Elemental and isotopic fractionation of Type B CAI-like liquids by evaporation

Vacuum evaporation experiments with Type B CAI-like starting compositions were carried out at temperatures of 1600, 1700, 1800, and 1900 °C to determine the evaporation kinetics and evaporation coefficients of silicon and magnesium as a function of temperature as well as the kinetic isotope fractionation factor for magnesium. The vacuum evaporation kinetics of silicon and magnesium are well characterized by a relation of the form J = J_oe^−E/RT with J_o = 4.17 × 10⁷ mol cm⁻² s⁻¹, E = 576 ± 36 kJ mol⁻¹ for magnesium, J_o = 3.81 × 10⁶ mol cm⁻² s⁻¹, E = 551 ± 63 kJ mol⁻¹ for silicon. These rates only apply to evaporation into vacuum whereas the actual Type B CAIs were almost certainly surrounded by a finite pressure of a hydrogen-dominated gas. A more general formulation for the evaporation kinetics of silicon and magnesium from a Type B CAI-like liquid that applies equally to vacuum and conditions of finite hydrogen pressure involves combining our determinations of the evaporation coefficients for these elements as a function of temperature (γ = γ₀e^−E/RT with γ₀ = 25.3, E = 92 ± 37 kJ mol⁻¹ for γ_Si; γ₀ = 143, E = 121 ± 53 kJ mol⁻¹ for γ_Mg) with a thermodynamic model for the saturation vapor pressures of Mg and SiO over the condensed phase. High-precision determinations of the magnesium isotopic composition of the evaporation residues from samples of different size and different evaporation temperature were made using a multicollector inductively coupled plasma mass spectrometer. The kinetic isotopic fractionation factors derived from this data set show that there is a distinct temperature effect, such that the isotopic fractionation for a given amount of magnesium evaporated is smaller at lower temperature. We did not find any significant change in the isotope fractionation factor related to sample size, which we interpret to mean that recondensation and finite chemical diffusion in the melt did not affect the isotopic fractionations. Extrapolating the magnesium kinetic isotope fractionations factors from the temperature range of our experiments to temperatures corresponding to partially molten Type B CAI compositions (1250-1400 °C) results in a value of α_Mg ≈ 0.991, which is significantly different from the commonly used value of .     

Assessment of Potential Alkali Aggregate Reactivity for Siliceous and Carbonate Aggregates: A Case Study

Alkali-aggregate reactivity (AAR) involves a reaction between the pore solution of concrete and certain minerals found in some aggregates. To assess the potential AAR various physical and chemical tests are available and extensively used. The petrographic examination is the initial assessment that decides the further investigation for potential reactivity of an aggregate. A chemical approach is another option to assess the aggregate for potential AAR. The accelerated mortar bar method and concrete prism tests are other very important tests for determination of potential AAR of aggregates samples. However, a combination of the results of all the techniques provides most reliable results for potential AAR in aggregates. Moreover, each test represents the stepwise investigation and provides the decision for the test of next approach. Petrographic examination and chemical test methods are the quick decision-making methods for the estimation of potential AAR. In some cases, by these two methods, the aggregate can be selected and rejected confidently. However, for critical values or doubtful aggregates, further tests are necessary to develop a higher confidence level of the results. The present study comprises of the assessment of the alkali-reactivity of siliceous and carbonate aggregates using petrographic and chemical approaches. X-ray diffraction analysis was used as a complementary method to the petrographic evaluation. Moreover, under chemical approach, two separate test methods were used for siliceous and carbonate aggregates. The study also included a comparison between the petrographic examination and chemical analysis for the same aggregate samples and found significant results.     

Reducing landscape heterogeneity for improved land use and land cover (LULC) classification across the large and complex Ethiopian highlands

This paper presents a land use and land cover (LULC) classification approach that accounts landscape heterogeneity. We addressed this challenge by subdividing the study area into more homogeneous segments using several biophysical and socio-economic factors as well as spectral information. This was followed by unsupervised clustering within each homogeneous segment and supervised class assignment. Two classification schemes differing in their level of detail were successfully applied to four landscape types of distinct LULC composition. The resulting LULC map fulfills two major requirements: (1) differentiation and identification of several LULC classes that are of interest at the local, regional, and national scales, and (2) high accuracy of classification. The approach overcomes commonly encountered difficulties of classifying second-level classes in large and heterogeneous landscapes. The output of the study responds to the need for comprehensive LULC data to support ecosystem assessment, policy formulation, and decision-making towards sustainable land resources management.     

