The roles of magmatic and hydrothermal processes in PGE mineralization,Ferguson Lake deposit,Nunavut, Canada

The Ferguson Lake Ni–Cu–Co–platinum-group element (PGE) deposit in Nunavut, Canada, occurs near the structural hanging wall of a metamorphosed gabbroic sill that is concordant with the enclosing country rock gneisses and amphibolites. Massive to semi-massive sulfide occurs toward the structural hanging wall of the metagabbro, and a low-sulfide, high-PGE style of mineralization (sulfide veins and disseminations) locally occurs ~30–50 m below the main massive sulfide. Water–rock interaction in the Ferguson Lake Ni–Cu–Co–PGE deposit is manifested mostly as widespread, post-metamorphic, epidote–chlorite–calcite veins, and replacement assemblages that contain variable amounts of sulfides and platinum-group minerals (PGM). PGM occur as inclusions in magmatic pyrrhotite and chalcopyrite in both the massive sulfide and high-PGE zones, at the contact between sulfides and hornblende or magnetite inclusions in the massive sulfide, in undeformed sulfide veins and adjacent chlorite and/or epidote halos, in hornblende adjacent to hydrothermal veins, and in plagioclase–chlorite aggregates replacing garnet cemented by sulfide. The PGM are mostly represented by the kotulskite (PdTe)–sobolevskite (PdBi) solid solution but also include michenerite (PdBiTe), froodite (PdBi₂), merenskyite (PdTe₂), mertieite II (Pd₈[Sb,As]₃), and sperrylite (PtAs₂) and occur in variety of textural settings. Those that occur in massive and interstitial sulfides, interpreted to be of magmatic origin and formed through exsolution from base metal sulfides at temperatures <600°C, are dominantly Bi rich (i.e., Te-bearing sobolevskite), whereas those that occur in late-stage hydrothermal sulfide/silicate veins and their epidote–chlorite alteration halos tend to be more Te rich (i.e., Bi-bearing kotulskite). The chemistry and textural setting of the various PGM supports a genetic model that links the magmatic and hydrothermal end-members of the sulfide–PGM mineralization. The association of PGM with magmatic sulfides in the massive sulfide and high-PGE zones has been interpreted to indicate that PGE mineralization was initially formed through exsolution from base metal sulfides which formed by magmatic sulfide liquid segregation and crystallization. However, the occurrence of PGM in undeformed sulfide-bearing veins and in their chlorite–epidote halos and differences in PGM chemistry indicate that hydrothermal fluids were responsible for post-metamorphic redistribution and dispersion of PGE.     

Electromagnetic characterization of polar ice-wedge polygons: Implications for periglacial studies on Mars and Earth

Polygonal terrain is found in a variety of polar environments on Earth and Mars. As a result, many areas of northern Canada may represent ideal terrestrial analogues for specific regions of Mars - in particular the northern plains. In the Canadian Arctic, polygon troughs are commonly underlain by wedges of massive ice, with rare examples of other wedge types. If the same is true for Mars, this raises interesting implications for the processes that concentrate H₂O at the Martian poles. This study uses an electromagnetic induction sensor to investigate the electromagnetic characteristics of terrestrial polar ice-wedge polygons. Surveys were conducted in two regions of the Canadian Arctic using a DUALEM-1S dual-geometry electromagnetic induction sensor, which measures electrical conductivity in the first 1.5-2 m of the subsurface. At locations where strong geomorphological evidence of ice was found, polygon troughs corresponded to local conductive anomalies. Trenching confirmed the presence of ice wedges at one site and allowed ground-truthing and calibration of the geophysical data. Previously unknown bodies of massive ice were also identified through the use of this geophysical technique. This study shows that an electromagnetic induction sounder is a useful instrument for detecting and mapping out the presence of subsurface ice in the Canadian Arctic. Taking together with its small size, portability and ruggedness, we suggest that this would also be a useful instrument for any future missions to Mars’ polar regions.     

