Abundance of 17 trace elements in carbonaceous chondrites

Seventeen trace elements (Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Rb, Re, Sb, Se, Te, Tl, U and Zn) were measured by neutron activation analysis in 8 C1 samples (1 Alais, 3 Ivuna, 4 Orgueil) and in 3 C2 samples (one each of Mighei, Murchison, Murray). The results show far less scatter than earlier literature data. The standard deviation of a single measurement from the mean of 8 C1 samples lies between 2 and 14 per cent, except for the following 4 elements: Au ±18 per cent, Ag ±22 per cent, Rb ±19 per cent and Br ±33 per cent. The first two probably reflect contamination and sample heterogeneity, the last two, analytical error. Apparently C1 chondrites have a far more uniform composition than some authors have claimed.The new data suggest significant revisions in cosmic abundance for the following elements (old values in parentheses): Zn 1250 (1500), Cd 1.51 (2.12), Ir 0.72 (0.43) atoms/10⁶ Si atoms. The Br value is also lower, 6.8 vs 20.6, but may be affected by analytical error.Relative to C1 chondrites, the C2 chondrites Mighei, Murchison and Murray are depleted in volatile elements by a factor of 0.508 ± 0.038, much more constant than indicated by oldor data. Ordinary chondrites also show a more uniform depletion relative to the new C1 data. The mean depletion factor of Sb, F, Cu, Ga, Ge, Sn, S, Se, Te and Ag is 0.227 ± 0.027 in H-chondrites. This constancy further strengthens the case for the two-component model of chondrite formation.     

Lunar crater Copernicus: search for debris of impacting body at Apollo 12 site

In an attempt to characterize meteoritic material at the Apollo 12 site, 4 KREEP concentrates from soil 12033 have been analyzed by neutron activation analysis. These contain a meteoritic component in which siderophile Ir, Re and Sb are depleted by about a factor of 2, while volatile Se, Zn, Ag and Bi are depleted by a factor of more than 5 relative to Au. This pattern does not closely resemble any major chondrite or iron meteorite group, but is very similar to that observed in high-alkali samples from Apollo 14. The meteoritic component in KREEP at both sites is therefore predominantly derived from Imbrian ejecta. However, a second, small component of primitive composition seems to be present in Apollo 12 KREEP, judging from the slight, uniform enrichments in Ir, Re, Sb, Se and Zn relative to Au. This component does not seem to be due to micrometeorites. If it is attributed to the Copernican projectile, the crater Copernicus may have been formed by a cometary nucleus, 4 km in diameter, with an impact velocity of 30–40 km/sec. These conclusions depend critically on the assumption that the meteoritic component in Apollo 12 KREEP is representative of the entire impact.     

Chemical fractionations in meteorites—VI. Accretion temperatures of H-, LL- and E-chondrites,from abundance of volatile trace elements

Extending our earlier work on 11 L-chondrites, we have measured 9 volatile elements (Ag, Bi, Cs, In, Rb, Tl, Se, Cd, Zn) by neutron activation analysis in 11 LL- and 10 E-chondrites; the first 6 elements also in 22 H-chondrites. The observed fractionation patterns are consistent with theoretical condensation curves and hence were apparently established during condensation from the solar nebula. Ordinary chondrites seem to have accreted between 420 and 500°K at $\text{P ≈ 10}{}^{\mathrm{?5}}$ atm; enstatite chondrites, at 460 to 520°K and P ≈ 5 x? 10^?4 atm. The values for ordinary chondrites agree with O¹⁸-based temperatures by Onuma. et al. (1972) and with other characteristics such as Fe²⁺ content, presence of FeS and absence of Fe₃O₄.A few detailed trends were noted. Seven of the 54 meteorites seem to contain small amounts of a material enriched in Ag, Bi and especially T1; possibly a late condensate from a region depleted in metal. Silver shows considerable scatter, which suggests inhomogeneous distribution in the meteorites. Xenon correlates with In approximately as expected for equilibrium solubility, with some differences (petrologic type 3; E-chondrites) attributable to mineralogical factors. Meteorites of higher petrologic types are slightly deficient in Xe, probably due to gas losses during metamorphism. Cesium also appears to have been redistributed during metamorphism.Various features of the two-component model are critically examined in the light of the latest evidence. Apparently this model still is an adequate approximation of reality.     

The Iceland 1986 GPS geodetic survey: tectonic goals and data processing results

Summary The 1986 GPS survey of Iceland aimed to: (1) establish geodetic control in the South Iceland Seismic Zone (SISZ), to study destructive earthquakes there, (2) measure a country-wide network to form the basis of a new first order national network. 51 points were surveyed, with 20–30 km spacings within the SISZ and 100 km spacings elsewhere. The data were processed using the Bernese GPS software Version 3. Analysis was difficult due to poor satellite geometry and short-period ionospheric variations. However, an ambiguity-fixed, ionosphere-free solution gave accuracies of 1–2 cm in the horizontal and 2–3 cm in the vertical for the SISZ network and an ambiguity-free, ionosphere-free solution yielded accuracies of about 5 cm for the country-wide network. An ionosphere-free solution for the total survey with ambiguities fixed for the SISZ network only gave marginal additional improvements over the two separate solutions. GPS surveying has continued annually in Iceland with measurements in South Iceland in 1989 and 1992 (Hackman 1991; Sigmundsson 1992) and in North Iceland in 1987, 1990 and 1992 (Jahn et al. 1992; Foulger et al. 1992).     