Managing Groundwater to Ensure Ecosystem Function

Groundwater is a critical resource not only for human communities but also for many terrestrial, riparian, and aquatic ecosystems and species. Yet groundwater planning and management decisions frequently ignore or inadequately address the needs of these natural systems. As a consequence, ecosystems dependent on groundwater have been threatened, degraded, or eliminated, especially in arid regions. There is growing acknowledgment that governmental protections for these ecological resources are necessary, but current legal, regulatory and voluntary provisions are often inadequate. Groundwater management premised on “safe yield,” which aims to balance human withdrawals with natural recharge rates, typically provides little to no consideration for water needed by ecosystems. Alternatively, the “sustainable yield” concept aims to integrate social, economic and environmental needs for groundwater, but the complexity of groundwater systems creates substantial uncertainty about the impact that current or future groundwater withdrawals will have on ecosystems. Regardless of the legal or regulatory framework, guidance is needed to help ensure environmental water needs will be met, especially in the face of pressure to increase human uses of groundwater resources. In this paper, we describe minimum provisions for planning, managing, and monitoring groundwater that collectively can lower the risk of harm to groundwater-dependent ecosystems and species, with a special emphasis on arid systems, where ecosystems and species may be especially reliant upon and sensitive to groundwater dynamics.     

Interaction of chemical and physical processes during deformation at fluid-present conditions: a case study from an anorthosite–leucogabbro deformed at amphibolite facies conditions

We present microstructural and chemical analyses of chemically zoned and recrystallized plagioclase grains in variably strained samples of a naturally deformed anorthosite–leucogabbro, southern West Greenland. The recorded microstructures formed in the presence of fluids at mid-crustal conditions (620–640 °C, 7.4–8.6 kbar). Recrystallized plagioclase grains (average grain size 342 μm) with a random crystallographic orientation are volumetrically dominant in high-strain areas. They are characterized by asymmetric chemical zoning (An₈₀ cores and An₆₄ rims) that are directly associated with areas exhibiting high amphibole content and phase mixing. Analyses of zoning indicate anisotropic behaviour of bytownite plagioclase with a preferred replacement in the $ \left\langle {0 10} \right\rangle $ direction and along the (001) plane. In areas of high finite strain, recrystallization of plagioclase dominantly occurred by bulging recrystallization and is intimately linked to the chemical zoning. The lack of CPO as well as the developed asymmetric zoning can be explained by the activity of grain boundary sliding accommodated by dissolution and precipitation creep (DPC). In low-strain domains, grain size is on average larger and the rim distribution is not related to the inferred stress axes indicating chemically induced grain replacement instead of stress-related DPC. We suggest that during deformation, in high-strain areas, pre-existing phase mixture and stress induced DPC-caused grain rotations that allowed a deformation-enhanced heterogeneous fluid influx. This resulted in local plagioclase replacement through interface-coupled dissolution and precipitation and chemically induced grain boundary migration, accompanied by bulging recrystallization, along with neocrystallization of other phases. This study illustrates a strong interaction and feedback between physical and chemical processes where the amount of stress and fluids dictates the dominant active process. The interaction is a cause of deformation and external fluid infiltration with a result of strain localization and chemical re-equilibration at amphibolite facies conditions.     

Pink manganian phengite in a high P/T meta-conglomerate from northern Syros (Cyclades, Greece)

A new occurrence of Mn-rich rocks was discovered within the high-pressure/low-temperature metamorphic rocks on the Palos peninsula of Syros (Greece). Near the summit of Mount Príonas, a meta-conglomerate consists of calcite (~63 wt%), pink manganian phengite, blue–purple manganian aegirine–jadeite, microcline, albite and quartz. In addition, it contains abundant braunite-rich aggregates (up to ~1.5 cm in diameter) that include hollandite [(Ba_0.98–1.02K_<0.01Na_<0.02Ca_<0.03) (Mn _1.02–1.52 ³⁺ Fe _0.38–0.88 ³⁺ Ti_0.29–0.92Mn _5.11–5.76 ⁴⁺ )O₁₆], barite and manganian hematite. Due to metamorphic recrystallization and deformation, the contacts between clasts and matrix are blurred and most clasts have lost their identity. In back-scattered electron images, many aegirine–jadeite grains appear patchy and show variable jadeite contents (Jd_10–67). These pyroxenes occur in contact with either quartz or albite. Manganian phengite (3.41–3.49 Si per 11 oxygen anions) is of the 3T type and contains 1.4–2.2 wt% of Mn₂O₃. At the known P–T conditions of high-pressure metamorphism on Syros (~1.4 GPa/ 470 °C), the mineral sub-assemblage braunite + quartz + calcite (former aragonite) suggests high oxygen fugacities relative to the HM buffer (+7 ≤ ?f_O2 ≤ + 17) and relatively high CO₂ fugacities. The exact origin of the conglomerate is not known, but it is assumed that the Fe–Mn-rich and the calcite-rich particles originated from different sources. Braunite has rather low contents of Cu (~0.19 wt%) and the concentrations of Co, Ni and Zn are less than 0.09 wt%. Hollandite shows even lower concentrations of these elements. Furthermore, the bulk-rock compositions of two samples are characterized by low contents of Cu, Co and Ni, suggesting a hydrothermal origin of the manganese ore. Most likely, these Fe–Mn–Si oxyhydroxide deposits consisted of ferrihydrite, todorokite, birnessite, amorphous silica (opal-A) and nontronite. Al/(Al + Fe + Mn) ratios of 0.355 and 0.600 suggest the presence of an aluminosilicate detrital component.     

