Integer ambiguity validation: an open problem?

The problem of integer estimation has drawn a lot of attention in the past decade, and is now often considered solved. However, a parameter resolution theory cannot be considered complete without rigorous measures for validating the parameter solution.     

Cambrian granitoids in pre-Alpine basement of Crete (Greece): evidence from U-Pb dating of zircon

The pre-Alpine basement of eastern Crete consists of at least three sub complexes which show differences in age and grade of pre-Alpine metamorphism. U-Pb analyses of zircons of two orthogneisses yielded upper intercepts in the concordia diagram at 511±16 Ma (Chamezí crystalline complex) and 514±14 Ma (Myrsini crystalline complex). These values are interpreted as protolith ages of the gneisses, suggesting that parts of the basement underwent Cadomian (Pan-African) imprints at the northern margin of Gondwana. The lower intercept ages are attributed to Alpine subduction which led to high-pressure/low-temperature metamorphism (T=ca. 300 °C), brittle-ductile deformation, and hydrothermal fluid activity. Due to pervasive Alpine fluid migration, the zircons of the Chamezí crystalline complex display disturbed zonation and solution, resulting in 87% radiogenic Pb loss, Ca- and Al-gain, and Zr depletion.     

The distribution of chiral asymmetry in meteorites: An investigation using asymmetric autocatalytic chiral sensors

We separated and analyzed several organic and inorganic phases of the carbonaceous chondrite matrix to determine whether they contained any inherent asymmetry. Our intent was to determine any possible foci of asymmetry besides the one determined for meteoritic amino acids. As a probe, we employed a very sensitive asymmetric autocatalytic reaction. We were able to determine that asymmetry still resides in powders after extraction with water and solvents as well as in the insoluble organic material (IOM) obtained after demineralization. Asymmetry is not found any longer in the IOM after hydrothermal treatment and in meteorite powders from which all organics had been removed by O₂ plasma at low temperature. The data are interpreted to indicate a diverse molecular asymmetry residing in yet unknown meteorite organics; these organics might have had an inductive effect on organic molecular evolution upon exogenous delivery to the early Earth.     

Massive barite deposits and carbonate mineralization in the Derugin Basin, Sea of Okhotsk: precipitation processes at cold seep sites

An area of massive barite precipitations was studied at a tectonic horst in 1500 m water depth in the Derugin Basin, Sea of Okhotsk. Seafloor observations and dredge samples showed irregular, block- to column-shaped barite build-ups up to 10 m high which were scattered over the seafloor along an observation track 3.5 km long. High methane concentrations in the water column show that methane expulsion and probably carbonate precipitation is a recently active process. Small fields of chemoautotrophic clams (Calyptogena sp., Acharax sp.) at the seafloor provide additional evidence for active fluid venting. The white to yellow barites show a very porous and often layered internal fabric, and are typically covered by dark-brown Mn-rich sediment; electron microprobe spectroscopy measurements of barite sub-samples show a Ba substitution of up to 10.5 mol% of Sr. Rare idiomorphic pyrite crystals (∼1%) in the barite fabric imply the presence of H₂S. This was confirmed by clusters of living chemoautotrophic tube worms (1 mm in diameter) found in pores and channels within the barite. Microscopic examination showed that micritic aragonite and Mg-calcite aggregates or crusts are common authigenic precipitations within the barite fabric. Equivalent micritic carbonates and barite carbonate cemented worm tubes were recovered from sediment cores taken in the vicinity of the barite build-up area. Negative δ¹³C values of these carbonates (>−43.5‰ PDB) indicate methane as major carbon source; δ¹⁸O values between 4.04 and 5.88‰ PDB correspond to formation temperatures, which are certainly below 5°C. One core also contained shells of Calyptogena sp. at different core depths with ¹⁴C-ages ranging from 20?680 to >49?080 yr. Pore water analyses revealed that fluids also contain high amounts of Ba; they also show decreasing SO₄^2- concentrations and a parallel increase of H₂S with depth. Additionally, S and O isotope data of barite sulfate (δ³⁴S: 21.0-38.6‰ CDT; δ¹⁸O: 9.0-17.6‰ SMOW) strongly point to biological sulfate reduction processes. The isotope ranges of both S and O can be exclusively explained as the result of a mixture of residual sulfate after a biological sulfate reduction and isotopic fractionation with ‘normal’ seawater sulfate. While massive barite deposits are commonly assumed to be of hydrothermal origin, the assemblage of cheomautotrophic clams, methane-derived carbonates, and non-thermally equilibrated barite sulfate strongly implies that these barites have formed at ambient bottom water temperatures and form the features of a Giant Cold Seep setting that has been active for at least 49?000 yr.     

