pH of seawater

The pH of seawater can be measured in the field using potentiometric and spectrophotometric methods. The use of pH standards or buffers is an important aspect of the calibration of both methods in a laboratory on a common concentration scale. The buffers can also be used to monitor the performance of pH meter and spectrophotometer during a cruise. A procedure is described for the determination of the pH of seawater, where the proton concentration is expressed as moles kg-H₂O⁻¹ using seawater buffers. The buffers are prepared in synthetic seawater in the laboratory by the methods outlined by Bates and coworkers. We have prepared four buffers (Bis, Tris, Morpholine and 2-Aminopyridine) that cover a pH range from 6.8 to 8.8. The emf values of the buffers were measured with a H₂, Pt/AgCl, Ag electrode system after their preparation and bottling for use at sea. The measured emf values were found to be in good agreement (±0.05 mV) with the original measurements of Bates and coworkers from 0 to 45°C. The measured pH of these buffers are in good agreement (±0.001 pH units) with the values calculated from the equations of Dickson on the total pH scale based on Bates et al. Studies are underway to access the long term stability of these buffers. We have also used these buffers to calibrate systems used to make potentiometric and spectrophotometric measurements of pH on seawater relative to the H₂, Pt/Ag, AgCl electrode from 5 to 45°C.     

GPS measurement of land subsidence in Gandhinagar,Gujarat (Western India), due to groundwater depletion

A continuous GPS measurement site, ISRR, at Gandhinagar (Western India), documented ~?5 mm/year of surface subsidence rate during 2009–2016. Preliminary modelling using an analytical solution indicates that the observed surface subsidence rate at the ISRR site is consistent with the ground water depletion reported from Gandhinagar. An assessment of data from GPS sites at Lucknow and Varanasi in the Indo-Gangetic plains in Northern India does not indicate any significant subsidence at these sites which is also consistent with the in situ observations of insignificant depletion of ground water in the region.     

Determination of focal depths of moderate earthquakes in Northeast Indian region using depth phase sPn

Natural Hazards - The precise focal depth of earthquakes is a crucial parameter for better characterising of complex tectonic zones, especially where seismogenic faults occur at different depths....     

Phenomenological fractional stress–dilatancy model for granular soil and soil-structure interface under monotonic and cyclic loads

The stress–dilatancy relation is of critical importance for constitutive modelling of geomaterial. A novel fractional-order stress–dilatancy equation had been developed for granular soil, where a nonlinear stress–dilatancy response was always predicted. However, it was experimentally observed that after a certain extent of shearing, an almost linear response between the stress ratio and the dilatancy ratio, rather than the nonlinear response, usually existed. To capture such stress–dilatancy behaviour, a new fractional stress–dilatancy model is developed in this study, where an apparent linear response of the stress–dilatancy behaviour of soil after sufficient shearing is obtained via analytical solution. As the fractional order varies, the derived stress–dilatancy curve and the associated phase transformation state stress ratio keep changing. But, unlike existing researches, no other specific parameters, except the parameter related to fractional order, concerning such shift are required. Then, the developed stress–dilatancy model is applied to constitutive modelling of granular soil and soil–structure interface, for further validation. A series of test results of different granular soils and soil–structure interfaces under different loading conditions are simulated and compared, where a good model performance is observed.

     

Study of Dynamical Structure of an Unusual Monsoon Depression formed over the Bay of Bengal during August 2006

Monsoon depressions, the main rain-producing systems over the Indian region along and near their tracks, are found to intensify the monsoon circulation by organizing low-level convergence. The normal track of the monsoon depressions is along the position of the monsoon trough at the surface, i.e., northwestward from the Head Bay of Bengal. Most of the monsoon depressions dissipate within one or two days after landfall. An unusual monsoon depression formed in the Bay of Bengal during the 1^st week of August 2006 causing heavy to very heavy rainfall over Madhya Pradesh, Maharashtra and Gujarat States of India. The track of this depression was anomalously southward from the mean track of the August depressions. It maintained its intensity during its longer travel. This paper addresses some of the dynamical characteristics of the depression in relation to its southward/westward track and longer travel. It is observed that horizontal advection of absolute vorticity above 550 hPa (below 600 hPa) along west (east) of the depression and maximum divergence of absolute vorticity below 400 hPa dominated for the westward movement of the depression. Increased moisture supply from the Arabian Sea (after the landfall of the depression) helped to maintain the intensity of the system throughout its long travel. The energy conversion terms revealed the strengthening of the zonal flow at higher levels prior to the formation of the depression.     

Stream temperature response to variable glacier coverage in coastal watersheds of Southeast Alaska

We measured stream temperature continuously during the 2011 summer run‐off season (May through October) in nine watersheds of Southeast Alaska that provide spawning habitat for Pacific salmon. The nine watersheds have glacier coverage ranging from 0% to 63%. Our goal was to determine how air temperature and watershed land cover, particularly glacier coverage, influence stream temperature across the seasonal glacial meltwater hydrograph. Multiple linear regression models identified mean watershed elevation (related to glacier extent) and watershed lake coverage (%) as the strongest landscape controls on mean monthly stream temperature, with the weakest (May) and strongest (July) models explaining 86% and 97% of the temperature variability, respectively. Mean weekly stream temperature was significantly correlated with mean weekly air temperature in seven streams; however, the relationships were weak to non‐significant in the streams influenced by glacial run‐off. Streams with >30% glacier coverage showed decreasing stream temperatures with rising summer air temperatures, whereas those with <30% glacier coverage exhibited summertime warming. Glaciers also had a cooling effect on monthly mean stream temperature during the summer (July through September) equivalent to a decrease of 1.1 °C for each 10% increase in glacier coverage. The maximum weekly average temperature (an index of thermal suitability for salmon) in the six glacial streams was substantially below the lower threshold for optimum salmon growth. This finding suggests that although glaciers are important for moderating summer stream temperatures, future reductions in glacier run‐off may actually improve the thermal suitability of some glacially dominated streams in Southeast Alaska for salmon. Copyright © 2013 John Wiley & Sons, Ltd.