The role of fire on soil mounds and surface roughness in the Mojave Desert

A fundamental question in arid land management centers on understanding the long‐term effects of fire on desert ecosystems. To assess the effects of fire on surface topography, soil roughness, and vegetation, we used terrestrial (ground‐based) LiDAR to quantify the differences between burned and unburned surfaces by creating a series of high‐resolution vegetation structure and bare‐earth surface models for six sample plots in the Grand Canyon‐Parashant National Monument, Arizona. We find that 11 years following prescribed burns, mound volumes, plant heights, and soil‐surface roughness were significantly lower on burned relative to unburned plots. Results also suggest a linkage between vegetation and soil mounds, either through accretion or erosion mechanisms such as wind and/or water erosion. The biogeomorphic implications of fire‐induced changes are significant. Reduced plant cover and altered soil surfaces from fire likely influence seed residence times, inhibit seed germination and plant establishment, and affect other ecohydrological processes. Published in 2012. This article is a US Government work and is in the public domain in the USA.     

New method for estimating reference evapotranspiration and comparison with alternative methods in a fruit-producing hub in the semi-arid region of Brazil

Theoretical and Applied Climatology - Analysing alternative methods for estimating reference evapotranspiration (ET0) is essential for improving the management of water resources, especially where...     

Paleoclimatic and archeological implications of Pleistocene and Holocene environments in Azraq, Jordan

Wetlands are a key archive for paleoclimatic and archeological work, particularly in arid regions, as they provide a focus for human occupation and preserve environmental information. The sedimentary record from 'Ayn Qasiyya, a spring site on the edge of the Azraq Qa, provides a well-dated sequence through the last glacial–interglacial transition (LGIT) allowing environmental changes in the present-day Jordanian desert to be investigated robustly through this time period for the first time. Results show that the wettest period at the site preceded the last glacial maximum, which itself was characterised by marsh formation and a significant Early Epipaleolithic occupation. A sedimentary hiatus between 16 and 10.5 ka suggests a period of drought in the region although seasonal rains and surface waters still allowed seasonal occupation of the Azraq region. Archeological evidence suggests that conditions had improved by the Late Epipaleolithic, about the time of the North Atlantic Younger Dryas. The changes between wet and dry conditions at the site show similarities to patterns in the eastern Mediterranean and in Arabia suggesting the Jordan interior was influenced by changes in both these regions through the LGIT climatic transition.     

Aram Chaos and its constraints on the surface heat flux of Mars

The surface heat flux of a planet is an important parameter to characterize its internal activity and to determine its thermal evolution. Here we report on a new method to constrain the surface heat flux of Mars during the Hesperian. For this, we explore the consequences for the martian surface heat flux from a recently presented new hypothesis for the formation of Aram Chaos (Zegers, T.E., Oosthoek, J.H.P., Rossi, A.P., Blom, J.K., Schumacher, S. [2010]. Earth Planet. Sci. Lett. 297, 496-504. doi:10.1016/j.epsl.2010.06.049.). In this hypothesis the chaotic terrain is thought to have formed by melting of a buried ice sheet. The slow sedimentation and burial of the ice sheet led to an increased thermal insulation of the ice and subsequently to a temperature increase high enough to trigger melting and the formation of the subsurface lake. As these processes highly depend on the thermal properties of the subsurface and especially on the surface heat flux, it is possible to constrain the latter by using numerical simulations. Based on the hypothesis for the formation of Aram Chaos, we conducted an extensive parameter study to determine the parameter settings leading to sufficient melting of the buried ice sheet. We find that the surface heat flux in the Aram Chaos region during the Hesperian was most likely between 20 and 45 mW m⁻² with a possible maximum value of up to 60 mW m⁻².