Preliminary groundwater quality assessment in the central region of Ghana

Insufficient knowledge of the hydrogeochemistry of aquifers in the Central Region of Ghana has necessitated a preliminary water quality assessment in some parts of the region. Major and minor ions, and trace metal compositions of groundwater have been studied with the aim of evaluating hydrogeochemical processes that are likely to impair the quality of water in the study area. The results show that groundwater in the area is weakly acidic with mean acidity being 5.83 pH units. The dominant cation in the area is Na, followed by K, Ca, and Mg, and the dominant anion is Cl^?, followed by HCO₃ ^? and SO₄ ^2?. Two major hydrochemical facies have been identified as Na–Cl and Na–HCO_3, water types. Multivariate statistical techniques such as cluster analysis (CA) and factor analysis/principal component analysis (PCA), in R mode, were employed to examine the chemical compositions of groundwater and to identify factors that influenced each. Q-mode CA analysis resulted in two distinct water types as established by the hydrochemical facies. Cluster 1 waters contain predominantly Na–Cl. Cluster 2 waters contain Na–HCO₃ and Na–Cl. Cluster 2 waters are fresher and of good quality than cluster 1. Factor analysis yielded five significant factors, explaining 86.56% of the total variance. PC1 explains 41.95% of the variance and is contributed by temperature, electrical conductivity, TDS, turbidity, SO₄ ^2?, Cl^?, Na, K, Ca, Mg, and Mn and influenced by geochemical processes such as weathering, mineral dissolution, cation exchange, and oxidation–reduction reactions. PC2 explains 16.43% of the total variance and is characterized by high positive loadings of pH and HCO₃ ^?. This results from biogenic activities taking place to generate gaseous carbon dioxide that reacts with infiltrating water to generate HCO₃ ^?, which intend affect the pH. PC3 explains 11.17% of the total variance and is negatively loaded on PO₄ ^3? and NO₃ ^? indicating anthropogenic influence. The R-mode PCA, supported by R-mode CA, have revealed hydrogeochemical processes as the major sources of ions in the groundwater. Factor score plot revealed a possible flow direction from the northern sections of the study area, marked by higher topography, to the south. Compositional relations confirmed the predominant geochemical process responsible for the various ions in the groundwater as mineral dissolution and thus agree with the multivariate analysis.     

Measuring the vulnerability of populations susceptible to lead contamination in the Dominican Republic: evaluating composite index construction methods

There are several suspected sources of lead contamination in the Dominican Republic (DR) to which populations, to a greater or lesser extent, may be exposed. These sources include: a lead battery recycling plant, a gold mine and vehicles using leaded gasoline. In this paper we create and compare indices of spatial vulnerability using different index construction methods including: the weighted average, ordered weighted average, and Data Envelopment Analysis. The vulnerability attributes used to create these indices include: exposure to lead effluents in water from the gold mine as measured by distance from potentially contaminated water, point source lead air emissions from the battery recycling plant estimated by air plume analysis; and mobile source exposure to lead emissions from road transportation measured by potential traffic impacts. The intensities of vulnerability to lead of the towns and cities in the DR, produced by each of the different index construction methods, are compared and evaluated.     

Oxygen and Ethene Biostimulation for a Persistent Dilute Vinyl Chloride Plume

Contamination of groundwater with chlorinated ethenes is common and represents a threat to drinking water sources. Standard anaerobic bioremediation methods for the highly chlorinated ethenes PCE and TCE are not always effective in promoting complete degradation. In these cases, the target contaminants are degraded to the daughter products DCE and/or vinyl chloride. This creates an additional health risk, as vinyl chloride is even more toxic and carcinogenic than its precursors. New treatment modalities are needed to deal with this widespread environmental problem. We describe successful bioremediation of a large, migrating, dilute vinyl chloride plume in Massachusetts with an aerobic biostimulation treatment approach utilizing both oxygen and ethene. Initial microcosm studies showed that adding ethene under aerobic conditions stimulated the rapid degradation of VC in site groundwater. Deployment of a full‐scale treatment system resulted in plume migration cutoff and nearly complete elimination of above‐standard VC concentrations.     

The effect of glaciation on the intensity of seismic ground motion

Seismicity is known to contribute to landscape denudation through its role in earthquake‐triggered slope failure; but little is known about how the intensity of seismic ground motions, and therefore triggering of slope failures, may change through time. Topography influences the intensity of seismic shaking – generally steep slopes amplify shaking more than flatter slopes – and because glacial erosion typically steepens and enlarges slopes, glaciation may increase the intensity of seismic shaking of some landforms. However, the effect of this may be limited until after glaciers retreat because valley ice or ice‐caps may damp seismic ground motions. Two‐dimensional numerical models (FLAC 6.0) were used to explore how edifice shape, rock stiffness and various levels of ice inundation affect edifice shaking intensity. The modelling confirmed that earthquake shaking is enhanced with steeper topography and at ridge crests but it showed for the first time that total inundation by ice may reduce shaking intensity at hill crests to about 20–50% of that experienced when no ice is present. The effect is diminished to about 80–95% if glacier ice level reduces to half of the mountain slope height. In general, ice cover reduced shaking most for the steepest‐sided edifices, for wave frequencies higher than 3 Hz, and when ice was thickest and the rock had shear stiffness well in excess of the stiffness of ice. If rock stiffness is low and shear‐wave velocity is similar to that of ice, the presence of ice may amplify the shaking of rock protruding above the ice surface. The modelling supports the idea that topographic amplification of earthquake shaking increases as a result of glacial erosion and deglaciation. It is possible that the effect of this is sufficient to have influenced the distribution of post‐glacial slope failures in glaciated seismically active areas. Copyright © 2012 John Wiley & Sons, Ltd.     

