Electron density distribution and bond critical point properties for forsterite, Mg2 SiO4, determined with synchrotron single crystal X-ray diffraction data

A generalized X-ray scattering factor model experimental electron density distribution has been generated for the orthosilicate forsterite, using an essentially extinction and absorption free set of single crystal diffraction data recorded with intense, high energy synchrotron X-ray radiation (E=100.6 keV). A refinement of the model converged with an R(F)=0.0061. An evaluation of the bond critical point, bcp, properties of the distribution at the (3, –1) stationary points for the SiO and MgO bonded interactions, yielded values that agree typically within ~5%, on average, with theoretical values generated with quantum chemical computational strategies, using relatively robust basis sets. On the basis of this result, the modeling of the experimental distribution is considered to be adequate. As the bcp properties increase in magnitude, the MgO and SiO bonds decrease in length as calculated for a number of rock forming silicates. As asserted by Coppens (X-ray charge densities and chemical bonding. Oxford University Press, Oxford, 1997), large negative ²(r_c) values, characteristic of shared interactions involving first row atoms, may not be characteristic of closed shell covalent bonded interactions involving second row Si, P and S atoms bonded to O. This study adds new evidence to the overall relatively good agreement between theoretical bcp properties generated with computational quantum strategies, on the one hand, and experimental properties generated with single crystal high energy synchrotron diffraction data on the other. The similarity of results not only provides a basis for using computational strategies for studying and modeling structures, defects and the reactivity of representative structures, but it also provides a basis for improving our understanding of the crystal chemistry of earth materials and the character of the SiO bonded interaction.     

Conflict in Common: Heritage-making in Cape York

The outstanding natural and cultural values of Cape York have been acknowledged for decades, but those decades have been characterised by deep conflict. Non-government organisation intervention in local politics has seen a forceful push for nominating some or all of the Cape York Peninsula as a World Heritage Site. We illuminate the authorised heritage discourse at work in heritage-making, and highlight contested issues of ownership, governance, authenticity, and value. These themes contribute to the possibility of marginalising the voices of local people who wish to contribute to heritage-making in Cape York. Politics infuses all aspects of heritage-making in Cape York, and the specific experiences on Cape York reflect larger political processes occurring in World Heritage discourse. The paper draws on interviews undertaken in May and June 2012.     

The organic geochemistry of chrysotile asbestos from the Eastern Townships,Quebec

Extractions of selected specimens of chrysotile from the Eastern Townships of Quebec yielded small quantities of organic material. Infrared and gas Chromatographic studies indicate the presence of predominantly n-alkanes. These were probably derived by distillation from Precambrian sediments although a magmatic origin is not completely ruled out. Sample collection, handling, methods of analysis and problems associated with such studies of chrysotile are discussed.     

Crystallization and eruption ages of Breccia Museo (Campi Flegrei caldera,Italy) plutonic clasts and their relation to the Campanian ignimbrite

The Campi Flegrei volcanic district (Naples region, Italy) is a 12-km-wide, restless caldera system that has erupted at least six voluminous ignimbrites during the late Pleistocene, including the >300 km³ Campanian ignimbrite (CI) which originated from the largest known volcanic event of the Mediterranean region. The Breccia Museo (BM), a petrologically heterogeneous and stratigraphically complex volcanic deposit extending over 200 km² in close proximity to Campi Flegrei, has long remained contentious regarding its age and stratigraphic relation to the CI. Here, we present crystallization and eruption ages for BM plutonic ejecta clasts that were determined via uranium decay series and (U–Th)/He dating of zircon, respectively. Despite mineralogical and textural heterogeneity of these syenitic clasts, their U–Th zircon rim crystallization ages are indistinguishable with an average age of 49.7 ± 2.5 ka (2σ errors; mean square of weighted deviates MSWD = 1.2; n = 34). A subset of these crystals was used to obtain disequilibrium-corrected (U–Th)/He zircon ages which average 41.7 ± 1.8 ka (probability of fit P = 0.54; n = 15). This age closely overlaps with published CI ⁴⁰Ar/³⁹Ar eruption ages (40.6 ± 0.1 ka) after recalibration to recently revised flux monitor ages. Concordant eruption ages for BM and CI agree with previous chemostratigraphic and paleomagnetic correlations, suggesting their origin from the same eruption. However, they are at variance with recalibrated ⁴⁰Ar/³⁹Ar ages which have BM postdate CI by 3 ± 1 ka. BM syenites show similar geochemical and Sr–Nd isotopical features of pre-caldera rocks erupted between 58 and 46 ka, but are distinctive from subsequent caldera-forming magmas. Energy-constrained assimilation and fractional crystallization modeling of Nd–Sr isotopic data suggests that pre-caldera magmas formed a carapace of BM-type intrusions in a mid-crust magma chamber (≥8 km depth) shielding the younger CI magma from contamination by Hercynian basement wall rocks. An ~41–50 ka hiatus in crystallization ages implies rapid solidification of these pre-CI intrusions. This argues against protracted pre-eruptive storage of a large volume of CI magma at shallow crustal levels.     

Tigers, trees and Tharu: An analysis of community forestry in the buffer zone of the Royal Chitwan National Park, Nepal

In the buffer zone of the Royal Chitwan National Park (RCNP), community forests represent a key land use to meet the objectives of the buffer zone concept. This article examines three diverse community forests surrounding the national park and explores how national policy has been mediated by emerging community forestry institutions to create different levels of resource access and benefit distribution both within and between local user groups. Mindful of recent critiques of community-based conservation, the analysis gives considerable attention to the dynamics of power relations and inequality. The extent to which property rights have been transferred to the local level is evaluated and to whom power has been devolved in the process is assessed. The distribution of benefits arising from community forestry is critically examined. It seems that the current system for community forestry creates sufficient incentives for local cooperation due to the potential for increased access to important resources and a high perception of ownership of community forests among the communities. However, emerging institutions vary in the extent to which they reproduce favourable resource access conditions for elites and benefit distribution does seem to be skewed in favour of the wealthy and higher castes, even where management practices on the surface appear fair. National policy creates sufficient but not necessary conditions for achieving downward accountability, transparency and fairness. Greater attention to these issues is needed for buffer zone community forestry to better serve the poor and marginalised populations within user groups.