3‐D laser images of splash‐form tektites and their use in aerodynamic numerical simulations of tektite formation

Ten splash‐form tektites from the Australasian strewn field, with masses ranging from 21.20 to 175.00 g and exhibiting a variety of shapes (teardrop, ellipsoid, dumbbell, disk), have been imaged using a high‐resolution laser digitizer. Despite challenges due to the samples’ rounded shapes and pitted surfaces, the images were combined to create 3‐D tektite models, which captured surface features with a high fidelity (≈30 voxel mm^?2) and from which volume could be measured noninvasively. The laser‐derived density for the tektites averaged 2.41 ± 0.11 g cm^?3. Corresponding densities obtained via the Archimedean bead method averaged 2.36 ± 0.05 g cm^?3. In addition to their curational value, the 3‐D models can be used to calculate the tektites’ moments of inertia and rotation periods while in flight, as a probe of their formation environment. Typical tektite rotation periods are estimated to be on the order of 1 s. Numerical simulations of air flow around the models at Reynolds numbers ranging from 1 to 10⁶ suggest that the relative velocity of the tektites with respect to the air must have been <10 m s^?1 during viscous deformation. This low relative velocity is consistent with tektite material being carried along by expanding gases in the early time following the impact.     

Constraints on the cooling history of the H‐chondrite parent body from phosphate and chondrule Pb‐isotopic dates from Estacado

Abstract— To constrain the metamorphic history of the H‐chondrite parent body, we dated phosphates and chondrules from four H6 chondritic meteorites using U‐Pb systematics. Reconnaissance analyses revealed that only Estacado had a sufficiently high ²⁰⁶Pb/²⁰⁴Pb ratio suitable for our purposes. The Pb‐Pb isochron date for Estacado phosphates is measured to be 4492 ± 15 Ma. The internal residue‐second leachate isochron for Estacado chondrules yielded the chondrule date of 4546 ± 18 Ma. An alternative age estimate for Estacado chondrules of 4527.6 ± 6.3 Ma is obtained from an isochron including two chondrules, two magnetically separated fractions, and four bulk chondrite analyses. This isochron date might represent the age of termination of Pb diffusion from the chondrules to the matrix. From these dates and previously established closure temperatures for Pb diffusion in phosphates and chondrules, we estimate an average cooling rate for Estacado between 5.5 ± 3.2 Myr/°C and 8.3 ± 5.0 Myr/°C. Using previously published results for Ste. Marguerite (H4) and Richardton (H5), our data reveal that the cooling rates of H chondrites decrease markedly with increasing metamorphic grade, in agreement with the predictions of the “onion‐shell” asteroid model. Several issues, however, need to be addressed before confirming this model for the H‐chondrite parent body: the discrepancies between peak metamorphic temperatures established by various mineral thermometers need to be resolved, diffusion and other mechanisms of element migration in polycrystalline solids must be better understood, and dating techniques should be further improved.     

Pi 2 pulsations: High latitude results

A review of recent experimental results from studies of high latitude Pi 2 pulsations indicates that these pulsations are fundamentally related to the initiation of the auroral breakup and substorm. At high latitudes, the Pi 2's show their peak intensities in the region where the breakup begins and appear to remain in this region after the breakup has spread poleward. In addition, the Pi 2's occur simultaneously with, or before all other ionospheric phenomena associated with the breakup. The field aligned and ionospheric currents associated with the Pi 2 resemble those of a typical substorm, but the ionospheric currents are phase shifted compared to the field aligned current. The periodic oscillations of the Pi 2's are probably caused by a reflection of the initial field aligned current pulse from the auroral ionosphere. This pulse is trapped on dipolar field lines leading to multiple reflections from North and South auroral ionospheres.     

