Lunar baselines and libration from differential Vlbi observations of alseps

Differential very-long-baseline interferometric observations of signals from Apollo Lunar Surface Experiment Package telemetry transmitters will yield the relative projected positions of the transmitters with uncertainty of only 1-3 m, set mainly by uncertainty of the lunar ephemeris. Noise and systematic instrumental errors which in the past affected similar observations have been reduced to the equivalent of a few centimeters on the lunar surface by the development of a new type of differential receiver. Continued observations should yield a determination of the motion of the Moon about its center of mass with uncertainty less than 1 s of selenocentric arc. Improvements (by other means) in our knowledge of the Moon's orbital motion would allow a further order-of-magnitude refinement in the libration and relative position results obtainable by differential VLBI.Communication presented at the conference on Lunar Dynamics and Observational Coordinate Systems held January 15–17, 1973 at the Lunar Science Institute, Houston, Tex. U.S.A.     

Laboratory and field evaluation of a flushable oxic limestone drain for treatment of net-acidic drainage from a flooded anthracite mine, Pennsylvania, USA

This paper demonstrates the use of dissolution-rate data obtained in the laboratory to indicate the potential quality of effluent from a field-scale oxic limestone drain (OLD) treatment system for neutralization of dilute acidic mine drainage (AMD). Effluent from the Reevesdale Mine South Dip Tunnel, a large source of AMD and base flow to the Wabash Creek and Little Schuylkill River in the Southern Anthracite Coalfield of east-central Pennsylvania, is representative of AMD with low concentrations but high loadings of dissolved Fe, Al and other metals because of a high flow rate. In January 2003, rapid neutralization of the AMD from the Reevesdale Mine was achieved in laboratory tests of its reaction rate with crushed limestone in closed, collapsible containers (Cubitainers). The tests showed that net-alkaline effluent could be achieved with retention times greater than 3 h and that effluent alkalinities and associated dissolution rates were equivalent for Fe(OH)₃-coated and uncoated limestone. On the basis of the laboratory results, a flushable OLD containing 1450 metric tons of high-purity calcitic limestone followed by two 0.7-m deep wetlands were constructed at the Reevesdale Mine. During the first year of operation, monthly data at the inflow, outflow and intermediate points within the treatment system were collected (April 2006–2007). The inflow to the treatment system ranged from 6.8 to 27.4 L/s, with median pH of 4.7, net acidity of 9.1 mg/L CaCO₃, and concentrations of dissolved Al, Fe and Mn of 1.0, 1.9 and 0.89 mg/L, respectively. The corresponding effluent from the OLD had computed void-volume retention times of 4.5–18 h, with median pH of 6.6, net acidity of −93.2 mg/L CaCO₃, and concentrations of dissolved Al, Fe and Mn of <0.1, 0.08 and 0.52 mg/L, respectively. The wetlands below the OLD were effective for retaining metal-rich solids flushed at monthly or more frequent intervals from the OLD, but otherwise had little effect on the effluent quality. During the first year of operation, approximately 43 metric tons of limestone were dissolved and 2 metric tons of Al, Fe and Mn were precipitated within the OLD. However, because of the accumulation of these metals within the OLD and possibly other debris from the mine, the effectiveness of the treatment system declined. Despite the installation of a flush-pipe network at the base of the OLD to remove precipitated solids, the limestone bed clogged near the inflow. Consequently, a large fraction of the AMD bypassed the treatment system. To promote flow through the OLD, the flush pipes were open continuously during the last 4 months of the study; however, this effluent was only partially treated because short-circuiting through the pipes decreased contact between the effluent and limestone. A reconfiguration of the flow path through the limestone bed from horizontal to vertical upward could increase the limestone surface area exposed to the metal-laden influent, increase the cross-sectional area perpendicular to flow, decrease the flow path for solids removal, and, consequently, decrease potential for clogging.     

