The rapid growth and decay of severe cyclone JAL (2010) over the Bay of Bengal

This study investigates the life cycle of Bay of Bengal cyclone JAL, characterized by a rapid fluctuation in its intensity during 60-h interval. The cyclone JAL underwent a period of rapid intensification during 24-h from 0000 UTC 05 November to 0000 UTC 06 November 2010. It was quasi-static during subsequent 24 h followed by a 12-h period of unusually rapid decay. During the rapid cyclogenesis phase, the system intensified (by 25 kt) from deep depression (DD) to severe cyclonic storm (SCS) and weakened (by 30 kt) from SCS to DD during the 12-h period of rapid cyclolysis. European Centre for Medium Range Weather Forecasts (ECMWF) model analysis field is used to analyze the Q vectors, K index and potential vorticity (PV) to diagnose the life cycle of this unusual cyclone. The analysis reveals that the 500–700 hPa column-averaged Q-vector convergence above the surface cyclone had strengthened and very high values of the K index produced a burst of heavy precipitation during the development stage of the cyclone. The associated latent heat release produced a substantial diabatic positive PV anomaly in the lower and middle troposphere that caused rapid cyclogenesis. The rapid cyclolysis is coincident with the weakening of the upper and lower PV anomalies and the westward shearing of the upper PV from the cyclone centre. Thus, the very latent heat release that assisted the rapid development of the cyclone also played an important role in its subsequent rapid decay. ECMWF model forecast for track and intensity is also verified.     

Probing for suitable climatology to estimate the predictability of monsoon onset over Kerala (MOK), India

Inter-annual variability in the onset of monsoon over Kerala (MOK), India, is investigated using daily temperature; mean sea level pressure; winds at 850, 500 and 200 hPa pressure levels; outgoing longwave radiation (OLR); sea surface temperature (SST) and vertically integrated moisture content anomaly with 32 years (1981–2013) observation. The MOK is classified as early, delayed, or normal by considering the mean monsoon onset date over Kerala to be the 1st of June with a standard deviation of 8 days. The objective of the study is to identify the synoptic setup during MOK and comparison with climatology to estimate the predictability of the onset type (early, normal, or delayed) with 5, 10, and 15 days lead time. The study reveals that an enhanced convection observed over the Bay of Bengal during early MOK is found to shift over the Arabian Sea during delayed MOK. An intense high-pressure zone observed over the western south Indian Ocean during early MOK shifts to the east during delayed MOK. Higher tropospheric temperature (TT) over the western Equatorial Ocean during early MOK and lower TT over the Indian subcontinent intensify the land–ocean thermal contrast that leads to early MOK. The sea surface temperature (SST) over the Arabian Sea is observed to be warmer during delayed than early MOK. During early MOK, the source of 850 hPa southwesterly wind shifts to the west equatorial zone while a COL region has been found during delayed MOK at that level. The study further reveals that the wind speed anomaly at the 200-hPa pressure level coincides inversely with the anomaly of tropospheric temperature.     

Influence of transient storage on stream nutrient uptake based on substrata manipulation

Quantification of the transient storage zone (A_s) has become critical in stream biogeochemical studies addressed to examine factors controlling nutrient uptake. It is expected that higher A_s may enhance the interaction between nutrients and biota and thus, increase nutrient uptake. However, results from the literature are controversial. We hypothesized that besides of the size of A_s, the intrinsic physical and biological characteristics of stream structures that generate A_s are also relevant for nutrient uptake. We performed 24 additions of phosphate, ammonium, and chloride in four reaches of a man-made channel where we introduced three types of naturally colonized substrata packs (mud, sand and cobbles) to modify A_s. We estimated ammonium and phosphate uptake coefficients in both the main channel and A_s using a solute transport model (OTIS-P) and compared the results among reaches with different substrata types. The introduction of substrata packs decreased water velocity and increased A_s similarly among treatments. Nutrient uptake coefficients in the main channel were similar among reaches with different type substrata packs; however, nutrient uptake coefficients measured in A_s differed among them as well as the ratio between ammonium and phosphorus uptake coefficients in A_s, which were 1.6 in reaches with mud packs and 0.02 in reaches with sand or cobble packs. Results obtained in this study suggest that the contribution of A_s in nutrient uptake not only depends on the size of A_s but on the type of materials used to increase A_s, and thus, have biogeochemical implications on restoration projects aimed to modify channel morphology.     

Fissures and fractures in the Koyna seismogenic zone,western India

Mn-rich ilmenites (up to 7 % MnO) have been identified in dykes cutting the Malanjkhand porphyry copper mining area in Madhya Pradesh. The dykes are hydrothermally altered and are of tholeiitic affinities. Lamprophyres have been reported from nearby areas. The presence of Mn-rich Ilmenites in the Malanjkhand copper mine dykes and the occurrence of lamprophyres and the pervasive potassium metasomatism in the area strongly suggests a possibility of finding diamondiferous rocks in the area. Such high-Mn bearing ilmenites are associated with diamondiferous deposits in other parts of the world, e.g. Juina kimberlites, Brazil. Mn-bearing ilmenite is considered as an indicator mineral for kimberlite/diamond occurrences. The presence of kimberlite pipes in Raipur district and the association of Mn-rich ilmenite with kimberlites is a fortuitous coincidence for venture-some mining companies. A probable explanation for the origin of manganese layers in the context of ‘rift’ tectonic environment is offered. Also a possible link between the dykes, quartz veins in the Malanjkhand granitic rocks and the copper mineralization is proposed.     

