Nitrogen Mass Fraction and Stable Isotope Ratios for Fourteen Geological Reference Materials: Evaluating the Applicability of Elemental Analyser Versus Sealed Tube Combustion Methods

Thirteen commercially available silicate reference materials (RM) and one in‐house reference material, eleven of which have no previously published values, were analysed for nitrogen mass fraction and isotopic ratios with an Elemental Analyser (EA), and a Sealed Tube Combustion line, coupled to a continuous flow isotope ratio mass spectrometer (IRMS). These materials ranged from < 10 μg g^?1 to 1% m/m nitrogen mass fractions and δ¹⁵N of ?0.5 to +19.8‰. Existing nitrogen RM BHVO‐2, MS#5 and SGR‐1b were used to assess the accuracy of the data from the sealed tube combustion line, which was found to be in good agreement with existing published values. In contrast, the EA‐IRMS failed to fully liberate nitrogen from all silicate rocks and minerals (achieving a mean of 44 ± 10% nitrogen yield) resulting in kinetic fractionation of isotope values by ?1.4‰ on average. Therefore, sealed tube combustion is better suited for analyses of silicate‐bound nitrogen. The EA worked reliably for organic samples, but care should be taken when using the EA for silicate nitrogen research. Moving forward, it is recommended that BHVO‐2, Biotite‐Fe, FK‐N and UB‐N be used as quality control materials as they appear to be most reproducible in terms of nitrogen mass fraction (relative error < 10%, 1s), and isotopic composition (< 0.6‰, 1s).     

Intra-City Variation in Urban Morphology and Turbulence Structure in Helsinki, Finland

Most atmospheric boundary-layer theories are developed over vegetative surfaces and their applicability at urban sites is questionable. Here, we study the intra-city variation of turbulence characteristics and the applicability of boundary-layer theory using building-morphology data across Helsinki, and eddy-covariance data from three sites: two in central Helsinki (400 m apart) and one 4 km away from the city centre. The multi-site measurements enable the analysis of the horizontal scales at which quantities that characterize turbulent transport vary: (i) Roughness characteristics vary at a 10-m scale, and morphometric estimation of surface-roughness characteristics is shown to perform better than the often used rule-of-thumb estimates (average departures from the logarithmic wind profile are 14 and 44 %, respectively). (ii) The drag coefficient varies at a 100-m scale, and we provide an updated parametrization of the drag coefficient as a function of z/z _H (the ratio of the measurement height to the mean building height). (iii) The transport efficiency of heat, water vapour and CO₂ is shown to be weaker the more heterogeneous the site is, in terms of sources and sinks, and strong scalar dissimilarity is observed at all sites. (iv) Atmospheric stability varies markedly even within 4 km across the city: the median difference in nocturnal sensible heat fluxes between the three sites was over 50W m^?2. Furthermore, (v) normalized power spectra and cospectra do not vary between sites, and they follow roughly the canonical theory as developed over vegetated terrain.     

New exact cosmologies on the brane

We develop a method for constructing exact cosmological solutions in brane world cosmology. New classes of cosmological solutions on Randall–Sandrum brane are obtained. The superpotential and Hubble parameter are represented in quadratures. These solutions have inflationary phases under general assumptions and also describe an exit from the inflationary phase without a fine tuning of the parameters. Another class solutions can describe the current phase of accelerated expansion with or without possible exit from it.     

Models of solar irradiance variations: Current status

Regular monitoring of solar irradiance has been carried out since 1978 to show that solar total and spectral irradiance varies at different time scales. Whereas variations on time scales of minutes to hours are due to solar oscillations and granulation, variations on longer time scales are driven by the evolution of the solar surface magnetic field. Here the most recent advances in modelling of solar irradiance variations on time scales longer than a day are briefly reviewed.     