Tectonics and volcanism along the Pacific Marginal Zone of Central America

The relation of volcanism to tectonics in the Central American region has been established by a review of the literature as well as by field and photogeological work of the authors. The association of a deep trench off the Pacific coast, a parallel seismic belt, and a similarly oriented chain of volcanic vents farther inland, has been recognized by numerous earlier workers. These features form a tectonic unit, and are here termed the Pacific marginal zone.Seismic foci on the northeastern edge of the southern part of the Middle American Trench define a fault zone which dips under the continent and suggests movement of the oceanic plate underneath the Central American continent.An impressive chain of volcanic cones and associated shallow seismic foci is aligned along a prominent graben, best developed in Nicaragua where it is known as the Nicaraguan Depression. This feature probably originated in late Tertiary time. The southeastern end of the graben terminates at the northern ranges of the Talamanca Cordillera in Costa Rica. At the Gulf of Fonseca the trend of the graben changes from NW to E-W; the graben continues as the Central Depression of El Salvador at a higher elevation. Only the fault of the seaward border of the graben is defined in Guatemala, where it is represented by a NW trending volcanic chain.In Nicaragua and El Salvador the oldest cones are situated on the north-eastern boundary fault zone of the graben. These include remnants of the largest volcanic structures of the region. All the active volcanoes are on the southwestern boundary fault belt. Cross fracturing of this fault system controlled later northerly trending cone alignments, often with the youngest cones on the south end.The main graben and associated faults are considered results of tensional stresses on the crest of geanticlinal arching on the landward side of the Middle American Trench. This arching is believed to be due to regional compression originated by the movement of the oceanic plate against the mainland.In northwestern Central America the youngest stresses produced N-S normal faults that are marked by well-defined scarps. These stresses may be the result of right-lateral motion along the underthrust fault zone. The complex Comayagua graben north of the Gulf of Fonseca, the Ipala graben and associated faults in southeastern Guatemala, and the Guatemala City graben are all north-south features illustrating the extent and youth of this structural trend.The distribution of volcanic vents along the Nicaraguan Depression and the N-S trends underscores the close tectonic control of volcanism.

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Zusammenfassung Der Zusammenhang zwischen Tektonik und Vulkanismus im mittelamerikanischen Raum wird aufgezeigt aufgrund einer Literaturdurchsicht und feldgeologischer Arbeiten der Verfasser. Die Beziehungen zwischen einem Tiefseegraben vor der pazifischen Küste, einem dem Festland parallelen seismischen Gürtel und einer ebenso orientierten Vulkankette weiter im Inland sind von früheren Bearbeitern bereits erkannt worden. Diese drei Einheiten werden hier zusammengefaßt und als pazifische Randzone bezeichnet.Erdbebenherde am Nordostrand des mittelamerikanischen Tiefseegrabens weisen auf eine Störungszone hin, die unter den Kontinent einfällt. Der Bewegungssinn spricht für ein Abtauchen der ozeanischen Platte unter das mittelamerikanische Festland.Eine eindrucksvolle Vulkankette und die mit ihr verbundenen Erdbebenherde sind längs eines bedeutenden Grabens aufgereiht, der in Nicaragua am deutlichsten ausgebildet ist und dort Nicaragua-Senke genannt wird. Diese tektonische Einheit entstand wahrscheinlich im Jung-Tertiär. Der Graben beginnt im Südosten an den nördlichen Ausläufern der Talamanca-Kordillere in Costa Rica.In Nicaragua verläuft er NW. Am Golf von Fonseca schwenkt er in eine E-W-Richtung und setzt sich in El Salvador in einem höheren Niveau als Zentral-Depression fort. In Guatemala ist nur der Südrand des Grabens erkennbar. Er ist gekennzeichnet durch eine in NW-Richtung aufgereihte Vulkankette. In Nicaragua und El Salvador liegen die ältesten Vulkane auf dem nordöstlichen Grenzbruch des Grabens. Zu dieser Gruppe zählen die größten Rumpfvulkane. Die meisten Kegel und alle tätigen Vulkane liegen hingegen auf dem südwestlichen Grenzbruchstreifen. Auf Querbrüchen haben sich jüngere, nördlich ausgerichtete Kegelreihen gebildet. Die jüngsten Kegel liegen meistens am südlichen Ende der Querbrüche.Es wird angenommen, daß der Hauptgraben und seine Störungen im Scheitel einer zum mittelamerikanischen Tiefseegraben parallel verlaufenden Aufwölbung entstanden sind. Die Aufwölbung kann auf Kompression der ozeanischen Platte gegen das Festland zurückgeführt werden.Im nordwestlichen Zentralamerika bewirkten jüngere Beanspruchungen die Bildung von N-S-Brüchen, die heute morphologisch als Steilkanten hervortreten. Diese Beanspruchungen können durch rechtslaterale Bewegungen entlang der pazifischen Störungszone ausgelöst worden sein. Beispiele dieser N-S-Struktur sind: Die Comayagua-Grabenzone, nördlich des Golfs von Fonseca, der Ipala-Graben und sein Störungssystem in Südost-Guatemala und der Guatemala-Stadt-Graben. Diese N-S-Störungen kennzeichnen das Ausmaß und das geringe Alter der Grabenbildung.Die Anordnung der Vulkane entlang der Nicaragua-Senke und der N-S-Brüche stellen die engen Beziehungen zwischen Tektonik und Vulkanismus in der pazifischen Randzone Mittelamerikas heraus.

