Rapid quantification of humic and fulvic acids by HPLC in natural waters

A simple method based on high-performance size-exclusion chromatography (HPSEC) has been developed for rapid quantification of humic and fulvic acids (HA and FA) in stream waters. A Tsk-gel column was used to separate natural dissolved organic matter (DOM) into two components: peak A and B. In terms of HPSEC chromatograms and fluorescence patterns, peak A and B were similar to the corresponding XAD-extracted HA and FA, respectively. It is suggested that peak A fraction mainly consisted of HA, and peak B fraction FA. The similar separation of HA and FA using HPSEC and a conventional XAD method suggests the consistency of molecular size distribution and physical–chemical properties of DOM. HPSEC offers a simple and rapid method for the quantification of HA and FA instead of tedious extractions of humic substances. Analyses of natural water samples show that the calculation of HA/FA based on UV absorbance was under- or over-estimated, the calibration using the extracted HS allows a more accurate quantification. The fast screening of HA and FA provides useful quantitative and qualitative information that can be used in environmental or monitoring studies.     

Paleolimnological studies of saline lakes

Salt water lakes are located in arid to semi-arid regions where evaporation rates exceed precipitation rates. As such, saline lakes are very sensitive to changes in their hydrological cycle. Research into the current limnology of saline lakes is expanding as population growth in these regions increases. Emerging concerns include water diversions, eutrophication, and toxic substances. Paleolimnological investigations of saline lakes are providing valuable new information on paleoclimate and paleohydrology. Such studies may allow for better predictions of the environmental consequences of global warming and for a better understanding of past climate change. Paleolimnological studies may also provide some insight to more recent, anthropogenic perturbations in the arid and semi-arid regions of the world.This publication is the introduction to a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. The conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor.     

The quaternary glacial history of the Lahul Himalaya,northern India

This paper presents the first glacial chronology for the Lahul Himalaya, Northern India. The oldest glaciation, the Chandra Glacial Stage, is represented by glacially eroded benches at altitudes greater than 4300 m above sea-level. This glaciation was probably of a broad valley type. The second glaciation, the Batal Glacial Stage, is represented by highly weathered and dissected lateral moraines, which are present along the Chandra valley and some of its tributaries. This was an extensive valley glaciation. The third major glaciation, the Kulti Glacial Stage, is represented by well-preserved moraines in the main tributary valleys of the Chandra valley. This represents a less extensive valley glaciation. Two minor glacial advances, the Sonapani I and II, are represented by small sharp-crested moraines, which are within a few hundred metres or few kilometres of the present-day glaciers. The change in style and extent of glaciation is attributed to an increase in aridity throughout the Quaternary, due either to global climatic change or uplift of the Pir Panjal mountains to the south of Lahul, which restricted the northward penetration of the south Asian summer monsoon. © 1996 John Wiley & Sons, Ltd.     

The use of solar faculae in studies of the sunspot cycle

Comparison of the long-term variation of photospheric faculae areas with that of sunspots shows that studies of faculae provide both complementary and supplementary information on the behaviour of the solar cycle. Detailed studies of the development of sunspots with respect to faculae show that there is a high degree of order over much of a given cycle, but marked differences from cycle to cycle. Within a cycle the relationship between spot and faculae areas appears to be similar for the N and S solar hemispheres, and over the early stages of a cycle it is directly related to the magnitude of the maximum sunspot number subsequently attained in that cycle.This result may well have predictive applications, and formulae are given relating the peak sunspot number to simple parameters derived from this early developmental stage. Full application to the current cycle 21 is denied due to the cessation of the Greenwich daily photoheliographic measurements, but use of the cruder weekly data suggests a maximum smoothed sunspot number of 150 ± 22.The effects of the incompatibility of the spot and faculae data, in that faculae are unobservable over a large fraction of the solar disc and also do not always develop associated spots, have been examined in a detailed study of two cycles and shown not to vitiate the results.Now at NOAA, Environmental Data Service, NGSTDC, Boulder, Colo. 80302, U.S.A.     

Estimation of the average surface heat flux over an inhomogeneous terrain from the vertical velocity variance

An indirect method of estimating the surface heat flux from observations of vertical velocity variance at the lower mid-levels of the convective atmospheric boundary layer is described. Comparison of surface heat flux estimates with those from boundary-layer heating rates is good, and this method seems to be especially suitable for inhomogeneous terrain for which the surface-layer profile method cannot be used.     

Stress orientation to 5 km depth in the basement below Basel (Switzerland) from borehole failure analysis

A vertical profile of maximum horizontal principal stress, SHmax, orientation to 5 km depth was obtained beneath the Swiss city of Basel from observations of wellbore failure derived from ultrasonic televiewer images obtained in two 1 km distant near-vertical boreholes: a 2755 m exploration well (OT2) imaged from 2550 m to 2753 m across the granitic basement-sediment interface at 2649 m; and a 5 km deep borehole (BS1) imaged entirely within the granite from 2569 m to 4992 m. Stress-related wellbore failure in the form of breakouts or drilling-induced tension fractures (DITFs) occurs throughout the depth range of the logs with breakouts predominant. Within the granite, DITFs are intermittently present, and breakouts more or less continuously present over all but the uppermost 100 m where they are sparse. The mean SHmax orientations from DITFs is 151 ± 13° whereas breakouts yield 143 ± 14°, the combined value weighted for frequency of occurrence being N144°E ± 14°. No marked depth dependence in mean SHmax orientation averaged over several hundred meters depth intervals is evident. This mean SHmax orientation for the granite is consistent with the results of the inversion of populations of focal mechanism solutions of earthquakes occurring between depths of 10–15 km within regions immediately to the north and south of Basel, and with the T-axis of events occurring within the reservoir (Deichmann and Ernst, this volume). DITFs and breakouts identified in OT2 above and below the sediment-basement interface suggest that a change in SHmax orientation to N115°E ± 12° within the Rotliegendes sandstone occurs near its interface with the basement. The origin of the 20–30° change is uncertain, as is its lateral extent. The logs do not extend higher than 80 m above the interface, and so the data do not define whether a further change in stress orientation occurs at the evaporites. Near-surface measurements taken within 50 km of Basel suggest a mean orientation of N–S, albeit with large variability, as do the orientation of hydrofractures at depths up to 850 m within and above the evaporite layers and an active salt diapir, also within 50 km of Basel. Thus, the available evidence supports the notion that the orientation of SHmax above the evaporites is on average more N–S oriented and thus differs from the NW–SE inferred for the basement from the BS1/OS2 wellbore failure data and the earthquake data. Changes in stress orientation with depth can have significant practical consequences for the development of an EGS reservoir, and serve to emphasise the importance of obtaining estimates from within the target rock mass.