Geotechnical engineering practice for collapsible soils

Conditions in arid and semi-arid climates favor the formation of the most problematic collapsible soils. The mechanisms that account for almost all naturally occurring collapsible soil deposits are debris flows, rapid alluvial depositions, and wind-blown deposits (loess). Collapsible soils are moisture sensitive in that increase in moisture content is the primary triggering mechanism for the volume reduction of these soils. One result of urbanization in arid regions is an increase in soil moisture content. Therefore, the impact of development-induced changes in surface and groundwater regimes on the engineering performance of moisture sensitive arid soils, including collapsible soils, becomes a critical issue for continued sustainable population expansion into arid regions.In practicing collapsible soils engineering, geotechnical engineers are faced with (1) identification and characterization of collapsible soil sites, (2) estimation of the extent and degree of wetting, (3) estimation of collapse strains and collapse settlements, and (4) selection of design/mitigation alternatives. Estimation of the extent and degree of wetting is the most difficult of these tasks, followed by selection of the best mitigation alternative.     

Numerical Analysis of Space–Time Finite Element Formulations for Miscible Displacements

A finite element formulation is proposed to approximate a nonlinear system of partial differential equations, composed by an elliptic subsystem for the pressure–velocity and a transport equation (convection–diffusion) for the concentration, which models the incompressible miscible displacement of one fluid by another in a rigid porous media. The pressure is approximated by the classical Galerkin method and the velocity is calculated by a post-processing technique. Then, the concentration is obtained by a Galerkin/least-squares space–time (GLS/ST) finite element method. A numerical analysis is developed for the concentration approximation. Then, stability, convergence and numerical results are presented confirming the a priori error estimates.     

Tectonic significance of deformation patterns in granitoid rocks of the Menderes nappes, Anatolide belt, southwest Turkey

Deformation fabrics in Proterozoic/Cambrian granitic rocks of the Çine nappe, and mid-Triassic granites of the Bozdag nappe constrain aspects of the tectonometamorphic evolution of the Menderes nappes of southwest Turkey. Based on intrusive contacts and structural criteria, the Proterozoic/Cambrian granitic rocks of the Çine nappe are subdivided into older orthogneisses and younger metagranites. The deformation history of the granitic rocks documents two major deformation events. An early, pre-Alpine deformation event (D_PA) during amphibolite-facies metamorphism affected only the orthogneisses and produced predominantly top-to-NE shear-sense indicators associated with a NE-trending stretching lineation. The younger metagranites are deformed both by isolated shear zones, and by a major shear zone along the southern boundary of the Çine submassif. We refer to this Alpine deformation event as D_A3. D_A3 shear zones are associated with a N-trending stretching lineation, which formed during greenschist-facies metamorphism. Kinematic indicators associated with this stretching lineation reveal a top-to-south sense of shear. The greenschist-facies shear zones cut the amphibolite-facies structures in the orthogneisses. ²⁰⁷Pb/²⁰⁶Pb dating of magmatic zircons from a metagranite, which crosscuts orthogneiss containing amphibolite-facies top-to-NE shear-sense indicators, shows that D_PA occurred before 547.2ǃ.0 Ma. Such an age is corroborated by the observation that mid-Triassic granites of the Çine and Bozdag nappes lack D_PA structures. The younger, top-to-south fabrics formed most likely as a result of top-to-south Alpine nappe stacking during the collision of the Sakarya continent with Anatolia in the Eocene.     

