Geology, petrography and geochemistry of rhyolite-hosted uranium mineralization at Mohar, Shivpuri district, Madhya Pradesh

In the westernmost part of the Bundelkhand Granitoid Complex (BGC), a mesa structure represents a unique outlier, surrounded by brecciated granite and filled with Vindhyan sedimentary rocks locally known as the Dhala Formation near Mohar village of Shivpuri district, Madhya Pradesh. Uranium mineralisation located in the area is mostly associated with rhyolite of peralkaline to peraluminous in nature, that has a high average uranium concentration (30 ppm). The mineralization is in or adjacent to caldera and is hydrothermal vein-type. Radioactivity is mainly due to coffinite with limited radioactivity due to U-Ti complex, uranium adsorbed in clay and labile uranium along fracture. Coffinite occurs in association with pyrite and chalcopyrite or chlorite with presence of fluorite. Features such as chloritisation, clay formation and sulfide mineralisation manifest hydrothermal alteration. Chemical analysis indicates the aluminous nature of the rock and their high K₂O/Na₂O (3.81–12.84) ratios are suggestive of predominance of potash feldspar over sodic. The alteration index varies from 49.88–92.40, which, reflects high intensity of hydrothermal alteration. Chlorite-carbonatepyrite index (CCPI), a measure of the intensity of replacement of sodic feldspars and glass by sericite, chlorite, carbonate, and pyrite associated with hydrothermal alteration proximal to the ore bodies varies from 3.84–49.66. On the basis of core study, geochemistry and mineralogy, it is envisaged that epigenetic hydrothermal solutions were responsible for concentration of uranium as coffinite, radioactive carbonaceous matter and adsorbed uranium phases in rhyolite with sulfide confined to weak planes.     

A database of archived drilling records of the drill cuttings piles at the North West Hutton oil platform

Drill cuttings piles are found underneath several hundred oil platforms in the North Sea, and are contaminated with hydrocarbons and chemical products. This study characterised the environmental risk posed by the cuttings pile at the North West Hutton (NWH) oil platform. Data on the drilling fluids and chemical products used over the platform's drilling history were transferred from archived well reports into a custom database, to which were added toxicological and safety data. Although the database contained many gaps, it established that only seven chemical products used at NWH were not in the lowest category of the Offshore Chemicals Notification Scheme, and were used in only small quantities. The study therefore supports the view that the main environmental risk posed by cuttings piles comes from hydrocarbon contamination. The (dated) well records could help future core sampling to be targeted at specific locations in the cuttings piles. Data from many platforms could also be pooled to determine generic 'discharge profiles.' Future study would benefit from the existence, in the public domain, of a standardised, 'legacy' database of chemical products.     

Effects of forest harvesting on the occurrence of landslides and debris flows in steep terrain of central Japan

Landslides and debris flows associated with forest harvesting can cause much destruction and the influence of the timing of harvesting on these mass wasting processes therefore needs to be assessed in order to protect aquatic ecosystems and develop improved strategies for disaster prevention. We examined the effects of forest harvesting on the frequency of landslides and debris flows in the Sanko catchment (central Japan) using nine aerial photo periods covering 1964 to 2003. These photographs showed a mosaic of different forest ages attributable to the rotational management in this area since 1912. Geology and slope gradient are rather uniformly distributed in the Sanko catchment, facilitating assessment of forest harvesting effects on mass wasting without complication of other factors. Trends of new landslides and debris flows correspond to changes in slope stability explained by root strength decay and recovery; the direct impact of clearcutting on landslide occurrence was greatest in forest stands that were clearcut 1 to 10 yr earlier with progressively lesser impacts continuing up to 25 yr after harvesting. Sediment supply rate from landslides in forests clearcut 1 to 10 yr earlier was about 10‐fold higher than in control sites. Total landslide volume in forest stands clearcut 0 to 25 yr earlier was 5·8 × 10³ m³ km^?2 compared with 1·3 × 10³ m³ km^?2 in clearcuts >25 yr, indicating a fourfold increase compared with control sites during the period when harvesting affected slope stability. Because landslide scars continue to produce sediment after initial failure, sediment supply from landslides continues for 45 yr in the Sanko catchment. To estimate the effect of forest harvesting and subsequent regeneration on the occurrence of mass wasting in other regions, changes in root strength caused by decay and recovery of roots should be investigated for various species and environmental conditions. Copyright © 2007 John Wiley & Sons, Ltd.     

Paleosols in Central Illinois as Potential Sources of Ammonium in Groundwater

Glacially buried paleosols of pre-Holocene age were evaluated as potential sources for anomalously large concentrations of ammonium in groundwater in East Central Illinois. Ammonium has been detected at concentrations that are problematic to water treatment facilities (greater than 2.0 mg/L) in this region. Paleosols characterized for this study were of Quaternary age, specifically Robein Silt samples. Paleosol samples displayed significant capacity to both store and release ammonium through experiments measuring processes of sorption, ion exchange, and weathering. Bacteria and fungi within paleosols may significantly facilitate the leaching of ammonium into groundwater by the processes of assimilation and mineralization. Bacterial genetic material (DNA) was successfully extracted from the Robein Silt, purified, and amplified by polymerase chain reaction to produce 16S rRNA terminal restriction fragment length polymorphism (TRFLP) community analyses. The Robein Silt was found to have established diverse and viable bacterial communities. 16S rRNA TRFLP comparisons to well-known bacterial species yielded possible matches with facultative chemolithotrophs, cellulose consumers, nitrate reducers, and actinomycetes. It was concluded that the Robein Silt is both a source and reservoir for groundwater ammonium. Therefore, the occurrence of relatively large concentrations of ammonium in groundwater monitoring data may not necessarily be an indication of only anthropogenic contamination. The results of this study, however, need to be placed in a hydrological context to better understand whether paleosols can be a significant source of ammonium to drinking water supplies.     

