A rapid method of trace analysis of uranium(VI) from phosphorites

A new spectrophotometric method for the microdetermination of uranium(VI) from phosphorites in the presence of commonly occurring metal ions has been developed. Uranium is extracted from chloroform solution of N-phenyl-2-naphtho-hydroxamic acid (N-P-2-NHA) at pH 4.0–4.5. The orange-red extract has the maximum absorption at 515 nm. The extraction was quantitative and obeys Beer's law at 515 nm.     

The Neogene/Quaternary boundary in India: A review

The Neogene/Quaternary boundary has been variously defined in different continents. A global review of the problem shows that only the Olduvai event on the palaeomagnetic timescale may provide an universally acceptable isochronous datum for delineating this boundary. The N/Q boundary in the Siwaliks, Kashmir and the Andamans in India is defined in the light of recent research.     

Utilization of remotely sensed data for soil resource mapping and its interpretation for landuse planning of Bhiwani district,Haryana

Visual interpretation of IRS-1A LISS-II (October 1988 & Feb. 1989) FCC (spectral bands 2, 3 & 4) at 1:50,000 scale was carried out for soil resource mapping of Bhiwani district (Haryana State) covering on area of 5099 sq. kim. Based on image characteristics, element analysis (landform, vegetation & erosion) and field traverses, physiography-soil relationship was established. Major physiographic units identified in the area are: Aeolian plain, Fluvio-acolian plain, Transitional plain, Alluvial plain, Hills and Pediments. Area was divided into 34 subunits. Final physiography-soil map on 1:50,000 scale was prepared. Taxonomically, the soils of each unit were classified and are found as: In aeolian plain—Typic Torripsamments/coarse loamy, Typic Camborthios; Fluvio-aeolian plain-Aridic Ustipsamments/coarse loamy/fine loamy Typic/Udic Ustochrepts; Alluvial plain—Typic Ustipsamments/coarse loamy/fine loamy Typic/Udic Ustochrepts; Hills and Pediments—fregmental Lithic Torriorthents/Typic Torripsamments. Interpretation for each subunit was made regarding land suitability for various land utilisation types. It was found that hills and pediments, dunal ridges, dunal complexes and serub-lands are best suitable for forestry and horiculture plantations. Dunal plains and inter-dunal depressions are best suitable for gram/bajra/oilseeds/guar, very gently sloping dunal plain and low lying plain are suitable for wheat/arhar/cotton/sunflower.     

Discriminating four tectonic settings: Five new geochemical diagrams for basic and ultrabasic volcanic rocks based on log — ratio transformation of major-element data

We present five new discriminant function diagrams based on an extensive database representative of basic and ultrabasic rocks from four tectonic settings of island arc, continental rift, ocean-island, and mid-ocean ridge. These diagrams were obtained after log_e-transformation of concentration ratios of major-elements — a technique recommended for a correct statistical treatment of compositional data. Higher % success rates (overall values from ∼ 83 to 97%) were obtained for proposing these new diagrams as compared to those (∼82 to 94%) obtained from the discriminant analysis of the raw major-element concentration data (i.e., without the log_e-transformation and without taking ratios of the compositional data, but using exactly the same database to provide an unbiased comparison), suggesting that such a data transformation constitutes a statistically correct and recommended technique. The new diagrams also resulted in less mis-classification of basic and ultrabasic rocks from known tectonic settings than the diagrams obtained from the raw data. The use of these highly successful new discriminant function diagrams is illustrated using Miocene to Recent basic and ultrabasic rocks from three areas of Mexico with complex or controversial tectonic settings (Mexican Volcanic Belt, Los Tuxtlas volcanic field, and Eastern Alkaline Province), as well as older rocks from three areas (Deccan, Malani, and Bastar) of India. Additionally, the major-element data from two ‘known’ continental arc settings are used to show that they are similar to those from the island arc setting. Continental rift setting is inferred for all Mexican cases and for one cratonic area of India (Malani) and an IAB setting for the Bastar craton. The Deccan flood basalt province of India is used to warn against an indiscriminate use of those discrimination diagrams that do not explicitly include the likely setting of the area under evaluation. An Excel template is also provided for an easy application of these new diagrams for discriminating the four settings considered in this work.     

Environmentally sustainable use of sandstone slurry in self-compacting concrete

Natural Hazards - Dried sandstone slurry (DSS) is generated during mining and processing of stone and is accounted as man-made hazardous waste material, contaminating the environment in nearby...     

