Storm-water hydrograph separation of run off from a mine-tailings impoundment formed by thickened tailings discharge at Kidd Creek, Timmins, Ontario

The Kidd Creek Cu---Zn sulphide mine is located near Timmins, Ontario. Mill tailings are thickened and deposited as a thickened slurry in a circular, conical-shaped pile with an area of approximately 1200 ha. Deposition of tailings as a thickened slurry results in a relatively uniform grain-size distribution and hydraulic conductivity, and a thick tension-saturated zone above the water table. The tailings are drained by numerous small, ephemeral stream channels, which have developed in a radial pattern. During storms, water from these streams collects in catchment ponds where it is held before treatment. The contribution of tailings pore water to the run off is of interest because of the potential for discharge of pore water containing high concentrations of Fe(II)-acidity, metals and SO₄ to the stream. Hydraulic head measurements, measurements of water-table elevation and groundwater flow modelling were conducted to determine the mechanisms responsible for tailings pore water entering the surface streams. Chemical hydrograph separation of storm run off in one of these streams, during three rainfall events, using Na and Cl as conservative tracers, indicates that the integrated tailings pore water fraction makes up between less than 1 % and 20% of the total hydrograph. This range is less than the maximum fraction of tailings pore water of 22–65% reported for run off from a conventional tailings deposit. At this site, preferential flow through permeable fractures may be the dominant mechanism causing discharge of tailings pore water to storm run off. Estimates of the mass of Fe(II) that discharges to the surface run off from the pore water range up to 2800 mg s⁻¹ during a moderate intensity, long duration rainfall event. The greatest potential for discharge of significant masses of solutes derived from the pore water exists during long duration rainfall events, when the water table rises to the surface over large areas of the tailings impoundment.     

Three-phase measurements of oil and gas trapping in sand packs

We measure the trapped saturations of oil and gas as a function of initial saturation in water-wet sand packs. We start with a water-saturated column and inject octane (oil), while water and oil are produced from the bottom. Once water production has ceased, air (gas) then enters from the top, allowing oil and gas to drain under gravity for different times. Finally water is then injected from the bottom to trap both oil and gas. The columns are sliced and the fluids analyzed using gas chromatography. We find that for high initial gas saturations more gas can be trapped in the presence of oil than in a two-phase (gas/water) system. The residual gas saturation can be over 20% compared to 14% in two-phase flow [Al Mansoori SK, Iglauer S, Pentland CH, Bijeljic B, Blunt MJ. Measurements of non-wetting phase trapping applied to carbon dioxide storage. Energy Procedia 2009;1(1):3173–80]. This is unlike previous measurements on consolidated media, where the trapped gas saturation is either similar or lower to that reached in an equivalent two-phase experiment. For lower initial gas saturation, the amount of trapping follows the initial-residual trend seen in two-phase experiments. The amount of oil trapped is insensitive to initial gas saturation or the amount of gas that is trapped, again in contrast to measurements on consolidated media. More oil is trapped than would be predicted from an equivalent two-phase (oil/water) system, although the trapped saturation is never larger than the maximum reached in two-phase flow (around 11%) [Pentland CH, Al Mansoori SK, Iglauer S, Bijeljic B, Blunt MJ. Measurement of non-wetting phase trapping in sand packs. In: SPE 115697, proceedings of the SPE annual technical conference and exhibition, Denver, Colorado, USA; 21–24 September 2008]. These initially surprising results are explained in the context of oil layer stability and the competition between snap-off and piston-like advance. In two-phase systems, displacement is principally by cooperative piston-like advance with relatively little trapping, whereas in consolidated media snap-off is generally more significant. However, oil layer collapse events during three-phase waterflooding rapidly trap the oil which acts as a barrier to direct water/gas displacement, except by snap-off, leading to enhanced gas trapping.     

Determination of Phosphate in Saudi Arabian Waters

The procedures for the determination of phosphate are based on the reduction of molybdophosphoric heteropoly acids using ascorbic acid. Measurements of the complex products formed with rhodamine B and chlorophenol red dyes and the reduced molybdophosphoric acid are made at 490 and 510 nm with molar absorptivities of 28571 and 20949 l/mol. cm with each dye, respectively. Phosphate could be determined in the concentration ranges of 0.44 to 1.21 and 0.44 to 1.32 μg/l PO₄-P with rhodamine B and chlorophenol red dyes, respectively. The results obtained are compared with those of molybdophosphoric acid with rhodamine B and chlorophenol red using stannous chloride as reducing agent. These procedures are used for the determination of phosphate in the Kingdom of Saudi Arabia.     

Integrating basin modeling with seismic technology and rock physics

We explore the link between basin modelling and seismic inversion by applying different rock physics models. This study uses the E‐Dragon II data in the Gulf of Mexico. To investigate the impact of different rock physics models on the link between basin modelling and seismic inversion, we first model relationships between seismic velocities and both (1) porosity and (2) effective stress for well‐log data using published rock physics models. Then, we build 1D basin models to predict seismic velocities derived from basin modelling with different rock physics models, in a comparison with average sonic velocities measured in the wells. Finally, we examine how basin modelling outputs can be used to aid seismic inversion by providing constraints for the background low‐frequency model. For this, we run different scenarios of inverting near angle partial stack seismic data into elastic impedances to test the impact of the background model on the quality of the inversion results. The results of the study suggest that the link between basin modelling and seismic technology is a two‐way interaction in terms of potential applications, and the key to refine it is establishing a rock physics models that properly describes changes in seismic signatures reflecting changes in rock properties.     