Recharge processes during snowmelt: An isotopic and hydrometric investigation

Results from hydrometric and isotopic investigations of unsaturated flow during snowmelt are presented for a hillslope underlain by well-sorted sands. Passage of melt and rainwater through the vadose zone was detected from temporal changes in soil water ²H concentrations obtained from sequential soil cores. Bypassing flow was indicated during the initial snowmelt phase, but was confined to the near-surface zone. Recharge below this zone was via translatory flow, as meltwater inputs displaced premelt soil water. Estimates of premelt water fluxes indicate that up to 19 per cent of the premelt soil water may have been immobile. Average water particle velocities during snowmelt ranged from 6.2 × 10^?7 to 1.1 × 10^?6 ms^?1, suggesting that direct groundwater recharge by meltwater during snowmelt was confined to areas where the premelt water table was within 1 m of the ground surface. Soil water ²H signatures showed a rapid response to isotopically-heavy rain-on-snow inputs late in the melt. In addition, spatial variations in soil moisture content at a given depth induced a pronounced lateral component to the predominantly vertical transport of water. Both factors may complicate isotopic profiles in the vadose zone, and should be considered when employing environmental isotopes to infer recharge processes during snowmelt.     

Temperature and precipitation trend analysis of the Iraq Region under SRES scenarios during the twenty-first century

Theoretical and Applied Climatology - Iraq is classified as the fifth most vulnerable country in the world to decreased water and food availability, extreme temperatures, and associated health...     

Mise en évidence et analyse d'une structure atlasique ennoyée au front de la Chaîne alpine tunisienne

The eastern Tunisian Atlas shows major subsurface faults: the Kairouan–Sousse Fault (FKS), to the north, and the El Hdadja fault (FEH), to the south. The FKS is an inherited structural trend active since Late Cretaceous times. This fault is an eastern splay of the Chérichira–Labeïd fault. It separates a large northern diapiric structure (Ktifa Diapir) from a subsident domain (the Kairouan–El Hdadja rim-syncline), with a pull-apart configuration to the south. The latter area, which appears to be an inherited weakness zone at the range border, has recorded a series of tectonic events that characterizes the Alpine structural development in Tunisia. To cite this article: S. Khomsi et al., C. R. Geoscience 336 (2004).     

The application of remote sensing and structural analysis in groundwater exploration in basement terrains, Darfur region, Western Sudan

Darfur region is one of the most vulnerable areas in Sudan that suffer from shortage in water supply. The objective of the current study is to utilize remote sensing techniques combined with the structural analysis to recognize the most potential fracture zones for groundwater occurrences in the hard rock terrains of Darfur region. The old ductile deformation features in Darfur region delineated from Landsat imageries are used for the structural analysis to determine and classify the fractures in the hard rock terrains of the region. Based on the structural analysis conducted in this study, Darfur region was divided into two domains—the western domain of the pre-Pan-African age that is affected by the two deformational phases (D1 and D2), and the eastern domain represented by the basement related to the Pan-African orogeny. The most potential fractures in the western domain are in the NW–SE and NE–SW trends that classified as extensional and release open fractures for the deformations D1 and D2. In the eastern domain, the main potential fractures for groundwater occurrence are in E–W and N–S directions that are classified as extensional and release open fractures of the deformation D3. From the results of the structural analysis, the main potential fracture systems in Darfur region trend are NW–SE, NE–SW, and E–W directions. The intersections of these fracture systems are the most promising targets for drilling, with consideration of the topography, the rates of recharge, and the underlying geology. The geophysical data and boreholes information in Zalingei and north of El Geneina areas in West Darfur confirm the results obtained from remote sensing data and structural analysis, in which the NW–SE, NE–SW, and E–W fractures trends are the most potential fractures in Darfur region.     

On the thermal instability in numerical models of the interstellar medium

We investigate with 3D hydrodynamical simulations the role played by thermal processes in the dynamical evolution of the interstellarmedium (ISM). A parametric approach of the coolingprocess shows that the observed mass fraction of the cold (< 300 K)and unstable gas (300K < T < 6000K) can not be produced by turbulentcompression or background heating of the medium alone. An analysis of theproperties of the clouds that are formed by the combined effect of the thermal and gravitational instability shows that the cloud’s scaling relations imprinted by the thermal instability (TI) are in good agreementwith observational values.