New REE and Trace Element Data on Two Kimberlitic Reference Materials by ICP-MS

Data on thirty-four minor and trace elements including all rare earth elements (REE) are reported for two kimberlitic international reference materials (SARM-39, MINTEK, RSA and MY-4, IGEM, Russia) by inductively coupled plasma-mass spectrometry (ICP-MS), some of them for the first time. Four digestion techniques (open acid, closed vessel acid, microwave and lithium metaborate fusion digestion) were used for the decomposition of samples for analysis by ICP-MS. Three other reference materials (USGS BHVO-1, CRPG BR-1 and ANRT UB-N) were analysed simultaneously using the same analytical methodology to assess the precision and accuracy of the determinations. The data obtained in this study compare well with working values wherever such values are available for comparison. Though open acid digestion was found to be very rapid, effective and convenient for the determination of several trace elements in kimberlitic samples, recoveries for heavy rare earth elements (HREE) were lower than the respective recoveries obtained by the other decomposition techniques used. The precision obtained was better than ± 6% RSD in the majority of cases with comparable accuracy. Chondrite-normalised plots of each RM for all the digestion techniques were smooth. The new data reported on the two kimberlitic reference materials make these samples useful for future geochemical studies of kimberlitic rocks.     

MEG Investigation of Low Pressure Silica — Shell model for polarization

We present a two-shell polarization model for the α-quartz and α-cristobalite structures. By allowing for polarization, we correct problems encountered in purely ionic bonding treatments of tetrahedrally coordinated silica phases. The shell model predicts zero pressure structures in very good agreement with experiment using no empirical parameters. The behavior of the shell model α-quartz lattice upon compression shows dramatic improvement over the distorted, rigid lattice given by the ionic model.     

A laboratory batch study on arsenic sorption and desorption on guava orchard soils of Baruipur,West Bengal,India

Groundwater contaminated with arsenic (As), when extensively used for irrigation, causes potentially long term detrimental effects to surface soils. Such contamination can also directly affect human health when irrigated crops, such as rice, vegetable and fruits, are used for human consumption. Therefore, an understanding of the sorption and desorption behavior of As in surface soils is of high importance, because these processes regulate the bioavailability of As in the soil environment. In this study, we have collected soils from guava orchards of Baruipur, West Bengal, and characterized soil chemistry and batch sorption and desorption behavior in the laboratory. The sorption and desorption behavior of As in the soils were examined using the Langmuir and Freundlich sorption equation. Regression analysis of the soil chemical characteristics and sorption equation parameters were also performed. The results suggest that the sorption behavior of arsenate is highly dependent on soil characteristics, specifically organic carbon, clay and Al₂O₃ content of the soils. Whereas desorption behavior is critically influenced by the presence of high concentrations of amorphous and/or crystalline Fe₂O₃ in the soils. Retention of the significant portion of As in the soils (~ 84% of the total) suggests that As in the orchard soils may not be highly bioavailable to plants for uptake. However, more detailed studies will be required to ascertain the role of individual soil components on the As sorption and desorption processes.     

Geochemical characteristics of Holocene sediments from Chuadanga district,Bangladesh: Implications for weathering,climate, redox conditions,provenance and tectonic setting

The present research deals with the geochemical characteristics of the Holocene sediments from Alamdanga area, Chuadanga district, Bangladesh. Main goals of the study are to delineate source rock characteristics, degree of chemical weathering and sorting processes and behavior of redox conditions during deposition of the sediments. Geochemical characteristics of the sediments show comparatively a wide variation in accordance with stratigraphy in their major element contents （e.g. SiO2 69.46-82.13, A1203 2.28-8.88 in wt%）, reflecting the distinctive provenance and in part an unstable period in terms of tectonic activity. Geochemical classification of the sediments shows mostly sub-arkose with few sub-litharenites. Some major and trace elements display comprehensible correlation with A1203 confirming their possible hydraulic fraetionation. The chemical index of alteration （CIA＊）, W＊ index, index of compositional variability （ICV）, plagioclase index of alteration （PIA＊） values and the ratio of SIO2/Al2O3, suggest low degrees of chemical weathering in the source areas as well as immature to moderately mature the sediments. The sediments suggest semi-arid climatic trends within oxic deltaic depositional conditions during the Holocene, at 3-12 ka. Whole rock geochemistry and discrimination diagrams demonstrate the continental signature derivatives, which might have been derived from the felsic to intermediate igneous rocks （granitic plutonic rocks） as well as from quartzose sedimentary/metamorphic provenance. These typical sources are present in a vast region of the Himalayan belt and catchment areas of Ganges. The tectonic setting of the sediments demarcates typically passive margin with slightly continental arc system.     

Supermagnetic enhancement,superparamagnetism, and archaeological soils

A range of mineral magnetic measurements have been carried out on archaeological sediments from Orkney and Cyprus. In a soil profile from Orkney, a magnetic enhancement factor of over 200 is observed in susceptibility data between the bedrock and a Norse sediment. The magnetic enhancement is associated with an increase in superparamagnetic grains probably caused by burning. Until now it has proved difficult to confirm the presence of superparamagnetic grains in natural samples using room temperature magnetic measurements. However, clear differences are to be found between the hysteresis loops of various magnetic domain states, including superparamagnetism. An algorithm has been developed to unmix hysteresis loops in terms of constituent domain states of ferrimagnetic iron oxides. Unmixing 128 hysteresis loops of archaeological sediments has shown that the dominant domain state in all sediments is superparamagnetic. Remarkably uniform superparamagnetic grain sizes of between 80 and 95 Å were found for all 128 sediments. © 1999 John Wiley & Sons, Inc.