Spectroscopic analysis of the nuclear and circumnuclear regions of the Seyfert 2 galaxy NGC 7130

We discuss here the spectroscopic properties of the Seyfert 2 galaxy NGC 7130 (= IC 5135). Emission line regions were isolated and line ratios were measured and fitted with photoionization models; this allowed to discriminate between thermal and non thermal ionization in the circumnuclear regions. Massive star formation is likely to occur at projected distances from the nucleus ≫ 2 kpc: line profiles in these regions suggest the presence of outflows of gas due to stellar winds from hot massive stars.     

Abundance and size distribution of transparent exopolymer particles (TEP) in a coccolithophorid bloom in the northern Bay of Biscay

The distribution of transparent exopolymer particles (TEP) was investigated during a coccolithophorid bloom in the northern Bay of Biscay (North Atlantic Ocean) in early June 2006. MODIS chlorophyll-a (Chl-a) and reflectance images before and during the cruise were used to localize areas of important biological activity and high reflectance (HR). TEP profiles along the continental margin, determined using microscopic (TEP_micro) and colorimetric (TEP_color) methods, showed abundant (6.1×10⁶–4.4×10⁷ L^?1) and relatively small (0.5–20 μm) particles, leading to a low total volume fraction (0.05–2.2 ppm) of TEP_micro and similar vertical profiles of TEP_color. Estimates of carbon content in TEP (TEP-C) derived from the microscopic approach yielded surface concentration of 1.50 μmol C L^?1. The contribution of TEP-C to particulate organic carbon (POC) was estimated to be 12% (molar C ratio) during this survey. Our results suggest that TEP formation is a probable first step to rapid and efficient export of C during declining coccolithophorid blooms.     

Catastrophic rockslide-debris avalanche at St. Bernard, Southern Leyte, Philippines

On 17 February 2006, a rockslide-debris avalanche cascaded down the steep slope of Mt. Can-abag, burying the entire village of Guinsaugon in St. Bernard, Southern Leyte, Philippines. Casualties include 139 dead with 980 still missing and presumed dead, making it perhaps the most catastrophic landslide in Philippine history. The landslide started at the ridge top along a fault plane associated with the active Philippine Fault Zone. It started as a block slide that transformed into an avalanche. The entire event lasted for only a few minutes. Estimated maximum landslide velocity is 120–130 m/s. The landslide left behind a deep, wedge-shaped scarp. The central part of the deposit exhibits a hummocky topography typical of avalanches, in contrast to the flatter surface of the debris-flow-type marginal deposit. High amounts of soil in the matrix were derived from the scouring of ancient landslide deposits and rice fields in the valley. The landslide has a total area of 3.2 km² and a runout distance of 4.1 km. Estimated volume of debris is approximately 20 Mm³. At least four streams were dammed by the landslide debris. Intense precipitation and earthquakes preceding the landslide are the potential triggers. Preliminary back analyses assuming a planar and wedge slip surface yielded very low factors of safety even under dry conditions. A more rigorous analysis of the failure mechanism of the landslide is needed.     

Die Feldspate des Granites von Eisenkappel (Kärnten) und seines Randporphyres

Zusammenfassung Der Eisenkappeler Granit und sein Randporphyr wurden mineralogisch und petrographisch untersucht. Der Randporphyr und auch Übergangszonen zum Kerngranit zeigen eine Ummantelung der Alkalifeldspate mit Plagioklas-Rapakivi Textur. Genaue analytische Untersuchungen an, Alkalifeldspateinkristallen und den dazugehörigen Plagioklashüllen (bzw. den in unmittelbarer Nachbarschaft befindlichen Plagioklasen bei Proben des Kerngranits) ergaben folgende Einzelheiten: Die Alkalifeldspate sind Mikroklinperthite mit einer durchschnittlichen Triklinität von =0,50. Der Ab-Gehalt ist hoch (Kerngranit um Ab=31%, Randporphyr um Ab=38%), ebenso der An-Gehalt (durchschnittlich 3,5%). Die Plagioklase sind Oligoklase (Kerngranit um An=28%, Randporphyr um An=22%) mit einem extrem hohen Or-Gehalt (Or=4,2% bis 7,0%) und teilweise antiperthitisch entmischt. Die Zusammensetzung der Feldspate läßt auf relativ hohe Bildungstemperaturen und entsprechend niedrige Wasserdampfdrucke schließen. Die Untersuchungsergebnisse und die Entstehung der Rapakivi Textur werden diskutiert.