Three-dimensional strain analysis in physical models of geological structures

A method is outlined for calculating three-dimensional finite strain in physical models of geological structures containing passive strain markers. This method makes it possible to determine the three-dimensional strain pattern in models of structures that lack any of the types of symmetry (such as that imparted by cylindrical folding) that simplified calculations in previous work. The strain markers in the new method are in the shape of stubby rectangular prisms or cubes. These form a three-dimensional grid or array occupying each of the active layers in a model (e.g., for a simple two-layer gravitationally unstable system, one grid for the overburden layer and one for the buoyant layer). Each of the grids can be described by positions of three families of “strain marker surfaces”, which are contacts between layers of strain markers.

After deformation, the model is serial-sectioned horizontally and the traces of the strain marker surfaces on the sections are digitized. The strain state is calculated at each of several hundred points arranged in a three-dimensional “output grid” extending throughout the mechanically active part of the model. An interpolation procedure is used to estimate the spacing and orientation of the strain marker surfaces in the vicinity of each of the output grid points. The following quantities are determined for each of the three families of strain marker surfaces:

1. (1) the local horizontal orientation of the strain marker surfaces;

2. (2) the local spacing of the surfaces; and

3. (3) the local inclination of the surfaces, calculated from their change in position from the serial section above, to the serial section below, the output grid point.

This information is used to generate a parallelepiped representing the strain marker geometry in the neighbourhood of the output grid point. The edges of the parallelepiped are equivalent to the coefficients of the strain matrix, from which the three principal strain magnitudes and orientations are readily derived.     

Behavior and effects of phosphorus in the system Na2O−K2O−Al2O3−SiO2−P2O5−H2O at 200 MPa(H2O)

The addition of phosphorus to H₂O-saturated and initially subaluminous haplogranitic (Qz–Ab–Or) compositions at 200 MPa(H₂O) promotes expansion of the liquidus field of quartz, a marked decrease of the solidus temperature, increased solubility limits of H₂O in melt at low phosphorus concentrations, and fractionation of melt out of the haplogranite plane (projected along an Or₂₈ isopleth) toward a peralkaline, silica-poor but quartz-saturated minimum composition. The partition coefficient for P₂O₅ between aqueous vapor and melt with an ASI (aluminum saturation index, mol Al/[mol Na+K])=1 is negligible (0.06), and consequently so are the effects of phosphorus on other melt-vapor relations involving major components. Phosphorus becomes more soluble in vapor, however, as the concentration of a NaPO₃ component increases via the fractionation of melt by crystallization of quartz and feldspar. The experimental results here corroborate existing concepts regarding the interaction of phosphorus with alkali aluminosilicate melt: phosphorus has an affinity for alkalis and Al, but not Si. Phosphorus is incorporated into alkali feldspars by the exchange component AlPSi_-2. For subaluminous compositions (ASI=1), the distribution coefficient of phosphorus between alkali feldspar and melt, D[P]Af/m, is 0.3. This value increases to D[P]Af/m=1.0 at a melt ASI value of 1.3. The increase in D[P]Af/m with ASI is expected from the fact that excess Al promotes the AlPSi_-2 exchange. With this experimental data, the P₂O₅ content of feldspars and whole rocks can reveal important facets of crystallization and phosphorus geochemistry in subaluminous to peraluminous granitic systems.     

Constructing environmental responsibility: Perceptions from retail business

This paper examines how retail businesses have employed the concept of environmental responsibility in order to justify their activities in the environmental arena. The sources of such publicised responsibility are investigated in terms of the relationship between the business and the consumer and how far responsibility has a moral base within the company or an economic justification with respect to demand. Data come from in-depth interviews with national and local managers of large multiple grocery superstores in the U.K. as well as from material published by these companies both through leafletting and more standardised reporting channels. Emphasis is placed upon the contradictions between the declaration of internally derived responsibility and the external pressures of demand, legislation and public image, suggesting an anticipatory form of environmental responsibility has been developed by retailers and that this may produce more proactive measures as the environmental debate matures.     

Growth and change and the innovative firm

Regional economic development is largely influenced by technical progress, and innovative manufacturing firms are important in this context. Large, fast growing, innovative firms contribute significantly to growth by direct and indirect employment and income-generating impacts, and these are likely to be extended through time if the firms are capable of developing new product lines and markets. Unfortunately, ‘orthodox’ theories of the firm provide a poor basis for understanding ‘how’ and ‘why’ innovative firms come into existence, grow, change, and operate over time and geographic space. Behavioral—managerial notions, on the other hand, do appear to provide a useful basis for conceptualization. This paper examines some of these concepts and goes on to provide a framework for understanding growth and change in innovative, multiproduct, multiregional firms.     

“Mysterite” : a late condensate from the solar nebula

We have attempted to clarify the nature of “mysterite”, a material that had been postulated to explain the overabundance of Tl, Bi and Ag in certain chondrites. Four dark clasts and a vein sample from the H6 chondrite Supuhee were analyzed by radiochemical neutron activation analysis for Ag, Au, Bi, Br, Cd, Cs, Ge, In, Ir, Ni, Os, Rb, Re, Sb, Se, Te, Tl and Zn. One of the clasts is enriched in all volatile elements, while the other 4 samples are enriched only in the siderophile volatiles Ag, Bi and Tl. The enrichments range up to 100 times typical H6 chondrite abundances. The proportions of Ag, Bi, Tl suggest the presence of at least two, Tl-rich and Tl-poor, varieties of mysterite ($\text{Tl}\text{Bi}\text{= 7.2}$ and <0.1). The former seems to dominate in Supuhee and Krymka, and the latter in Mezö-Madaras. Apparently mysterite is a late condensate from the solar nebula that collected volatiles left behind by earlier generations of chondrites. It was incorporated in Supuhee and perhaps in other chondrites (mainly of low petrologic types) during brecciation events.