Heavy metal distribution in soil and plant in municipal solid waste compost amended plots

A field study was carried out to evaluate long-term heavy metal accumulation in the top 20 cm of a Tunisian clayey loam soil amended for four consecutive years with municipal solid waste compost at three levels (0, 40 and 80 t/ha/y). Heavy metals uptake and translocation within wheat plants grown on these soils were also investigated. Compared to untreated soils, compost-amended soils showed significant increases in the content of all measured metals: cadmium, chromium, copper, nickel, lead and zinc in the last three years, especially for plots amended with municipal solid waste compost at 80 t/ha/y. Wheat plants grown on compost-amended soils showed a general increase in metal uptake and translocation, especially for chromium and nickel. This heavy metal uptake was about three folds greater in plots amended at 80 t/ha/y as compared to plots amended at 40 t/ha/y. At the end of the experimental period, the diluting effect resulting from enhanced growth rates of wheat plants due to successive compost applications resulted in lower concentrations in the plants (grain part) grown on treated plots. On the other hand, chromium and nickel were less mobile in the aerial part of wheat plants and were accumulated essentially in root tissues. Plant/soil transfer coefficients for compost-amended treatments were higher than threshold range reported in the literature, indicating that there was an important load/transfer of metal ions from soils to wheat plants.     

ENSO, IOD and Indian Summer Monsoon in NCEP climate forecast system

El Ni?o-Southern Oscillation (ENSO), Indian Ocean Dipole (IOD) and Indian Summer Monsoon rainfall features are explored statistically and dynamically using National Centers for Environment Prediction (NCEP) Climate Forecast System (CFSv1) freerun in relation to observations. The 100?years of freerun provides a sufficiently long homogeneous data set to find out the mean state, periodicity, coherence among these climatic events and also the influence of ENSO and IOD on the Indian monsoon. Differences in the occurrence of seasonal precipitation between the observations and CFS freerun are examined as a coupled ocean–atmosphere system. CFS simulated ENSO and IOD patterns and their associated tropical Walker and regional Hadley circulation in pure ENSO (PEN), pure IOD (PIO) and coexisting ENSO-IOD (PEI) events have some similarity to the observations. PEN composites are much closer to the observation as compared to PIO and PEI composites, which suggest a better ENSO prediction and its associated teleconnections as compared to IOD and combined phenomenon. Similar to the observation, the model simulation also show that the decrease in the Indian summer monsoon rainfall during ENSO phases is associated with a descending motion of anomalous Walker circulation and the increase in the Indian summer monsoon rainfall during IOD phase is associated with the ascending branch of anomalous regional Hadley circulation. During co-existing ENSO and IOD years, however, the fate of Indian summer monsoon is dictated by the combined influence of both of them. The shift in the anomalous descending and ascending branches of the Walker and Hadley circulation may be somewhat attributed to the cold (warm) bias over eastern (western) equatorial Indian Ocean basin, respectively in the model. This study will be useful for identifying some of the limitations of the CFS model and consequently it will be helpful in improving the model to unravel the realistic coupled ocean–atmosphere interactions for the better prediction of Indian Summer Monsoon.     

A tensile damage model for rocks: Application to blast induced damage assessment

In this paper, an experimental methodology is presented using digital image techniques to assess the internal microcracks and to quantify the rock damage within rock cores. The second part of the work is devoted to the numerical estimation of the tensile blast induced damage evolution law. The set up methodology is then applied to a set of limestone cores which were sampled before and after a real field blast round. The image analysis algorithm which was developed during the present work is based on a segmentation technique that uses a particular thresholding. Petrographic parameters, such as crack number, orientation, extension, centroid position were computed as a first step aiming at a fine characterization of the cracked medium. The most important estimated parameter is the specific crack area which is defined as the ratio between the crack area and the total image area. This parameter was taken as the rock internal damage. A dynamic tensile damage ordinary partial differential equation is numerically solved and calibrated with the obtained data in order to derive a general blast induced damage evaluation law within the muckpile blocks. The application of the numerical algorithm to cores coming from sampled blocks before and after real field blasts allowed the estimation of damage parameter and dynamic stress evolution histories as well as an estimation of the microfracturing activation and growth energies used during the blast.     

Conservation laws and invariants of motion for nonlinear internal waves: part II

In this paper, we derive three conservation laws and three invariants of motion for the generalized Gardner equation. These conserved quantities for internal waves are the momentum, energy, and Hamiltonian. The approach used for the derivation of these conservation laws and their associated invariants of motion is direct and does not involve the use of variational principles. It can be easily applied for finding similar invariants of motion for other general types of KdV, Gardner, and Boussinesq equations. The stability and conservation properties of discrete schemes for the simulations of internal waves propagation can be assessed and monitored using the analytical expressions of the constants of motion that are derived in this work.     

Status of NCEP CFS vis-a-vis IPCC AR4 models for the simulation of Indian summer monsoon

National Centers for Environmental Prediction (NCEP) Coupled Forecast System (CFS) is selected to play a lead role for monsoon research (seasonal prediction, extended range prediction, climate prediction, etc.) in the ambitious Monsoon Mission project of Government of India. Thus, as a prerequisite, a detail analysis for the performance of NCEP CFS vis-a-vis IPCC AR4 models for the simulation of Indian summer monsoon (ISM) is attempted. It is found that the mean monsoon simulations by CFS in its long run are at par with the IPCC models. The spatial distribution of rainfall in the realm of Indian subcontinent augurs the better results for CFS as compared with the IPCC models. The major drawback of CFS is the bifurcation of rain types; it shows almost 80–90 % rain as convective, contrary to the observation where it is only 50–65 %; however, the same lacuna creeps in other models of IPCC as well. The only respite is that it realistically simulates the proper ratio of convective and stratiform rain over central and southern part of India. In case of local air–sea interaction, it outperforms other models. However, for monsoon teleconnections, it competes with the better models of the IPCC. This study gives us the confidence that CFS can be very well utilized for monsoon studies and can be safely used for the future development for reliable prediction system of ISM.     

Chemical Fractionation of Aluminium in the Sediments of El-Burullus Lagoon of Nile Delta,Egypt

A five step sequential extraction technique, following Tessier’s protocol has been applied to determine the chemical association of aluminium with major sedimentary phases (exchangeable, carbonate, manganese and iron oxides, organic and residual fraction) in four short sediment cores collected from El-Burullus lagoon of the Nile delta, Egypt. This study is a first approach of chemical fractionation of aluminium in one of the protective areas of the Mediterranean Sea of Egypt. The total metal content was also determined. The results of the fractionation study indicated that aluminium was mainly associated with the residual fraction (>95%). The organic and Fe–Mn oxide fractions were the next important phases. The exchangeable and carbonate fractions were less than 1%, limiting its potential toxicity as a pollutant. The geochemical analysis of aluminium forms reflected the lithogenic origin of this metal in the study area.     

Consistent scale-dependency of future increases in hourly extreme precipitation in two convection-permitting climate models

Climate Dynamics - Convection-permitting models (CPMs) have been proven successful in simulating extreme precipitation statistics. However, when such models are used to study climate change,...     

Role of convective and microphysical processes on the simulation of monsoon intraseasonal oscillation

Climate Dynamics - The study explores the role of ice-phase microphysics and convection for the better simulation of Indian summer monsoon rainfall (ISMR) and monsoon intraseasonal oscillation...