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Resumen Mediante información tomada de la literatura, trabajos de campo e interpretation fotogeológica, se establece la relación entre el volcanismo y la tectónica en la región de América Central. Se usa la denominación de zona marginal del Pacífico para identificar, como una unidad, la asociación ya reconocida por otros autores de la profunda Fosa Mesoamericana frente a la costa del Pacífico de America Central y las franjas paralelas de actividad sísmica y de cadenas volcánicas.Los focos sísmicos en el borde nororiental de la Fosa Mesoamericana definen una gran zona de afallamiento inclinada hacia el continente, cuyos movimientos indican que un bloque de la corteza oceánica se sumerge bajo la porción continental de America Central.Una imponente serie de conos volcánicos, asociada a focos sísmicos poco profundos, está situada a lo largo de un gran graben conocido como Depresión de Nicaragua, por ser en ese país donde aparece más claramente definido. Este graben, que posiblemente se originó durante el Terciario tardío, termina en su extremo suroriental contra las estribaciones de la parte norte de la Cordillera de Talamanca, en Costa Rica. En Nicaragua el graben está orientado hacia el NW hasta el Golfo de Fonseca donde toma un rumbo E-W a través de El Salvador, donde se encuentra a mayor elevación. En Guatemala se conoce únicamente una línea de fallas, la más próxima al mar, definida por una cadena de volcanes que tiene nuevamente dirección NW.En Nicaragua y El Salvador los conos volcánicos más antiguos están situados a lo largo de las fallas que limitan al graben en su lado nororiental. Allí se encuentran las ruinas de los edificos volcánicos más grandes de la región. La mayoría de los conos que incluye todos los actualmente activos, se localizan a lo largo de las fallas del borde suroccidental del graben. Fracturas transversales controlan la localization de varios grupos de conos alineados de N-S. Los volcanes más jóvenes se encuentran frecuentemente en el extremo sur.Se postula que el graben principal y otras fallas del mismo sistema han sido formados como resultado de esfuerzos de tensión, en la cresta de un geanticlinal que resultó del arqueamiento del lado terrestre de la zona marginal del Pacífico. Dicho arqueamiento se cree que resulta de la compresión regional debida al movimiento del bloque oceánico contra el continente.En la parte noroccidental de América Central los esfuerzos más recientes produjeron fallas orientadas N-S, fácilmente identificables por sus bien marcadas escarpas. Estos esfuerzos pueden haber resultado del desplazamiento dextromóvil a lo largo de las zonas de afallamiento paralelas a la Fosa Mesoamericana.El complejo graben de Comayagua, al norte del Golfo de Fonseca, y los graben de Ipala y de la Ciudad de Guatemala, orientados también de norte a sur, ilustran la extension y la joven edad de las fracturas.La distribución de los focos volcánicos a lo largo de la Depresión de Nicaragua y de las fracturas N-S muestran de manera evidente, la estrecha relación que existe entre la tectónica y la localización del volcanismo en la zona marginal del Pacifico de America Central.