Tectonics of an extinct ridge-transform intersection,Drake Passage (Antarctica)

New swath bathymetric, multichannel seismic and magnetic data reveal the complexity of the intersection between the extinct West Scotia Ridge (WSR) and the Shackleton Fracture Zone (SFZ), a first-order NW-SE trending high-relief ridge cutting across the Drake Passage. The SFZ is composed of shallow, ridge segments and depressions, largely parallel to the fracture zone with an `en echelon' pattern in plan view. These features are bounded by tectonic lineaments, interpreted as faults. The axial valley of the spreading center intersects the fracture zone in a complex area of deformation, where N120° E lineaments and E–W faults anastomose on both sides of the intersection. The fracture zone developed within an extensional regime, which facilitated the formation of oceanic transverse ridges parallel to the fracture zone and depressions attributed to pull-apart basins, bounded by normal and strike-slip faults.On the multichannel seismic (MCS) profiles, the igneous crust is well stratified, with numerous discontinuous high-amplitude reflectors and many irregular diffractions at the top, and a thicker layer below. The latter has sparse and weak reflectors, although it locally contains strong, dipping reflections. A bright, slightly undulating reflector observed below the spreading center axial valley at about 0.75 s (twt) depth in the igneous crust is interpreted as an indication of the relict axial magma chamber. Deep, high-amplitude subhorizontal and slightly dipping reflections are observed between 1.8 and 3.2 s (twt) below sea floor, but are preferentially located at about 2.8–3.0 s (twt) depth. Where these reflections are more continuous they may represent the Mohorovicic seismic discontinuity. More locally, short (2–3 km long), very high-amplitude reflections observed at 3.6 and 4.3 s (twt) depth below sea floor are attributed to an interlayered upper mantle transition zone. The MCS profiles also show a pattern of regularly spaced, steep-inclined reflectors, which cut across layers 2 and 3 of the oceanic crust. These reflectors are attributed to deformation under a transpressional regime that developed along the SFZ, shortly after spreading ceased at the WSR. Magnetic anomalies 5 to 5 E may be confidently identified on the flanks of the WSR. Our spreading model assumes slow rates (ca. 10–20 mm/yr), with slight asymmetries favoring the southeastern flank between 5C and 5, and the northwestern flank between 5 and extinction. The spreading rate asymmetry means that accretion was slower during formation of the steeper, shallower, southeastern flank than of the northwestern flank.     

Fractal Analysis of the Complexity of United States Coastlines

Coastlines have long been used as a principal example of a natural feature that exhibits fractal structure. With the advent of large digitized databases, it has become possible to examine in detail large regions of coast and to examine differences in complexity, as measured by the fractal dimension, among regions. In this study, we have determined the fractal dimension of the Atlantic and Pacific coastlines of the conterminous United States. The traditional divider method was used in obtaining the fractal dimension of each coastline arc from the NOAA Medium-Resolution Shoreline Data Set. On average, the Atlantic coast has much higher fractal dimension than the Pacific coast. The results also indicate that the complexity of the Atlantic coast increases toward low latitudes. These results have implications for the interpretation of species distributions and diversity patterns along the coast and for the understanding of the dynamics of biotic recovery from mass extinctions.     

A copula-based multivariate analysis of Canadian RCM projected changes to flood characteristics for northeastern Canada

In the present work, climate change impacts on three spring (March–June) flood characteristics, i.e. peak, volume and duration, for 21 northeast Canadian basins are evaluated, based on Canadian regional climate model (CRCM) simulations. Conventional univariate frequency analysis for each flood characteristic and copula based bivariate frequency analysis for mutually correlated pairs of flood characteristics (i.e. peak–volume, peak–duration and volume–duration) are carried out. While univariate analysis is focused on return levels of selected return periods (5-, 20- and 50-year), the bivariate analysis is focused on the joint occurrence probabilities P1 and P2 of the three pairs of flood characteristics, where P1 is the probability of any one characteristic in a pair exceeding its threshold and P2 is the probability of both characteristics in a pair exceeding their respective thresholds at the same time. The performance of CRCM is assessed by comparing ERA40 (the European Centre for Medium-Range Weather Forecasts 40-year reanalysis) driven CRCM simulated flood statistics and univariate and bivariate frequency analysis results for the current 1970–1999 period with those observed at selected 16 gauging stations for the same time period. The Generalized Extreme Value distribution is selected as the marginal distribution for flood characteristics and the Clayton copula for developing bivariate distribution functions. The CRCM performs well in simulating mean, standard deviation, and 5-, 20- and 50-year return levels of flood characteristics. The joint occurrence probabilities are also simulated well by the CRCM. A five-member ensemble of the CRCM simulated streamflow for the current (1970–1999) and future (2041–2070) periods, driven by five different members of a Canadian Global Climate Model ensemble, are used in the assessment of projected changes, where future simulations correspond to A2 scenario. The results of projected changes, in general, indicate increases in the marginal values, i.e. return levels of flood characteristics, and the joint occurrence probabilities P1 and P2. It is found that the future marginal values of flood characteristics and P1 and P2 values corresponding to longer return periods will be affected more by anthropogenic climate change than those corresponding to shorter return periods but the former ones are subjected to higher uncertainties.