Plant–water relationships and growth strategies of Jatropha curcas L. seedlings under different levels of drought stress

Although Jatropha curcas, an important tropical biofuel crop, is reputed for its drought resistance, its ability to perform under dry conditions has hardly been investigated. In a greenhouse experiment we investigated the plant–water relationships of Jatropha seedlings from different accessions under different levels of drought stress. There was little difference in plant–water relations between accessions. Drought significantly reduced leaf area, biomass and relative growth rate, but had no effect on specific leaf area, daily range in leaf water potential, leaf water content, transpiration efficiency or aboveground biomass water productivity, corrected for atmospheric conditions. Stem wood density was equally low (0.26 g cm^?3) for all treatments. Stem water content was lowest for dry treatment seedlings. Based on these results, Jatropha could be characterized as a stem-succulent tree. In contrast to other stem-succulent deciduous trees, leaves were not shed immediately after the seedlings were confronted with drought. Instead, at the onset of drought, leaves with a higher adaxial stomatal density were formed, after which leaves were only gradually shed. The role of the succulent stem in the water economy of Jatropha was confined to balancing the small water losses of the leaves during drought.     

Timing and thermochemical constraints on multi-element mineralisation at the Nori/RA Cu–Mo–U prospect, Great Bear magmatic zone, Northwest Territories, Canada

The timing of Cu–Mo–U mineralisation at the Nori/RA prospect in the Paleoproterozoic Great Bear magmatic zone has been investigated using Re–Os molybdenite and ⁴⁰Ar–³⁹Ar biotite geochronology. The Re–Os molybdenite ages presented are the first robust sulphide mineralisation ages derived from the Great Bear magmatic zone. Cu–Mo–U mineralisation is hosted in early to syn-deformational hydrothermal veins consisting of quartz and K-feldspar or more commonly tourmaline-biotite-quartz-K-feldspar, with associated wall-rock alteration assemblages being predominantly biotite. Sulphide and oxide minerals consist of chalcopyrite, molybdenite and uraninite with lesser pyrite and magnetite. Elevated light rare earth elements and tungsten concentrations associated with the Cu–Mo–U mineralisation have also been reported at the prospect by previous workers. Molybdenite and uraninite occur intimately in dravitic tourmaline growth zones and at grain margins, attesting to their syngenetic nature (with respect to hydrothermal veining). Two molybdenite separates yield Re–Os model ages of 1,874.4 ± 8.7 (2σ) and 1,872.4 ± 8.8 Ma (2σ) with a weighted average model age of 1,873.4 ± 6.1 Ma (2σ). Laser step heating of biotite from the marginal alteration of the wall-rock adjacent to the veins yields a ⁴⁰Ar–³⁹Ar maximum cooling age of 1,875 ± 8 Ma (MSWD = 3.8; 2σ), indistinguishable from the Re–Os molybdenite model age and a previously dated ‘syn-tectonic’ aplitic dyke in the region. Dravitic tourmaline hosts abundant primary liquid–vapour–solid-bearing fluid inclusions. Analytical results indicate liquid–vapour homogenisation at >260°C constraining the minimum temperature of mineralisation. The solids, which are possibly trapped, did not homogenise with the liquid–vapour by 400°C. Salinities in the inclusions are variable. Raman spectra identify that at least some of the solids are calcite and anhydrite. Raman spectra also confirm the vapour phases contain some CO₂; whereas clathrates or CH₄ was not observed or detected. Quartz grains only host secondary fluid inclusions, which fluoresce under ultraviolet light, indicating trapped hydrocarbons. We speculate that these resulted from Phanerozoic fluid circulation through the Proterozoic basement. The collective interpretation of the age, hydrothermal character and associated metals, high temperature and variable salinity suggests that the Nori/RA Cu–Mo–U mineralisation can be linked with the earliest stages of plutonism in the Great Bear magmatic zone. From a regional perspective, the mineralisation may pre-date the extensive multi-element mineralisation now recognised as part of the iron oxide copper–gold (IOCG) spectrum of deposits. As IOCG provinces generally contain a variety of mineralisation styles, we interpret this as the earliest phase of the extensive mineralising system.     