A Seasonal Statistical Evaluation of COAMPS® over the Arabian Gulf Region

A statistical evaluation of the Coupled Ocean/Atmosphere Mesoscale Prediction System (COAMPS^®) was performed over the Arabian Gulf region for the period, 1 August to 5 October, 2004. Verification skill scores of bias and root-mean-square error were estimated for surface variables and for vertical profiles to investigate any diurnal variations. The model predictions of boundary-layer heights are compared with the observations at Abu Dhabi, United Arab Emirates. The Middle East presents challenges to numerical weather prediction due to complex land-ocean-land mesoscale processes. An independent data set of surface measurements from 50 stations in the UAE was available from the Department of Water Resources Studies, Abu Dhabi for model verification. The results indicate a diurnal variation in the model errors. The errors are small considering the magnitudes of the observed variables. Errors in the coastal region can be attributed to the differences in the timing of the onset of sea and land breeze circulations in the simulations as compared to the observations. Errors are relatively smaller in the offshore locations.     

Impacts of Anthropogenic Land Use Changes on Nutrient Concentrations in Surface Waterbodies: A Review

Increased population leads to land use (LU) changes from natural to urban and agricultural LU. These disturbances not only decrease the natural treatment potential but they also worsen surface water quality (SWQ). The aim of this review is to assess studies about impacts of anthropogenic LU changes on levels of nutrient concentrations in surface waterbodies, highlighting the important parameters needed for an integrated simulation. The results reported in the literature are not always fully consistent. These contradictory results can sometimes be explained by field measurements under different climatic conditions, different features of landscapes, air deposition rates on ground surfaces, and groundwater flow interactions with surface water. Integrated modelling has been suggested to overcome these inconsistencies. Physical‐based and empirical models are the most popular approaches for LU‐SWQ studies. Generally, anthropogenic LU such as agricultural and urban areas usually enhances nutrient concentrations much more than natural lands such as forest and barren. Developing sustainable metropolitan areas instead of rural areas, establishing high‐standard wastewater treatment plants, and practicing efficient fertiliser application would ameliorate the poor nutrient conditions in SWQ. Riparian vegetation, grassed swales, and construction of artificial wetlands as buffer zones are the most promising natural water quality control measures.     

The Fill–Spill Hydrology of Prairie Wetland Complexes during Drought and Deluge

The fill–spill of surface depressions (wetlands) results in intermittent surface water connectivity between wetlands in the prairie wetland region of North America. Dynamic connectivity between wetlands results in dynamic contributing areas for runoff. However, the effect of fill–spill and the resultant variable or dynamic basin contributing area has largely been disregarded in the hydrological community. Long‐term field observations recorded at the St. Denis National Wildlife Area, Saskatchewan, allow fill–spill in the basin to be identified and quantified. Along with historical water‐level observations dating back to 1968, recent data collected for the basin include snow surveys, surface water survey and production of a light detection and ranging–derived digital elevation model. Data collection for the basin includes both wet and dry antecedent basin conditions during spring runoff events. A surface water survey at St. Denis in 2006 reveals a disconnected channel network during the spring freshet runoff event. Rather than 100% of the basin contributing runoff to the outlet, which most hydrological models assume, only approximately 39% of the basin contributes to the outlet. Anthropogenic features, such as culverts and roads, were found to influence the extent and spatial distribution of contributing areas in the basin. Historical pond depth records illustrate the effect of antecedent basin conditions on fill–spill and basin contributing area. A large pond at the outlet of the St. Denis basin, which only receives local runoff during dry years when upstream surface storage has not been satisfied, has pond runoff volumes that increase by a factor of 20 or more during wet years when upstream antecedent basin surface storage is satisfied and basin‐wide runoff contributes to the pond. Copyright © 2011 John Wiley & Sons, Ltd.     

The water balance of the Dead Sea: an integrated approach

The Dead Sea is the lowest spot on Earth. It is a closed saline lake located in the middle of the Jordan Rift Valley between Lake Tiberias and the Red Sea. Its major tributaries are the Jordan River itself and the Dead Sea side wadis. The Dead Sea has a unique ecosystem and its water has curative, industrial and recreational significance. The level of the Dead Sea has been continuously falling since the early 1930s at an average rate of 0·7 m per year. The water level, as of February 1998, is about 410·9 m below mean sea level. In this paper, a water balance model is developed for the Dead Sea by considering different hydrological components of this water balance, including precipitation, runoff, evaporation and groundwater flow. This model is calibrated based on historical levels of the Dead Sea. Different scenarios are investigated, including the proposed Dead Sea–Red Sea Canal. This project is supposed to halt the shrinking of the Dead Sea and restore it to pre‐1950 levels in the next century. Copyright © 2000 John Wiley & Sons, Ltd.     

Strategic groundwater resources planning in arid regions

A strategic approach is presented for future groundwater reservoir planning in arid regions where the evaluation of groundwater resources is restricted by scarcity of rainfall, data paucity, restrictive and unrepresentative methodologies, weak economies, almost nonexisting management and optimization programs, frequent groundwater quality variables along short distances, etc. This paper explains the necessary steps in preparing an effective strategic planning program that is expected to provide all the necessary data for identifying alternative solution scenarios especially in arid regions. It is shown on the basis of available scarce data that the risk model of these factors appears as the logarithmic normal probability distribution. The basic decision variables in groundwater storage and recharge planning are furnished with application to Wadi Fatimah in the western central part of the Kingdom of Saudi Arabia along the Red Sea coast. The approach given in this paper provides a basic example for future groundwater reservoir strategic use and management studies in the Kingdom in particular and in any part of the arid regions of the world, in general.