Intercalibration of international and domestic 40Ar/39Ar dating standards

Four international standards, Ga1550, MMhb-1, Lp-6, Bem 4M, and one domestic standard BT-1 have been intercalibrated. The repeated measurements on MMhb-1 with different mass demonstrate that MMhb-1 is inhomogeneous in age and its average age is 519.8 Ma. The results of Bern 4M and Lp-6 reflect that they have an invariable value of ⁴⁰Ar*/³⁹Ar_k (F) and the ages we obtained are consensus with their K-Ar age: Lp-6=127.7Ma; Bern 4M=18.2 Ma. Analyses of BT-1 age spectra, Ca/K and Cl/K spectra as well as inverse isochrons indicate that the sample is homogeneous and invariable and keeps close chemically, with its trapped argon isotope composition close to the atmosphere. The dating results show that age values are reproducible and steady, total fusion age, step-heating age, plateau age and isochron age are in accord with each other within the error range (2σ). Therefore, we recommend 28.7 Ma as the calibrated age of BT-1. We also discuss the variation in neutron flux gradients of Beijing 49-2 reactor. It was found that the neutron flux gradient varies considerably, and more monitors (standard samples) are needed to fix the trend of variation. The coefficient of the 49-2 reactor that transfers the ratio of production rate of ³⁷Ar_Ca/³⁹Ar_K into Ca/K ratio is 1.78. This is different from that reported earlier, 2.0, which may be caused by the reconstruction of the reactor.     

宁夏冬季负积温变化特征

对宁夏20个测站1961—2004年的冬季负积温EOF分析表明,冬季的冷趋势具有明显的大尺度特征,在近40 a逐渐变暖。据累积距平显示,l986年出现了突变,之前,冬季气温偏低,具体表现为冷冬年全部分布在此时段,之后偏暖,90年代以后出现暖冬的频次明显增加。≤0℃持续日数具有明显的年代际变化,2001—2004年比60年代平均减少了13.5 d。在80%保证率下,全区≤0℃持续日数和负积温依地势自北向南增多,引黄灌区最少,中部干旱带次之,南部黄土丘陵区相对最多。     

济南东部埠村超单元及其就位机制

分布于济南东部六山圈—大有一带的侵入岩,为燕山早期同一岩浆热事件多次侵入形成的杂岩体,依其形成顺序可划分为山张庄、西杜、大有、赵家鹊山四个单元,归并为埠村超单元。该超单元的形成与幔源基性岩浆上侵及同源岩浆分异产生的中偏基性—中性岩浆多次侵入有关,属热气球式膨胀与火山口塌陷复合就位机制。     

Cordierite breakdown under high-pressure hydrous conditions

Green and Vernon (1974) have experimentally determined a divariant field of cordierite-orthoamphibole-kyanite-quartz with a slope of 12±4 bars per °C occurring between 8.0 and 10.4 kbar at 750° C and between 9.5 and 11.3 kbar at 850° C. However, the writers' thermodynamic calculation of the divariant band indicates a more limited range of 0.65 and 0.7 kbar at 750° C and 850° C respectively, with an estimated error of ±0.2 kbar.     

Demersally drifting invertebrates from Kongsfjorden,Svalbård (Arctic Ocean)–a comparison of catches from drift-pump and drift-nets

Demersally drifting organisms were collected at Ny Ålesund (Svalbård–Arctic Ocean) to study the taxon composition and relative abundances in the Arctic summer. Catch potentials of two collection devices for demersal drift were compared. A lowvolume submersible drift-pump and a drift-net unit were employed for the collection of demersally drifting biota, particularly for shallow aquatic habitats. With the exception of Appendicularia, Chaetognatha, Coelenterata, and Ctenophora, which were damaged at times, the pump catches were in good condition and sufficient for identification and quantification of less mobile fauna. A comparison of the two devices revealed that the drift-pump collected more specimens than the drift-net. However, the drift-net may have caused an underestimation of the abundances of invertebrates. No differences in identified taxon number and indices of richness, evenness and diversity were found. However, the proportion of invertebrate animals in the two devices was different for the three groups: zooplankton, macrofauna and meiofauna. At Svalbård, zooplankton, larvae of macrofauna, and meiofauna were successfully collected by the two collecting devices. However, the catchibility of the two devices in collecting various invertebrate taxa was different and, therefore, a sound ‘Device Effect’ was revealed.     