Precise U-Pb Zircon Constraints on the Earliest Magmatic History of the Carolina Terrane

The early magmatic and tectonic history of the Carolina terrane and its possible affinities with other Neoproterozoic circum-Atlantic arc terranes have been poorly understood, in large part because of a lack of reliable geochronological data. Precise U-Pb zircon dates for the Virgilina sequence, the oldest exposed part, constrain the timing of the earliest known stage of magmatism in the terrane and of the Virgilina orogeny. A flow-banded rhyolite sampled from a metavolcanic sequence near Chapel Hill, North Carolina, yielded a U-Pb zircon date of 632.9 +2.6/-1.9 Ma. A granitic unit of the Chapel Hill pluton, which intrudes the metavolcanic sequence, yielded a nearly identical U-Pb zircon date of 633 +2/-1.5 Ma, interpreted as its crystallization age. A felsic gneiss and a dacitic tuff from the Hyco Formation yielded U-Pb zircon dates of 619.9 +4.5/-3 Ma and 615.7 +3.7/-1.9 Ma, respectively. Diorite and granite of the Flat River complex have indistinguishable U-Pb upper-intercept dates of 613.9 +1.6/-1.5 Ma and 613.4 +2.8/-2 Ma. The Osmond biotite-granite gneiss, which intruded the Hyco Formation before the Virgilina orogeny, crystallized at 612.4 +5.2/-1.7 Ma. Granite of the Roxboro pluton, an intrusion that postdated the Virgilina orogeny, yielded a U-Pb upper intercept date of 546.5 +3.0/-2.4 Ma, interpreted as the time of its crystallization. These new dates both provide the first reliable estimates of the age of the Virgilina sequence and document that the earliest known stage of magmatism in the Carolina terrane had begun by 633 +2/-1.5 Ma and continued at least until 612.4 +5.2/-1.7 Ma, an interval of approximately 25 m.yr. Timing of the Virgilina orogeny is bracketed between 612.4 +5.2/-1.7 Ma and 586+/-10 Ma (reported age of the upper Uwharrie Formation). The U-Pb systematics of all units studied in the Virgilina sequence are simple and lack any evidence of an older xenocrystic zircon component, which would indicate the presence of a continental-type basement. This observation, together with the juvenile Nd isotopic character of the Virgilina volcanic arc sequence, suggests that the oldest part of the Carolina terrane was built on oceanic crust away from a continental crustal influence.     

Polarization characteristics of Pi 2 pulsations and implications for their source mechanisms: Influence of the westward travelling surge

This paper expands the earlier results of Rostoker and Samson (1981), who noted that there are two latitudinal areas of Pi 2 localization near the high latitude, substorm enhanced electrojets. The detailed study presented here outlines the morphology of the polarizations of the Pi 2's in and near the westward travelling surge. There are two latitudinal areas of Pi 2 localization. A poleward Pi 2 predominates within the surge and to the East, whereas an equatorward Pi 2 predominates equatorward and West of the surge. These Pi 2 localizations appear to correlate with the substorm enhanced westward and eastward electrojets respectively. However, the maximum in the Pi 2 power does not always coincide with the center of the electrojet. The poleward Pi 2 has largest amplitudes to the East of the head of the westward travelling surge. This Pi 2 shows a latitudinal polarization reversal from clockwise on the equatorside (viewed down on H-D plane) to counterclockwise on the poleside of a latitudinal demarcation line, which occurs just poleward of the initial breakup. This demarcation line is usually equatorward of the most poleward expansion of the surge. To the West of the surge front, where the equatorward Pi 2 predominates, there is again a latitudinal polarization reversal but in this case the polarization is counterclockwise equatorward and clockwise poleward of the demarcation line. This demarcation is equatorward of that for the poleward Pi 2, and appears to lie at the latitude of the initial breakup. Consequently, the westward travelling surge appears to mark the longitudinal transition from equatorward to poleward Pi 2. The elliptical polarization of the Pi 2's is most likely caused by azimuthai (longitudinal) expansion of the field-aligned currents in the surge, in association with reflection of the field-aligned current pulses from northern and southern high latitude ionospheres.