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, - . - , . . , , . , , - . - Talamanca Kordillere -. - - . Fanseca . . , , . - . . . , . . - N-S , . . : Comayagua, Fanseca, Ipala - . - . , .

     

Atmospheric noble gases in volcanic glasses from the southern Lau Basin: origin from the subducting slab?

Noble gas concentrations and isotopic compositions have been determined for four submarine volcanic glasses from the Valu Fa Ridge (VFR) in the southern Lau Basin. The samples are the least differentiated ones from this area, and they display enrichments in fluid-mobile elements similar to the nearby island arc. ³He/⁴He ratios are slightly below average MORB (6.8–7.8 times atmospheric), whereas Ne, Ar, Kr, and Xe have isotopic compositions very similar to air. Together with previously published data from the Valu Fa Ridge and other spreading segments in the Lau Basin, our data show a systematic latitudinal variation of increasing Ne, Ar, Kr, and Xe abundances from north to south as well as Ne and Ar isotopic compositions changing from MORB-like to atmosphere-like in the same direction. Moreover, isotopic compositions and noble gas abundances of the lavas correlate strongly with Ba/Nb ratios and H₂O concentrations. Based on these observations and mass balance arguments, we propose that the atmospheric noble gases come from the subducting oceanic crust and are not due to shallow contamination with air dissolved in seawater or assimilation of old crust. Our data suggest that the noble gases released from the subducting slab are atmospheric and thus contain little or no solar He and Ne. In addition to the fact that ratios of He to heavy noble gases are small in aged ocean crust, He has possibly fractionated from the other noble gases due to its higher diffusivity, and thus He transport from the subducting slab into the mantle wedge is probably insignificant. We propose that the ³He/⁴He ratios lower than MORB observed in the VFR lavas result from radiogenic ingrowth of He in a highly depleted, and hence degassed, mantle wedge after the enrichment of U and Th released from the downgoing slab.     

A mass‐balance approach to estimate in‐stream processes in a large river

A mass‐balance approach was used to estimate in‐stream processes related to inorganic nitrogen species (NH₄⁺, NO₂^? and NO₃^?) in a large river characterized by highly variable hydrological conditions, the Garonne River (south‐west France). Studies were conducted in two consecutive reaches of 30 km located downstream of the Toulouse agglomeration (population 760 000, seventh order), impacted by modification of discharge regime and high nitrogen concentrations. The mass‐balance was calculated by two methods: the first is based on a variable residence time (VRT) simulated by a one‐dimensional (1‐D) hydraulic model; the second is a based on a calculation using constant residence time (CRT) evaluated according to hydrographic peaks. In the context of the study, removal of dissolved inorganic nitrogen (DIN) for a reach of 30 km is underestimated by 11% with the CRT method. In sub‐reaches, the discrepancy between the two methods led to a 50% overestimation of DIN removal in the upper reach (13 km) and a 43% underestimation in the lower reach (17 km) using the CRT method. The study highlights the importance of residence time determination when using modelling approaches in the assessment of whole stream processes in short‐duration mass‐balance for a large river under variable hydrological conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

Modeling basin-scale hydrology in support of physical climate and global biogeochemical studies: An example using the Zambezi River

Human activity is an important agent defining the contemporary hydrologic cycle. We have documented the potential impacts of impoundment, land use change and climate change on the Zambezi River system in southern Africa and found that they can be substantial. A full analysis requires construction and parameterization of a simulation for the entire catchment. This paper develops a strategy for implementing catchment-scale models of the major hydrologic processes operating within the basin. A coherent data set for calibrating the models has also been assembled. The algorithms consist of a Water Balance (WBM) and a Water Transport (WTM) operating at 1/2^o spatial scale and at monthly timesteps. These models transform complex patterns of regional climatology into estimates of soil water, evapotranspiration, runoff, and discharge through rivers of various size. The models are dependent on the characteristics of the terrestrial surface, principally soil texture and land cover. A simulated river network is also required. Additional tabular data sets are essential for model testing and calibration. These include subcatchment areas; observed river discharge at selected points; flooding, storage and loss characteristics of major wetlands; floodwave translation; and, volume, surface area, withdrawal and evaporative losses from impoundments. An important design consideration for the numerous impoundments in the Zambezi requires an understanding of the seasonal variation in discharge, in particular how it might respond to climate and land use change. The research strategy offered here lays a framework for addressing such issues. Although the primary focus of this work is hydrologic, we discuss how the model can be extended to consider constituent transport and biogeochemical cycling issues at the continental scale.     