大坪里—向阳坪地区铀成矿条件分析

从岩体特征、构造条件、围岩蚀变,以及矿石类型等方面总结了大坪里—向阳坪地区铀成矿特征,开展了铀成矿条件分析。并与沙子江铀矿床铀成矿特征相比较,确定找矿类型为受脆-韧性走滑断裂带控制的硅质脉型热液铀矿,为今后的工作奠定了基础。     

模拟CO_2埋藏的煤储层元素迁移实验研究

采用高压超临界CO2地球化学反应器对CO2在煤储层中的地质埋藏进行模拟,利用电感耦合等离子体发射光谱仪(ICP-OES)以及电感耦合等离子体质谱(ICP-MS)分别对淋滤液和煤样中的10种微量元素进行测试,对煤中微量元素在CO2的地质埋藏过程中的迁移进行了实验研究。结果表明:在CO2的地质埋藏过程中对煤的有机组成和无机矿物等均具有改造作用,从而影响到煤中微量元素的赋存和迁移特征,Cr、Zn、Cu等元素迁移能力相对较强,而Co、Ba、V等元素相对较弱;元素迁移能力大小顺序为:CrZnCuNiCdMnCoBaV。     

Effects of natural and calcined oyster shells on Cd and Pb immobilization in contaminated soils

In Korea, soils adjacent to abandoned mines are commonly contaminated by heavy metals present in mine tailings. Further, the disposal of oyster shell waste by oyster farm industries has been associated with serious environmental problems. In this study, we attempted to remediate cadmium (Cd)- and lead (Pb)-contaminated soils typical of those commonly found adjacent to abandoned mines using oyster shell waste as a soil stabilizer. Natural oyster shell powder (NOSP) and calcined oyster shell powder (COSP) were applied as soil amendments to immobilize Cd and Pb. The primary components of NOSP and COSP are calcium carbonate (CaCO₃) and calcium oxide (CaO), respectively. X-ray diffraction, X-ray fluorescence and scanning electron microscope analyses conducted in this study revealed that the calcination of NOSP at 770°C converted the less reactive CaCO₃ to the more reactive CaO. The calcination process also decreased the sodium content in COSP, indicating that it was advantageous to use COSP as a liming material in agricultural soil. After 30 days of incubation, we found that the 0.1 N HCl-extractable Cd and Pb contents in soil decreased significantly as a result of an increase in the soil pH and the formation of metal hydroxides. COSP was more effective in immobilizing Cd and Pb in the contaminated soil than NOSP. Overall, the results of this study suggest that oyster shell waste can be recycled into an effective soil ameliorant.     

Effects of biochar, cow bone, and eggshell on Pb availability to maize in contaminated soil irrigated with saline water

Toxicity of heavy metals adversely affects environment and human health. Organic materials derived from natural matters or wastes have been applied to soils to reduce the mobility of contaminants such as heavy metals. However, the application of cow bone powder (CB), biochar (BC), and eggshell powder (ES) is rarely investigated for the reduction of Pb bioavailability in soils irrigated with saline water. The objective of this study was to assess the effectiveness of CB, BC, and ES additions as immobilizing substances on Pb bioavailability in shooting range soil irrigated with deionized and saline water. Each additive of CB, BC, and ES at 5 % (w/w) was mixed with soils and then the deionized and saline water were irrigated for 21 days. With deionized water irrigation, the soils treated with CB, BC, and ES exhibited higher pH when compared with saline water irrigation. With saline water irrigation, the electrical conductivity, water-soluble anions, and cations were significantly increased in soils treated with CB, BC, and ES. The water-soluble Pb in soils treated with CB, BC, and ES was significantly decreased with saline water irrigation. On the other hand, the water-soluble Pb in soil treated with CB was increased with deionized water irrigation. Only BC with saline water irrigation decreased the Pb concentration in maize shoots.     

黔西地区煤层埋深与地应力对其渗透性控制机制

基于黔西六盘水煤田和织纳煤田16口井36层次的试井资料, 采用地质统计分析等方法, 探讨了黔西地区煤储层渗透性的展布规律与地应力特征, 论证了煤层埋深与地应力对其渗透性的控制机制.研究表明, 研究区煤储层以特低渗-低渗透率储层(＜0.1×10-9m2)为主, 中渗透率储层(0.1×10-9~1.0×10-9m2)也占有相当大比例; 应力场类型在浅部表现为大地动力场型, 一定深度可能转化为准静水压力状态.煤储层渗透率及其埋深的负幂指数关系较为离散, 但在不同深度渗透率转折点与地应力场类型转变一致; 单井煤储层试井渗透率差异较大, 随地应力增大和埋深增加而降低, 平面展布受地应力强度控制由SW-NE具"低-高-低"发育规律.埋深对渗透率的控制实质是地应力的控制, 区域构造位置及其所处高应力场作用下的煤体形变与破碎致使孔裂隙压缩或闭合是该区渗透性差异的主要控制机制.