Geochemistry and Mineralogy of Paleocene Coal from the Padhrar and Darra Adam Khel Coalfields of Pakistan

Pakistan is rich in coal resources, which amount to around 186 billion tons. The Paleocene Padhrar and Darra Adam Khel coalfields are located in the Central Salt Range Punjab Province and the Khyber Pakhtunkhwa Province, Pakistan, respectively. Padhrar coal has not been studied in detail and the Darra Adam Khel coalfields are newly-discovered, so no research has been done, due to security considerations. In this study, an attempt has been made to study the geochemical and mineralogical characteristics of the Padhrar and Darra Adam Khel coals, in order to learn about the coal quality, element enrichment mechanism, sedimentary medium conditions and potentially valuable elements for coal utilization. The Padhrar and Darra Adam Khel coals are low to medium ash, low moisture content, high in volatiles and high total sulfur coal. The vitrinite reflectance in Darra Adam Khel coal is higher than in Padhrar coal, indicating either a greater burial depth or the effects of Himalayan tectonism. The vitrinite content is dominant in the Padhrar and Darra Adam Khel coals, followed by inertinite and liptinite, the major minerals including quartz, clay minerals, calcite and pyrite. The trace elements Ni, As, Be Zn, Ge, Mo, Ta, W, Co and Nb, Sn, Hf, Ta, Pb, Th, Cd, In, Be, V, Cr, Zr, Ag, Li, W and Co are concentrated in some of the Padhrar and Darra Adam Khel coal samples, respectively. The Padhrar coal shows positive Ce, Eu and Gd anomalies, with most of the Darra Adam Khel coal showing negative Ce, Eu and positive Gd anomalies with high LREE. The Al2O3/TiO2 values indicate that the sediment source of the Padhrar and Darra Adam Khel coals is mostly related to intermediate igneous rocks. The Sr/Ba, SiO2 + Al2O3, Fe2O3 + CaO + MgO/SiO2 + Al2O3 and high sulfur content in the Padhrar and Darra Adam Khel coals indicate epithermal and marine water influence with a tidal flat, coal-forming environment and a deltaic coal-forming environment, respectively.     

Long-term changes in physical and chemical conditions of nutrient-poor lakes along a latitudinal gradient: is there a coherent phytoplankton community response?

To evaluate climate and atmospheric deposition induced physical and water chemical changes and their effects on phytoplankton communities, we used complete time series (14 years, monthly measurements during the growing season) of 18 physical and chemical variables and phytoplankton data from 13 nutrient-poor Swedish reference lakes along a latitudinal gradient. We found numerous strong significant changes over time that were most coherent among lakes for sulfate concentrations, conductivity, calcium, magnesium, chloride, potassium, water color, surface water temperature and the intensity of thermal stratification. Despite these pronounced coherent physical and water chemical changes over Sweden, the phytoplankton biomass and species richness of six phytoplankton groups, measured at the same time as the water chemical variables, showed only few and weak significant changes over time. The only coherent significant change over Sweden, occurring in seven lakes, was observed in the species richness of chlorophytes. The number of chlorophyte taxa significantly declined over Sweden. Using a partial least square model for each lake, we attributed the decline primarily to an increase in water temperatures and water color, which were among the most important variables for the model performance of each lake. All other taxonomic groups were driven primarily by non-coherent changes in nutrient concentrations, pH and probably also non-coherent grazing pressure. We concluded that coherent phytoplankton responses can only be achieved for taxonomic groups that are driven primarily by coherent physical/chemical changes. According to our study, chlorophytes belong to such a group, making them possible global change indicators. Our findings give new insights into global change effects on different phytoplankton taxonomic groups in nutrient-poor lakes.     

Satellite remote sensing for mapping vegetation in New Zealand freshwater environments: A review

Freshwater environments in New Zealand provide a range of ecosystem services and contain important biodiversity. Managing these environments effectively requires a comprehensive inventory of the resource and cost-effective tools for regular monitoring. The complex and extensive margins of natural water bodies make them difficult to sample comprehensively. Problems thus occur with extrapolating point-specific sampling to accurately represent the diversity of vegetation in large freshwater bodies. Mapping freshwater vegetation using satellite remote sensing can overcome problems associated with access, scale and distribution, but it requires high-resolution images that have appropriate spectral characteristics. This paper provides an overview of the optical satellite data characteristics required for mapping riparian, submerged and emergent vegetation associated with freshwater environments in New Zealand.     