Travel time controls the magnitude of nitrate discharge in groundwater bypassing the riparian zone to a stream on Virginia's coastal plain

Groundwater that bypasses the riparian zone by travelling along deep flow paths may deliver high concentrations of fertilizer‐derived NO₃^? to streams, or it may be impacted by the NO₃^? removal process of denitrification in streambed sediments. In a study of a small agricultural catchment on the Atlantic coastal plain of Virginia's eastern shore, we used seepage meters deployed in the streambed to measure specific discharge of groundwater and its solute concentrations for various locations and dates. We used values of Cl^? concentration to discriminate between bypass water recharged distal to the stream and that contained high NO₃^? but low Cl^? concentrations and riparian‐influenced water recharged proximal to the stream that contained low NO₃^? and high Cl^? concentrations. The travel time required for bypass water to transit the 30‐cm‐thick, microbially active denitrifying zone in the streambed determined the extent of NO₃^? removal, and hydraulic conductivity determined travel time through the streambed sediments. At all travel times greater than 2 days, NO₃^? removal was virtually complete. Comparison of the timescales for reaction and transport through the streambed sediments in this system confirmed that the predominant control on nitrate flux was travel time rather than denitrification rate coefficients. We conclude that extensive denitrification can occur in groundwater that bypasses the riparian zone, but a residence time in biologically active streambed sediments sufficient to remove a large fraction of the NO₃^? is only achieved in relatively low‐conductivity porous media. Instead of viewing them as separate, the streambed and riparian zone should be considered an integrated NO₃^? removal unit. Copyright © 2011 John Wiley & Sons, Ltd.     

Volcanic resurfacing and the early terrestrial crust: Zircon U-Pb and REE constraints from the Isua Greenstone Belt, southern West Greenland

The oldest known bona fide succession of clastic metasediments occurs in the Isua Greenstone Belt, SW Greenland and consists of a variety of mica schists and rare metaconglomerates. The metasediments are in direct contact with a felsic metavolcanic lithology that has previously been dated to 3.71 Ga. Based on trace element geochemical data for > 30 metasediments, we selected the six samples with highest Zr concentrations for zircon extraction. These samples all yielded very few or no zircon. Those extracted from mica schists yielded ion probe U/Pb ages between 3.70 and 3.71 Ga. One metaconglomerate sample yielded just a single zircon of 3.74 Ga age.The mica schist hosted zircons have U/Pb ages, Th / U ratios, REE patterns and Eu anomalies indistinguishable from zircon in the adjacent 3.71 Ga felsic metavolcanic unit. Trace element modelling requires the bulk of material in the metasediments to be derived from variably weathered mafic lithologies but some metasediments contain substantial contribution from more evolved source lithologies. The paucity of zircon in the mica schists is thus explained by incorporation of material from largely zircon-free volcanic lithologies. The absence of older zircon in the mica schists and the preponderance of mafic source material imply intense, mainly basaltic resurfacing of the early Earth. The implications of this process are discussed.Thermal considerations suggest that horizontal growth of Hadean crust by addition of mafic-ultramafic lavas must have triggered self-reorganisation of the protocrust by remelting. Reworking of Hadean crust may have been aided by burial of hydrated (weathered) metabasalt due to semi-continuous addition of new voluminous basalt outpourings. This process causes a bias towards eruption of Zr-saturated partial melts at the surface with O-isotope compositions potentially different from the mantle. The oldest zircons hosted in sediments would have been buried to substantial depth or formed in plutons that crystallised at some depth, from which it took hundreds of millions of years for them to be exhumed and incorporated into much younger sediments.