Pn wave velocity and Moho geometry in north eastern India

Pn velocity has been computed across the NE India and Moho geometry constrained, using regional earthquake travel times recorded by a network of 30 seismological stations operated during February-May 1993. Using an appropriate velocity model and the arrival times at the network stations, preliminary hypocentres of 16 regional earthquakes provided by NEIC were also improved. The average Pn wave velocity in NE India has been found to be 8.5 ±0.2 km/s. It varies from 8.3 to 8.5 km/s beneath the Shillong Plateau, Mikhir hills and Assam valley, which is significantly higher than those in other parts of India. The crustal thickness in NE India is also high, varying from 45–49 km under the Shillong plateau and the adjoining region to 55–65 km in the convergence zone. The presence of a thick crust and high Pn velocity suggests that the lithosphere in NE India is colder, as also indicated by the observed deeper level (45-51 km) seismicity of the region.     

Effect of simultaneous state–parameter estimation and forcing uncertainties on root-zone soil moisture for dynamic vegetation using EnKF

In this study, an EnKF-based assimilation algorithm was implemented to estimate root-zone soil moisture (RZSM) using the coupled LSP–DSSAT model during a growing season of corn. Experiments using both synthetic and field observations were conducted to understand effects of simultaneous state–parameter estimation, spatial and temporal update frequency, and forcing uncertainties on RZSM estimates. Estimating the state–parameters simultaneously with every 3-day assimilation of volumetric soil moisture (VSM) observations at 5 depths lowered the average standard deviation (ASD) and the root mean square error (RMSE) for RZSM by approximately 1.77% VSM (78%) and 2.18% VSM (93%), respectively, compared to the open-loop ASD where as estimating only states lowered the ASD by approximately 1.26% VSM (56%) and the RMSE by 1.66% VSM (71%). The synthetic case obtained RZSM estimates closer to the observations than the MicroWEX-2 case, particularly after precipitation/irrigation events. The differences in EnKF performance between MicroWEX-2 and synthetic observations may indicate other sources of errors in addition to those in parameters and forcings, such as errors in model biophysics.     

Multifaceted Role of Microalgae for Municipal Wastewater Treatment: A Futuristic Outlook toward Wastewater Management

Municipal wastewater (MWW) or urban wastewater (UWW) is generated by the domestic consumption of freshwater, which contains a huge amount of nutrients. The release of unprocessed wastewater causes eutrophication and harms aquatic life. Moreover, ingestion of polluted MWW causes a severe negative impact on human health. Microalgae are unicellular, eukaryotic photosynthetic organisms and have the capability of nutrient assimilation in the presence of light. Moreover, the produced biomass can be used for the generation of value-added bioproducts such as bioenergy. However, conventional microalgae-based MWW treatment is not as sustainable on a commercial scale. Therefore, more advanced approaches using microalgae need to be integrated in wastewater cultivation systems to improve nutrient removal efficiency. Thus, the present review explores the use of microalgae for the removal of nutrients from MWW, provides an outlook of direct and indirect methods of nutrient uptake from wastewater and the effects of the influencing factors in biomass growth. Moreover, the review also gives insight into recent approaches used for MWW treatment and the applications of algal biomass resulting from treated wastewater. It is predicted that microalgae-based MWW treatment systems will be a significant green approach to help eliminate nutrient loads and implement circular economy.     

Accretion flow dynamics during 1999 outburst of XTE J1859+226—modeling of broadband spectra and constraining the source mass

We examine the dynamical behavior of accretion flow around XTE J1859+226 during the 1999 outburst by analyzing the entire outburst data (～166 days) from RXTE Satellite. Towards this, we study the hysteresis behavior in the hardness intensity diagram (HID) based on the broadband (3–150 keV) spectral modeling, spectral signature of jet ejection and the evolution of Quasi-periodic Oscillation (QPO) frequencies using the two-component advective flow model around a black hole. We compute the flow parameters, namely Keplerian accretion rate (\({\dot{m}}_{d}\)), sub-Keplerian accretion rate (\({\dot{m}}_{h}\)), shock location (\(r_{s}\)) and black hole mass (\(M_{\mathit{bh}}\)) from the spectral modeling and study their evolution along the q-diagram. Subsequently, the kinetic jet power is computed as \(L^{\mathrm{obs}}_{\mathrm{jet}} \sim3\mbox{--}6 \times10^{37}~\mbox{erg}\,\mbox{s}^{-1}\) during one of the observed radio flares which indicates that jet power corresponds to 8–16% mass outflow rate from the disc. This estimate of mass outflow rate is in close agreement with the change in total accretion rate (～14%) required for spectral modeling before and during the flare. Finally, we provide a mass estimate of the source XTE J1859+226 based on the spectral modeling that lies in the range of 5.2–7.9 \(M_{\odot}\) with 90% confidence.