The Great Zab River catchment is a major left-bank tributary of the River Tigris and drains a substantial part of the Kurdistan Region, an autonomous region of Northern Iraq. Within Kurdistan, the water resources of the Great Zab River catchment are under pressure from population increase and are utilized for potable, domestic and agricultural and industrial supply. As with many parts of the world, effective management of water resources within Kurdistan is hindered by a lack of water quality data and established background concentrations. This study therefore represents the first regional survey of river water chemistry for the Great Zab River catchment and presents data on the spatial and temporal trends in concentrations of As, Ba, Ca, Cd, Co, Cr, Cu, Fe, Hg, Li, Mn, Mo, Ni, Pb, Sr, Zn, NO3?, SO42?, F?, Cl? and PO43?, in addition to pH, electrical conductivity, dissolved oxygen and turbidity. As a tool for underpinning the management and monitoring of water quality, background concentrations were defined for the Great Zab catchment using three methods. The influences of geogenic and anthropogenic controls upon spatial and temporal trends in water chemistry are also evaluated. The influence of geogenic loading from underlying bedrock was identifiable within the observed spatial trends, with the most notable differences found between waters sampled from the relatively more volcanic-rich Zagros zone to the north and those sampled from the lower catchment underlain by younger clay-, sand- and siltstones. The greatest anthropogenic influence, identifiable through elements such as Cl? and NO3?, is present in the more highly populated lower catchment. The background concentrations identified in the Great Zab catchment would be those expected as a result of geogenic loading with some anthropogenic influence and represent a more conservative value when compared to those such as the World Health Organization Maximum Admissible Concentration. However, background concentrations represent a powerful tool for identifying potential anthropogenic impacts on water quality and informing management of such occurrences. 相似文献
A hydrogeological conceptual model of the source, circulation pathways and temporal variation of a low-enthalpy thermal spring in a fractured limestone setting is derived from a multidisciplinary approach. St. Gorman’s Well is a thermal spring in east-central Ireland with a complex and variable temperature profile (maximum of 21.8 °C). Geophysical data from a three-dimensional(3D)audio-magnetotelluric(AMT) survey are combined with time-lapse hydrogeological data and information from a previously published hydrochemical analysis to investigate the operation of this intriguing hydrothermal system. Hydrochemical analysis and time-lapse measurements suggest that the thermal waters flow within the fractured limestones of the Carboniferous Dublin Basin at all times but display variability in discharge and temperature. The 3D electrical resistivity model of the subsurface revealed two prominent structures: (1) a NW-aligned faulted contact between two limestone lithologies; and (2) a dissolutionally enhanced, N-aligned, fault of probable Cenozoic age. The intersection of these two structures, which has allowed for karstification of the limestone bedrock, has created conduits facilitating the operation of relatively deep hydrothermal circulation (likely estimated depths between 240 and 1,000 m) within the limestone succession of the Dublin Basin. The results of this study support a hypothesis that the maximum temperature and simultaneous increased discharge observed at St. Gorman’s Well each winter is the result of rapid infiltration, heating and recirculation of meteoric waters within a structurally controlled hydrothermal circulation system.
While karst environments present methodological and interpretive challenges to archaeologists, they also provide some unique opportunities. One of these opportunities is the ability to date field walls by measuring divergent rates of bedrock dissolution underneath and adjacent to ancient walls. Field walls are traditionally difficult to date, either by using morphological typologies or through the association of diagnostic or chronometric materials. The method presented here, therefore, represents a valuable tool for archaeologists working in karst landscapes. The methodology is described along with a discussion of potential problems, drawing in particular upon evidence from the karstic terrain of the Burren in western Ireland. The methodology is then applied to a group of field walls on the Burren, which are shown to date to the Chalcolithic ‐ Early Bronze Age. 相似文献
Strombolian eruptions from the long-lived lava lake of Erebus volcano, Ross Island, Antarctica, generate repeating Very Long Period (VLP) signals, containing energy between approximately 30 and 5 s, that persist for several minutes and through the post-eruptive refilling of the lava lake. The initial approximately 10 s of this signal is moderately variable, particularly with respect to its initial polarity, while the following VLP coda has been observed to be stable since the earliest VLP observations were made (1996). To estimate forces and force couples consistent with the Erebus VLP signature, we perform moment tensor inversions for point sources using high signal-to-noise data stacks from the six-station, 18-component broadband seismographic network and Green's function forward calculations that incorporate topography. We infer a shallow (approximate depth of less than 400 m below the lava lake surface) source centroid that underlies the center to the northwestern rim of the main crater, east and north of the lava lake. Integrated Mii functions over the predominant (180 s) signal duration of VLP events show that the net scalar moments for these events are on the order of 4 × 1013 N m (corresponding to a moment magnitude mw ≈ 3) for typical sized VLP events. Moment rate tensors which characterize force couple components are dominated (85–97% of variance) by dilatational components. Approximately 25% of the data variance is attributable to single forces that are attributable to oscillatory reaction forces caused by fluid transport, however, the relative contributions of vertical forces and couples with this sparse network is poorly resolved for these shallow sources. The generally high degree of repeatability in the VLP signal across thousands of eruptions over the past decade indicates that the response of the conduit system to gas slug ascent and subsequent gravitational disequilibrium is stable, consistent with the generally unchanging surface manifestation of the convecting lava lake system, and arguing for a thermally and dynamically stable conduit system beneath the lava lake. 相似文献
Namurian cliff sections are described in detail. A minimum thickness of about 76 m is ascribed to Namurian A and 198 m and 104 m respectively to Namurian B and C. Faunal marker bands enable the Chokierian, Marsdenian and Yeadonian Stages to be recognised and the detailed structure to be worked out and this confirms the structural interpretation of Dixon. The succession is correlated and compared with adjacent areas in Pembrokeshire and South Wales. The Marsdenian includes a fauna of highly variable Sanguinolites. S. ovalis Hind is redescribed and a lectotype chosen. 相似文献