Towards quantitative evaluation of gas injection using time‐lapse seismic data

Of particular concern in the monitoring of gas injection for the purposes of storage, disposal or improved oil recovery is the exact spatial distribution of the gas volumes in the subsurface. In principle this requirement is addressed by the use of 4D seismic data, although it is recognized that the seismic response still largely provides a qualitative estimate of moved subsurface fluids. Exact quantitative evaluation of fluid distributions and associated saturations remains a challenge to be solved. Here, an attempt has been made to produce mapped quantitative estimates of the gas volume injected into a clastic reservoir. Despite good results using three accurately repeated seismic surveys, time‐delay and amplitude attributes reveal fine‐scale differences though large‐scale agreement in the estimated fluid movement. These differences indicate disparities in the nature of the two attributes themselves, which can be explained by several possible causes. Of most impact are the effects of processing and migration, wave interference effects and noise from non‐repeatability of the seismic surveys. This subject highlights the need for a more careful consideration in 4D acquisition, amplitude processing and use of true amplitude preserving attributes in quantitative interpretation.     

Modeling of air stripping from volatile organic compounds in biological treatment processes

The removal of volatile organic compounds from biological treatment processes occurs through several mechanisms. These include biodegradation, adsorption onto solids, and air stripping or volatilization to the atmosphere. Volatilization results in fugitive emissions to the atmosphere, which is largely uncontrolled. Recent regulations have called for increased evaluation and control of inadvertent volatile organic compounds emissions from treatment processes. The use oxygen as a parallel volatile compound is extremely useful for prediction of volatile organic compounds removal by air stripping. In this study, the simultaneous biodegradation and air stripping of volatile organic compounds, based on steady state mass balance are examined and a general approach to estimating the dominant removal mechanism is developed. A Monte Carlo simulation technique was used to estimate air stripping over a wide range of operating conditions. Several volatile organic compounds were selected for this study. The results showed the values drived from the model correspond with the experimental data for benzene, toluene, methylene chloride, trichloroethylene, and methyl isobutyl ketone.     

Uptake of platinum group elements by the marine macroalga, Ulva lactuca

Uptake of environmentally relevant platinum group elements (PGE) by the marine macroalga, Ulva lactuca, has been studied. Removal of nM concentrations of Rh(III), Pd(II) and Pt(IV) added to filtered sea water appeared to proceed via pseudo-first-order kinetics, with respective forward rate constants of either 0.0039 or 0.0042 h^− 1, 0.0058 or 0.0096 h^− 1 and 0.0017 or 0.0032 h^− 1, depending on whether an irreversible or reversible reaction was invoked. The (quasi-) equilibrium distribution coefficients, derived from linear fits to uptake (sorption) isotherms, were about 1400, 900 and 350 mL g^− 1 on a dry mass basis for Rh, Pd and Pt, respectively. With increasing sea water pH, over the range 7.9 to 8.4, uptake of Rh by Ulva increased considerably, whereas a small increase in Pt removal was observed; in contrast, uptake of Pd exhibited no clear dependence on pH. The percentage of metal taken up that was internalised within cells, evaluated by washing selected algal samples in 3 mM EDTA, was about 40% for Rh, 80% for Pd and 95% for Pt. Results of this study were interpreted in terms of what is known about the aqueous speciation of PGE in sea water. Thus, Rh exists as cationic hydrated chloride complexes which are readily adsorbed at the algal surface. Palladium has an exceptional affinity for organic ligands, and uptake (and internalisation) appears to be governed by competition for Pd²⁺ from aqueous and algal binding sites. Platinum (IV) exists predominantly as a series of (mainly) negatively charged chloride and mixed hydroxychloride complexes that have little propensity to interact with the algal surface; however, its high degree of internalisation requires at least some interaction with specific and perhaps physiologically active sites.     

Sur l'origine par altération du substratum schisteux de la minéralisation chlorurée des eaux d'une nappe côtière sous climat semi-aride (Chtouka-Massa,Maroc)

The origin of chloride ions in groundwater from the Chtouka-Massa plain (Morocco) was studied by using chemical and isotopic analyses of water, and petrographic and chemical analyses of rocks. It appears that the schist formation, which forms the basement of the studied aquifer, is the main source of the high Cl^? concentrations in groundwater. In these schists, chloride is, for a part, probably contained in biotites, and is released into groundwater through the weathering of these minerals. However, the exceptionally high chloride contents of these schists are difficult to explain if one does not assume that they also contain evaporitic-type minerals. To cite this article: S. Krimissa et al., C. R. Geoscience 336 (2004).     

Ba- and Ti-rich oxymica from nephelinites in the Middle Atlas Volcanic Province,northern Morocco

Mineralogy and Petrology - A Ba- and Ti-rich mica (up to 14.0 wt% BaO and 13.1 wt% TiO2) occurs in nephelinites from the Middle Atlas Volcanic Province, Morocco. The rocks show a...     

Conditioning DRASTIC model to simulate nitrate pollution case study: Hamadan–Bahar plain

One of the major causes of groundwater pollution in Hamadan–Bahar aquifer in western Iran is a non-point source pollution resulting from agricultural activities. Withdrawal of over 88% of drinking water from groundwater resources, adds urgency to the studies leading to a better management of water supplies in this region. In this study, the DRASTIC model was used to construct groundwater vulnerability maps based on the “intrinsic” (natural conditions) and “specific” (including management) concepts. As DRASTIC has drawbacks to simulate specific contaminants, we conditioned the rates on measured nitrate data and optimized the weights of the specific model to obtain a nitrate vulnerability map for the region. The performance of the conditioned DRASTIC model improved significantly (R ² = 0.52) over the intrinsic (R ² = 0.12) and specific (R ² = 0.19) models in predicting the groundwater nitrate concentration. Our study suggests that a locally conditioned DRASTIC model is an effective tool for predicting the region’s vulnerability to nitrate pollution. In addition, comparison of groundwater tables between two periods 30 years apart indicated a drawdown of around 50 m in the central plain of the Hamadan–Bahar region. Our interpretation of the vulnerability maps for the two periods showed a polluted zone developing in the central valley requiring careful evaluation and monitoring.     

Approaches to stress monitoring in deep boreholes for future CCS projects

There is no monitoring technology available to observe possible changes of stress in the rock mass of a CO₂ reservoir or its cap rock formations. Any development of a stress-monitoring technique must be related to the natural regional stress conditions and must be adjusted to the possibly changing in situ stress conditions due to CCS activity. As a step towards an in situ stress-monitoring probe, a lab scale device was developed and used for investigations on the practicability of a hard-inclusion tool for stress monitoring. In situ stress conditions, as deduced from the Altmark Gas Field, were applied to evaluate the efficiency and the limits of this stress-monitoring technique. At lab-scale the applied stresses resp. stress differences with moderate amounts of 9?C15?% of the vertical stress component Sv coincide sufficiently with the resulting strain answers of the hard inclusion tool (i.e., a steel tube corresponding to the liner in the borehole). Therefore, it was possible to re-calculate the stresses and to compare them with the applied ones. The resulting coincidence, however, can be disturbed at high pressure levels due to rock failure around the borehole with extended deformations. In addition, the results are influenced by the mechanical behaviour of the surrounding rock mass type. Nevertheless, a further development of a hard inclusion probe for monitoring of stress changes in deep boreholes can be successful and may be the only possible way to detect stress changes without fracturing damages in deep boreholes.