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Summary The granite of Eisenkappel and its marginal porphyry (Carinthia) have been investigated. The latter as well as gradations toward the central granite have alkalifeldspars manteled with plagioclase (rapakivi texture). The phenocrysts of the alkalifeldspars and their plagioclase rims and the phenocrysts of alkalifeldspar and neighbouring plagioclases in case of the central granite show the following attitudes: The alkalifeldspar are microcline perthites with an abliquity =0,50; From the central granite to the marginal porphyry the Abcontent of the alkalifeldspar increases from Ab=31–38 wight percent. The An-content is 3,5%. The An-content of the plagioclase drops in the same direction (An=28–22%). They exhibit a high Or-content (Or=4,2–7%) which is partly unmixed to antiperthite. The composition of the feldspars reflects a rather high temperature of formation and corresponding low water vapor pressure. The results and the origin of the rapakivi texture are discussed.

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Mit 6 Textabbildungen

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Herrn Prof. Dr.H. Leitmeier zum 80. Geburistag gewidmet.     

Wave-trains in the solar wind

Applying an Alfvén-Wave-Extended-QRH-approximation and the method of characteristics, we solve the equations of motion for outwardly propagating Alfvén waves analytically for three different cases of an azimuthal dependence of the background solar wind, (a) for a pure fast-slow stream configuration, (b) for the situation where the high-speed stream originates from a diverging magnetic field region, and (c) for the case of (b) and an initially decreasing density configuration (‘coronal hole’). The reaction of these waves on the background state as well as mode-mode coupling effects are neglected. These three solar wind models are discussed shortly. For the superimposed Alfvén waves we find, on an average, that there is a strong azimuthal dependence of all relevant wave parameters which, correlated with the azimuthal distributions of the solar wind variables, leads to good agreements with observations. The signature of high-speed streams and these correlations could clearly indicate solar wind streams originating from ‘coronal holes’. Contrary to the purely radial dependent solar wind, where outwardly propagating Alfvén waves are exclusively refracted towards the radial direction, we now find a refraction nearly perpendicular to the direction of the interplanetary magnetic field in the compression region and closely towards the magnetic field direction down the trailing edge and in the low-speed regime.     

Medium and short-term channel planform changes on the Rivers Tay and Tummel, Scotland

Channel planform change was analysed using a variety of data-sources for the medium-term (>25 years and <250 years) and short-term (<25 years) on a reach of the Rivers Tay and Tummel, Scotland. Map data were input into a Geographic Information System (GIS) and used to determine planform characteristics and changes in width, braiding index and sinuosity for the study reach between 1755 and 1976. Aerial photographs were utilised to determine the more recent changes that had taken place between 1971 and 1994. The analysis showed that significant changes had occurred over the medium term with a mean reduction in channel width of 34% for this period. These changes are comparable to those found in studies of similar European rivers for this period. Changes determined for the short-term displayed a continuance of this trend at a comparable rate of change. An analysis of flood frequency and magnitude, precipitation and discharge records for both periods does not show an associated decrease and therefore does not reflect the changes in channel planform. Evidence points towards flood embankment construction in the mid-1800s as the initial cause of channel change for the study reach which was later exacerbated by flow regulation. Incision and the subsequent stabilisation of lateral and mid-channel gravel bars by vegetation succession has resulted in an overall increase in the stability of the study reach which has persisted even where the embankments have fallen into disrepair.     

Microstructurally controlled trace element (Zr,U–Pb) concentrations in metamorphic rutile: An example from the amphibolites of the Bergen Arcs

As a common constituent of metamorphic assemblages, rutile provides constraints on the timing and conditions of rock transformation at high resolution. However, very little is known about the links between trace element mobility and rutile microstructures that result from synmetamorphic deformation. To address this issue, here we combine in situ LA-ICP-MS and sensitive high-resolution ion microprobe trace element data with electron back-scatter diffraction microstructural analyses to investigate the links between rutile lattice distortions and Zr and U–Pb systematics. Furthermore, we apply this integrated approach to constrain further the temperature and timing of amphibolite facies metamorphism and deformation in the Bergen Arcs of southwestern Norway. In outcrop, the formation of porphyroblastic rutile in dynamically hydrated leucocratic domains of otherwise rutile-poor statically hydrated amphibolite provides key contextual information on both the ambient conditions of hydration and deformation and the composition of the reactive fluid. Rutile in amphibolite recorded ambient metamorphic temperatures of ~590–730°C during static hydration of the granulitic precursor. By contrast, rutile from leucocratic domains in the directly adjacent shear zone indicates that deformation was accompanied by a localized increase in temperature. These higher temperatures are recorded in strain-free rutile (~600–860°C) and by Zr concentration measurements on low-angle boundaries and shear bands (620–820°C). In addition, we also observe slight depletions of Zr and U along rutile low-angle boundaries relative to strain-free areas in deformed grains from the shear zone. This indicates that crystal–plastic deformation facilitated the compositional re-equilibration of rutile upon cooling to slightly below the peak temperature of deformation. Cessation of deformation at mid-crustal conditions near ~600°C is recorded by late stage growth of small (<150 µm) rutile in the high-strain zones. U–Pb age data obtained from the strain-free and distorted rutile grains cluster in distinct populations of 437.4 ± 2.7 Ma and c. 405–410 Ma, respectively. These different ages are interpreted to reflect the difference in closure for thermally induced Pb diffusion between undeformed and deformed rutile during post-deformation exhumation and cooling. Thus, our results provide a reconstruction of the thermochronological history of the amphibolite facies rocks of the Lindås Nappe and highlight the importance of integration of microstructural data during application of thermometers and geochronometers.     

