Hydrogen isotope fractionation between OH-bearing minerals and water

Hydrogen isotope fractionation factors between hydroxyl-bearing minerals and water were determined at temperatures ranging between 400 and 850°C. The hydrogen isotope exchange rates for the mineral-water pairs examined were very slow. In most cases it was necessary to use an interpolation method for the determination of the hydrogen isotope equilibrium fractionation factor, α_e.For the temperature range of 450–850°C the hydrogen isotope fractionation factors for the mica-water and amphibole-water systems are simply expressed as a function of temperature and the molar fractions of the six-fold coordinated cations in the crystal, regardless of mineral species, as follows: 10³ In α_{e(mineral-water)} = ? 22.4 (10⁶T^?2) + 28.2 + (2X_Al ? 4X_Mg ? 68X_Fe), where X is the molar fraction of the cations. As the equation indicates, for any specific composition of the OH-bearing minerals, the change of α_e with temperature, over the temperature range investigated, is the same for all minerals studied. Thus for any specified values of X_Al, X_Mg, and X_Fe for these minerals, the relationship between α_e and T is 10³ In α_e = αT^?2 + k. Consequently, hydrogen isotope fractionation among coexisting minerals is temperature independent and cannot be used as a hydrogen isotope geothermometer.Some exceptions to the above general observations exist for minerals such as boehmite and kaolinite. In these minerals hydrogen bonding modifies the equilibrium hydrogen isotopic fractionation between mineral and water.     

Processes controlling precipitation of carbonate cement and dissolution of silica in reef and near-reef settings

Carbonate cementation in the surface layer of reefs and beachrock eliminates porosity and partially replaces detrital quartz grains. The uptake and release of CO₂ by photosynthesis and respiration in reef communities cause a shift in the carbonate buffer system of seawater. Field studies and experimentation simulating the natural settings show minimum values of CO₂ (1.9 mmoles 1^?1) and HCO₃^? (2.4 meq 1^?1) in association with maximum values of pH (9.8) and O₂ (> 100% oxygen saturation) in waters covering corals and algae prior to sunset. The converse is true for these variables prior to sunrise, when minimum values of pH (7.6) and O₂ (<66% oxygen saturation) occur with maximum values of CO₂ (2.7 mmoles 1^?1) and HCO₃^? (2.7 meq 1^?1). Experimental tanks containing plain seawater showed almost no diurnal variability in pH (a constant 7.5–7.6) or O₂ (80–90% oxygen saturation) measurements. Seawater adjacent to reef biomass, with elevated pH and supersaturated with calcium carbonate, is periodically pumped into the underlying reef and beach sediments due to pressure-buildups between the reef framework or algal zones and open waters. Carbonate precipitation and quartz dissolution follow. As the system equilibrates, pH values progressively decrease.     

Floods in the Sahel: an analysis of anomalies, memory, and anticipatory learning

This study explores the implications of recent extreme rainfall and flood events in the Sahel and the wider West African region for climate change adaptation. Are these events merely a temporal nuisance as suggested by the lingering desertification discourse or will more climatic extremes characterize the region over the next century? After reviewing incidences of severe rainfall and projected future climate variability, the paper examines local flood knowledge and decision-making, drawing upon a case study in Ghana. The data demonstrate that a variety of response strategies to flooding exist; yet, knowledge of and access to climate forecasts and other learning tools are essentially absent. So far, floods have not triggered mass displacement although cumulative environmental deterioration is likely to cause environmental refugees. The paper recommends to lay to rest the desertification narrative, consider the possibility of both floods and droughts, and mobilize local memory for anticipatory learning and practical adaptation.     

What drives policy change for REDD+? A qualitative comparative analysis of the interplay between institutional and policy arena factors

Reducing Emissions from Deforestation and forest Degradation (REDD+) has emerged as a promising climate change mitigation mechanism in developing countries. In order to identify the enabling conditions for achieving progress in the implementation of an effective, efficient and equitable REDD+, this paper examines national policy settings in a comparative analysis across 13 countries with a focus on both institutional context and the actual setting of the policy arena. The evaluation of REDD+ revealed that countries across Africa, Asia and Latin America are showing some progress, but some face backlashes in realizing the necessary transformational change to tackle deforestation and forest degradation. A Qualitative Comparative Analysis (QCA) undertaken as part of the research project showed two enabling institutional configurations facilitating progress: (1) the presence of already initiated policy change; and (2) scarcity of forest resources combined with an absence of any effective forestry framework and policies. When these were analysed alongside policy arena conditions, the paper finds that the presence of powerful transformational coalitions combined with strong ownership and leadership, and performance-based funding, can both work as a strong incentive for achieving REDD+ goals.

Key policy insights

• The positive push of already existing policy change, or the negative stress of resource scarcity together with lack of effective policies, represents institutional conditions that can support REDD+ progress.