Modelling metolachlor exports in subsurface drainage water from two structured soils under maize (eastern France)

The study investigated the processes involved in metolachlor transport in two artificially drained, structured soils in eastern France. Measured losses of bromide and metolachlor in drainage water were compared with results simulated by the mechanistic, stochastic AgriFlux model. Simulated drainage water volumes were generally similar to the measured volumes when the spatial variability of the soil water properties was taken into account. When such variability was disregarded, cumulative water volumes of the clay soil were over- or underestimated by more than 20%. Two types of adsorption were tested. For instantaneous, reversible adsorption, using the partition coefficient Koc, metolachlor losses were underestimated in the first drainage water volumes and overestimated for the total study period. The use of slow adsorption and desorption kinetics (ADK) produced an export pattern similar to the observed one. A sensitivity analysis indicated that the simulated results are very sensitive to the values of the ADK rates, especially for the silty loam soil. The effect of ADK on the attenuation of metolachlor exports was more significant than the effect of degradation (2.3 and 6.7 times higher for the clay and silty loam soils, respectively). For the same four-month period, the bromide and metolachlor losses (using ADK) in the clay soil were 2.1 and 1.3 times greater, respectively, if the macroporosity was set at 10% than if it was not simulated. Conversely, macroporosity did not significantly affect these losses in the silty loam. The main factors involved in the metolachlor transport in the studied soils were: (i) the macroporosity, especially in the clay soil because of the low hydraulic conductivity of the matrix and (ii) the sorption kinetics rates which varied according to the soil physico-chemical characteristics.     

Defining phases of bedload transport using piecewise regression

Differences in the transport rate and size of bedload exist for varying levels of flow in coarse‐grained channels. For gravel‐bed rivers, at least two phases of bedload transport, with notably differing qualities, have been described in the literature. Phase I consists primarily of sand and small gravel moving at relatively low rates over a stable channel surface. Transport rates during Phase II are considerably greater than Phase I and more coarse grains are moved, including material from both the channel surface and subsurface. Transition from Phase I to Phase II indicates initiation and transport of grains comprising the coarse surface layer common in steep mountain channels. While the existence of different phases of transport is generally acknowledged, the threshold between them is often poorly defined. We present the results of the application of a piecewise regression analysis to data on bedload transport collected at 12 gravel‐bed channels in Colorado and Wyoming, USA. The piecewise regression recognizes the existence of different linear relationships over different ranges of discharge. The inflection, where the fitted functions intersect, is interpreted as the point of transition from Phase I to Phase II transport; this is termed breakpoint. A comparison of grain sizes moved during the two phases shows that coarse gravel is rarely trapped in the samplers during Phase I transport, indicating negligible movement of grains in this size range. Gravel larger than about D₁₆ of the channel surface is more consistently trapped during Phase II transport. The persistence of coarse gravel in bedload samples provides good evidence that conditions suitable for coarse grain transport have been reached, even though the size of the sediment approaches the size limits of the sampler (76 mm in all cases). A relative breakpoint (R_br) was defined by the ratio between the discharge at the breakpoint and the 1·5‐year flow (a surrogate for bankfull discharge) expressed as a percentage. The median value of R_br was about 80 percent, suggesting that Phase II begins at about 80 percent of the bankfull discharge, though the observed values of R_br ranged from about 60 to 100 percent. Variation in this value appears to be independent of drainage area, median grain size, sorting of bed materials, and channel gradient, at least for the range of parameters measured in 12 gravel‐bed channels. Published in 2002 by John Wiley & Sons, Ltd.     

The distribution of macrozoobenthos in the southern North Sea in relation to meso-scale bedforms

This study investigates the distribution of macrozoobenthos in relation to meso-scale bedforms in the southern North Sea. Three sites on the Dutch Continental Shelf were sampled that are representative of large areas of the North Sea and show diverse morphological settings. These sites are (i) part of a shoreface-connected ridge, (ii) the lower part of a concave shoreface and (iii) a sandwave area. Within these sites, two or three different morphological units were distinguished. Sampling was undertaken in two seasons for two consecutive years. The species composition was analysed for differences in benthic assemblage within sites, based on the meso-scale morphology, and between sites and seasons. In addition, the benthic assemblage was correlated to water depth, median grain size (D50) and sorting (D60/D10). Results show that significant differences in the benthic assemblage can be found related to meso-scale bedforms, but macro-scale morphological setting and seasonal effects are more important.