Sea level forcing in the Mediterranean Sea between 1960 and 2000

Sea level trends and inter-annual variability in the Mediterranean Sea for the period 1960–2000 is explored by comparing observations from tide gauges with sea level hindcasts from a barotropic 2D circulation model, and two full primitive equation 3D ocean circulation models, a regional one and the Mediterranean component of a global one,. In the 2D model, 50% of the sea level variance was found to result from the wind and atmospheric pressure forcing. In the 3D models, 20% of the sea level variance was explained by the steric effects. The sea level residuals at the tide gauges locations, calculated by subtraction of the 2D model output from the sea level observations are significantly correlated (r = 0.4) with the steric signals from the 3D models. After the removal of the atmospheric and the steric contributions the tide-gauge sea level records indicate a period where sea level was stable (1960–1975) and a period where sea level was rising (1975–2000) with rates in the range 1.1–1.8 mm/yr. A part of the residual trend can be explained by the contribution of local land movements (0.3 mm/yr) while its major part indicates a global signal, probably mass addition, appearing after 1975.     

Contourites in the Gulf of Cadiz: a cautionary note on potentially ambiguous indicators of bottom current velocity

Facies associations in cores collected in the deep part of the Gulf of Cadiz, which is under the influence of the lower branch of the Mediterranean Outflow Water, are investigated in terms of the classical contourite model using grain-size analyses and thin sections of indurated sediment. Cores include both low-energy (contourite drift) and high-energy (channel) environments. The thin sections and grain-size distributions show that clayey fine silts and sandy coarse silts are the most common facies associations in the studied contourite sequences, while coarse-grained, gravelly contourites are less common. Grain-size distributions are unimodal in the fine-grained and bi- or trimodal in the coarser-grained contourites. This change in grain-size composition is related both to the partial removal of the fine-grained fraction and to the replenishment of the coarser-grained one. In addition, most of the contacts between individual facies are sharp rather than transitional. This suggests that the contourite sequence is only in part related to changes in bottom current velocity and flow competency, but may also be related to the supply of a coarser terrigeneous particle stock, provided by either increased erosion of indurated mud along the flanks of confined contourite channels (mud clasts), or by increased sediment supply by rivers (quartz grains) and downslope mass transport on the continental shelf and upper slope. The classical contourite facies association may therefore not be solely controlled by current velocity, but may be the product of a variety of depositional histories. The classical contourite depositional sequence should therefore be interpreted with greater care and in the light of the regional sedimentological background. In addition, the wisdom of exclusively using mean or modal particle size for the interpretation of depositional contourite processes is questioned. Instead, it is proposed that the vertical evolution of grain-size populations in the facies successions forming contourite sequences be assessed.     

Constraints on Upward Migration of Hydraulic Fracturing Fluid and Brine

Recent increases in the use of hydraulic fracturing (HF) to aid extraction of oil and gas from black shales have raised concerns regarding potential environmental effects associated with predictions of upward migration of HF fluid and brine. Some recent studies have suggested that such upward migration can be large and that timescales for migration can be as short as a few years. In this article, we discuss the physical constraints on upward fluid migration from black shales (e.g., the Marcellus, Bakken, and Eagle Ford) to shallow aquifers, taking into account the potential changes to the subsurface brought about by HF. Our review of the literature indicates that HF affects a very limited portion of the entire thickness of the overlying bedrock and therefore, is unable to create direct hydraulic communication between black shales and shallow aquifers via induced fractures. As a result, upward migration of HF fluid and brine is controlled by preexisting hydraulic gradients and bedrock permeability. We show that in cases where there is an upward gradient, permeability is low, upward flow rates are low, and mean travel times are long (often >10⁶ years). Consequently, the recently proposed rapid upward migration of brine and HF fluid, predicted to occur as a result of increased HF activity, does not appear to be physically plausible. Unrealistically high estimates of upward flow are the result of invalid assumptions about HF and the hydrogeology of sedimentary basins.     

Sm–Nd isotopic mapping of lithospheric growth and stabilization in the eastern Kaapvaal craton

Whole-rock Sm–Nd isotope systematics of 79 Archean granitoids from the eastern Kaapvaal craton, southern Africa, are used to delineate lithospheric boundaries and to constrain the timescale of crustal growth, assembly and geochemical differentiation c. 3.66–2.70 Ga. Offsets in ε_Nd values for 3.2–3.3 Ga granitoids across the Barberton greenstone belt (BGB) are consistent with existing models for c. 3.23 Ga accretion of newly formed lithosphere north of the BGB onto pre-existing c. 3.66 Ga lithosphere south of the BGB along a doubly verging subduction margin. The Nd isotopic signature of c. 3.3–3.2 Ga magmatic rocks show that significant crustal growth occurred during subduction–accretion. After c. 3.2 Ga, however, the Nd signature of intrusive rocks c. 3.1 and 2.7 Ga is dominated by intracrustal recycling rather than by new additions from the mantle, signalling cratonic stability.