• Progress also requires the presence of powerful transformational coalitions and strong ownership and leadership. In the absence of these internal drivers, performance-based funding can work as a strong incentive.

• When comparing three assessments (2012, 2014, 2016) of REDD+ enabling conditions, some progress in establishing processes of change can be observed over time; however, the overall fluctuation in progress of most countries reveals the difficulty in changing the deforestation trajectory away from business as usual.

     

Climate change, adaptation and economic growth

This paper explores the links between economic growth and the impacts of climate change. Inclusive, pro-poor growth is central to the development of low-income countries. There is also a broad consensus that growth and development are important to reduce vulnerability to climate change. Growth does not automatically reduce vulnerability, only the right kind of growth does. The paper aims to develop a better understanding of what the ??right kind of growth?? may be. We find that many growth policies, such as investment in skills and access to finance, indeed reduce vulnerability to climate change. However, climate change calls for some adjustments in growth policy. In particular, investment in infrastructure and efforts to stimulate entrepreneurship and competitive markets must take more of a risk management perspective and recognise climate risks.     

大气和植被生态及土壤系统水文过程相互作用的一些研究

利用我国测站的降水资料、卫星测得的OLR和高云量资料、SST和137°E次表层海温资料以及NCEP/NCAR再分析资料,分析了东亚夏季风的爆发和北进的年际变化特征及其与热带西太平洋热状态的关系.分析结果表明:当春季热带西太平洋处于暖状态,菲律宾周围对流活动强,在这种情况下,南海上空对流层下层有气旋性距平环流,西太平洋副热带高压偏东,从而使得南海夏季风爆发早;并且,当夏季热带西太平洋也处于暖状态,菲律宾周围对流活动也很强,在这种情况下,西太平洋副热带高压北进时,在6月中旬和7月初存在明显的突跳,从而使得东亚季风雨带在6月中旬明显由华南北跳到江淮流域,并于7月初由江淮流域北跳到黄河流域、华北和东北地区.这将引起江淮流域和长江中、下游夏季风降水偏少,并往往发生干旱,而黄河流域、华北和东北地区的夏季降水正常或偏多.相反,当春季热带西太平洋处于冷状态,菲律宾周围对流活动弱,在这种情况下,南海上空对流层下层有反气旋性距平环流,西太平洋副热带高压偏西,从而使得南海夏季风爆发晚;并且,当夏季热带西太平洋也处于冷状态,菲律宾周围对流活动也很弱,在这种情况下,西太平洋副热带高压北进时,在6月中旬或7月初向北突跳并不明显,而是以渐进式向北移动,从而使得东亚季风雨带一直维持在长江流域和淮河流域.这将引起此两流域夏季风降水偏多,并往往发生洪涝,而黄河流域、华北和东北地区的夏季降水偏少,发生干旱.作者还从非线性多平衡态动力理论说明了菲律宾周围对流活动强弱对西太平洋副热带高压北进时以突跳或渐进式向北移动起到重要作用.     

Evaluation of Density Corrections to Methane Fluxes Measured by Open-Path Eddy Covariance over Contrasting Landscapes

Corrections accounting for air density fluctuations due to heat and water vapour fluxes must be applied to the measurement of eddy-covariance fluxes when using open-path sensors. Experimental tests and ecosystem observations have demonstrated the important role density corrections play in accurately quantifying carbon dioxide \((\hbox {CO}_{2})\) fluxes, but less attention has been paid to evaluating these corrections for methane \((\hbox {CH}_{4})\) fluxes. We measured \(\hbox {CH}_{4}\) fluxes with open-path sensors over a suite of sites with contrasting \(\hbox {CH}_{4}\) emissions and energy partitioning, including a pavement airfield, two negligible-flux ecosystems (drained alfalfa and pasture), and two high-flux ecosystems (flooded wetland and rice). We found that density corrections successfully re-zeroed fluxes in negligible-flux sites; however, slight overcorrection was observed above pavement. The primary impact of density corrections varied over negligible- and high-flux ecosystems. For negligible-flux sites, corrections led to greater than 100% adjustment in daily budgets, while these adjustments were only 3–10% in high-flux ecosystems. The primary impact to high-flux ecosystems was a change in flux diel patterns, which may affect the evaluation of relationships between biophysical drivers and fluxes if correction bias exists. Additionally, accounting for density effects to high-frequency \(\hbox {CH}_{4}\) fluctuations led to large differences in observed \(\hbox {CH}_{4}\) flux cospectra above negligible-flux sites, demonstrating that similar adjustments should be made before interpreting \(\hbox {CH}_{4}\) cospectra for comparable ecosystems. These results give us confidence in \(\hbox {CH}_{4}\) fluxes measured by open-path sensors, and demonstrate that density corrections play an important role in adjusting flux budgets and diel patterns across a range of ecosystems.