Geotechnical assessment of cut slopes in the landslide-prone Himalayas: rock mass characterization and simulation approach

Natural Hazards - The roadway networks serve as arteries for the ongoing socio-economic activities within the Himalayan region. The perilous conditions of geologically active and fragile terrain...     

Treatment of Collapsibility of Gypseous Soils by Dynamic Compaction

Gypseous soils are distributed in vast areas and various regions of Iraq and other countries. Many foundation failure problems that occur in these soils are associated with percolation of water and dissolution of gypsum. Many attempts were made by several researchers to treat and improve the properties of gypseous soils to decrease the dissolution of gypsum and collapse potential of these soils. The purpose of the present work is to investigate the effect of dynamic compaction process on the behaviour of gypseous soils. Extensive laboratory tests are carried out to study the geotechnical properties and the behaviour of three gypseous soils of different gypsum contents; 60.5, 41.1 and 27?%. The tests included compaction characteristics, compressibility, and collapsibility tests for samples tested before and after treatment by dynamic compaction process under different number of blows, falling weights and heights of falling of the weights. Three weights are used to compact the samples, namely; 2, 3 and 5?kg. The number of blows is varied between 20 and 40, while three heights of drop are tried (35, 50 and 65) cm. The results showed that the best improvement in compressibility is achieved when the sample is compacted by 20 blows; above this number a negligible decrease in the compression index C_C is obtained. As the gypsum content increases, the dynamic compaction has greater effect on improvement of compressibility of the soil, while as the height of drop increases, the compression index C_C decreases.     

Investigating the flood damages in Lower Indus Basin since 2000: Spatiotemporal analyses of the major flood events

While historically significant for ancient civilizations, the Indus basin is also known for its floods and complex anthropogenic management history. Resulting from years of modifications by the pre-British era Mughal rulers followed by the post-partition division of river waters among the two neighbors, India and Pakistan, Pakistan faces severe management and financial challenges of water management. This study investigates the intricacies arising from this complicated management doctrine for the lower Indus basin. A detailed remote sensing-based analysis of the significant floods to hit the lower Indus basin since 2000 has been provided. Flood years were identified, and Moderate Resolution Imaging Spectroradiometer (MODIS) data for the years 2003, 2005, 2006, 2010, 2011, 2012, 2015, and 2016 were used to map their spatiotemporal extents. Almost all the flood water accumulated in the north is released in one river channel of the lower Indus basin. Further, the challenges were exacerbated due to the excessive rainfall in 2011 and 2012 in southeastern Sindh. A trend analysis of rainfall data shows an increase in the southern basin in the last 21 years, particularly toward the central plains and Sindh Province. The floodwater accumulated in the lower basin for as many as?~?425 days on average, stretching to?~?800 days of stagnancy in some places. The water stagnation period has been the highest in the river floodplain, highly populated and cultivated. The analyses of the current study suggest that the riverine channel has been better managed after the 2010 floods; however, the monsoon’s shift in 2011 and 2012 led to widespread disaster in low-lying regions of Sindh Province.

     

Extremely energetic 4B/X17.2 flare and associated phenomena

We observed 4B/X17.2 flare in Hα from super-active region NOAA 10486 at ARIES, Nainital. This is one of the largest flares of current solar cycle 23, which occurred near the Sun’s center and produced extremely energetic emission almost at all wavelengths from γ-ray to radio-waves. The flare is associated with a bright/fast full-halo earth directed CME, strong type II, type III and type IV radio bursts, an intense proton event and GLE. This flare is well observed by SOHO, RHESSI and TRACE. Our Hα observations show the stretching/de-twisting and eruption of helically twisted S shaped (sigmoid) filament in the south-west direction of the active region with bright shock front followed by rapid increase in intensity and area of the gigantic flare. The flare shows almost similar evolution in Hα, EUV and UV. We measure the speed of Hα ribbon separation and the mean value is ∼ 70 km s^-1. This is used together with photospheric magnetic field to infer a magnetic reconnection rate at three HXR sources at the flare maximum. In this paper, we also discuss the energetics of active region filament, flare and associated CME.     

Some factors controlling the concentration of uranium in the world ocean

Low-temperature alteration of the oceanic crust is a major sink for the U supplied to the oceans and may account for about 50% of the estimated present-day input of this element. Uranium uptake by organic-rich sediments and coexisting phosphorites on continental margins is also important and may remove in excess of 10% of the total supply. High-temperature alteration of oceanic basalts, metalliferous sediments, carbonate sediments, and sediments in anoxic basins deeper than 200 m play a relatively minor role in the removal of U. Each of these sinks is responsible for the uptake of less than 5% of the overall input.