Assessment of climate change impacts on the hydrology of the Peruvian Amazon–Andes basin

In this article, we propose an investigation of the modifications of the hydrological response of two Peruvian Amazonas–Andes basins in relationship with the modifications of the precipitation and evapotranspiration rates inferred by the IPCC. These two basins integrate around 10% of the total area of the Amazonian basin. These estimations are based on the application of two monthly hydrological models, GR2M and MWB3, and the climatic projections come from BCM2, CSMK3 and MIHR models for A1B and B1 emission scenarios (SCE A1B and SCE B1). Projections are approximated by two simple scenarios (anomalies and horizon) and annual rainfall rates, evapotranspiration rates and discharge were estimated for the 2020s (2008–2040), 2050s (2041–2070) and 2080s (2071–2099). Annual discharge shows increasing trend over Requena basin (Ucayali river), Puerto Inca basin (Pachitea river), Tambo basin (Tambo river) and Mejorada basin (Mantaro river) while discharge shows decreasing trend over the Chazuta basin (Huallaga river), the Maldonadillo basin (Urubamba river) and the Pisac basin (Vilcanota river). Monthly discharge at the outlet of Puerto Inca, Tambo and Mejorada basins shows increasing trends for all seasons. Trends to decrease are estimated in autumn discharge over the Requena basin and spring discharge over Pisac basin as well as summer and autumn discharges over both the Chazuta and the Maldonadillo basins. Copyright © 2011 John Wiley & Sons, Ltd.     

Ab initio calculations of 6‐ and 7‐carbon meteoritic amino acids and their diastereomers

Abstract– To better explain the unusual distribution and relative abundances of several 6‐ and 7‐carbon amino acids found in meteorites, their thermodynamic properties were studied using accurate ab initio techniques. In addition to optimized structures and relative energies, vibrational frequency and thermochemical analysis of different diastereomers were performed at temperatures relevant to conditions of synthesis of these amino acids in meteorites. The results of calculations were compared with the measured content of the amino acids in the Murchison meteorite. The distribution of several longer chain amino acids in meteorites seems to point to at least some thermodynamic control in their formation. For diastereomeric compounds, on the other hand, the comparison suggests that their synthetic conditions, or those of their precursors, were far from thermodynamic equilibrium.     

An Evaluation of the Effects of Primary and Cross‐Contamination during the Preparation of Rock Powders for Chemical Determinations

Quartz crystals from the Batatal site, Minas Gerais, southern Brazil, were used to determine quantitatively primary contamination when submitting the samples to milling processes. Crushing devices used were a primary steel jaw crusher (br1), a secondary tungsten carbide (WC) crusher (br2) and a hydraulic press with stainless steel plates (pr). Fragments with suitable sizes were then ground in different Fritsch planetary mills, equipped with agate, WC and chromium‐steel rings for 7, 4 and 3 min, respectively. Solutions of the powders were analysed initially with the TotalQuant^? method in a quadrupole ICP‐MS instrument, providing semi‐quantitative results for seventy‐five elements. Contamination from crushers and mills was visible in major and minor elements such as Fe, Mn and Ti, and noticeable in trace elements such as Cr, Co, Ni, Cu and also V, Zr, Sc; significant contamination was observed from W, Mo, Co, Ta and Nb (mainly by use of the WC devices). Little or no contamination was observed for Pb, REE, Sr and Rb, elements that are important in routine isotopic determinations. Cross‐contamination was tested by grinding either a granite or a basalt sample, followed by conventional cleaning with mica‐free quartz sand, before the working quartz powder was prepared.