Anomalous Diffuse CO2 Emission prior to the January 2002 Short-term Unrest at San Miguel Volcano, El Salvador, Central America

On January 16, 2002, short-term unrest occurred at San Miguel volcano. A gas-and-steamash plume rose a few hundred meters above the summit crater. An anomalous microseismicity pattern, about 75 events between 7:30 and 10:30 hours, was also observed. Continuous monitoring of CO₂ efflux on the volcano started on November 24, 2001, in the attempt to provide a multidisciplinary approach for its volcanic surveillance. The background mean of the diffuse CO₂ emission is about 16 g m^-2 d^-1, but a 17- fold increase, up to 270 g m^-2 d^-1, was detected on January 7, nine days before the January 2002 short-term unrest at San Miguel volcano. These observed anomalous changes on diffuse CO₂ degassing could be related to either a sharp increase of CO₂ pressure within the volcanic-hydrothermal system or degassing from an uprising fresh gas-rich magma within the shallow plumbing system of the volcano since meteorological fluctuations cannot explain this observed increase of diffuse CO₂ emission.     

Unravelling the widening of the earliest Andean northern orogen: Maastrichtian to early Eocene intra‐basinal deformation in the northern Eastern Cordillera of Colombia

The onset of deformation in the northern Andes is overprinted by subsequent stages of basin deformation, complicating the examination of competing models illustrating potential location of earliest synorogenic basins and uplifts. To establish the width of the earliest northern Andean orogen, we carried out field mapping, palynological dating, sedimentary, stratigraphic and provenance analyses in Campanian to lower Eocene units exposed in the northern Eastern Cordillera of Colombia (Cocuy region) and compare the results with coeval succession in adjacent basins. The onset of deformation is recorded in earliest Maastrichtian time, as terrigenous detritus arrived into the basin marking the end of chemical precipitation and the onset of clastic deposition produced by the uplift of a western source area dominated by shaly Cretaceous rocks. Disconformable contacts within the upper Maastrichtian to middle Palaeocene succession document increasing supply of quartzose sandy detritus from Cretaceous quartzose rocks exposed in eastern source areas. The continued unroofing of both source areas produced a rapid shift in depositional environments from shallow marine in Maastrichtian to fluvial‐lacustrine systems during the Palaeocene‐early Eocene. Supply of immature Jurassic sandstones from nearby western uplifts, together with localized plutonic and volcanic Cretaceous rocks, caused a shift in Palaeocene sandstones composition from quartzarenites to litharenites. Supply of detrital sandy fragments, unstable heavy minerals and Cretaceous to Ordovician detrital zircons, were derived from nearby uplifted blocks and from SW fluvial systems within the synorogenic basin, instead of distal basement rocks. The presence of volcanic rock fragments and 51–59 Ma volcanic zircons constrain magmatism within the basin. The Maastrichtian–Palaeocene sequence studied here documents crustal deformation that correlates with coeval deformation farther south in Ecuador and Peru. Slab flattening of the subducting Caribbean plate produced a wider orogen (>400 km) with a continental magmatic arc and intra‐basinal deformation and magmatism.     

Earthquake early warning scenarios at critical facilities in the Eastern Caribbean

A feasibility study of an earthquake early warning (EEW) system was conducted for the Eastern Caribbean region using scenario earthquakes, corresponding to the maximum credible earthquakes and to the earthquakes associated with a return period of 475 years. Broadband synthetic seismograms were produced at selected critical facilities, where there is potential interest in the installation of an EEW system. The expected damage was derived from the synthetic seismograms and compared with the lead-time determined for both a regional and on-site EEW configuration. Next, the Virtual Seismologist EEW algorithm, as included in SeisComP3, was tested. Additional broadband synthetic seismograms were produced for the stations in the Eastern Caribbean seismic networks in order to simulate the real time behaviour of the seismic networks during the occurrence of the synthetic earthquakes and to assess the predictive capacity of the selected ground motion prediction equation. Expected peak ground parameters and lead-times at the critical facilities constitute the major outcome of the study.     

Accumulation of lead and associated metals (Cu and Zn) at different growth stages of soybean crops in lead-contaminated soils: food security and crop quality implications

The Pb, Cu and Zn content, the physicochemical parameters in soils (EC, OM%, soil texture and pH) and the metal accumulation of Glycine max plants at different growth stages were evaluated. Topsoil and soybean samples were collected in the vicinity of a former battery-recycling plant, with the results showing that only the concentrations of Pb in soils corresponding to sites located near to the lead emission source were above the maximum permissible levels. However, soybean crops accumulated Pb above the permitted levels at all studied sites, revealing a potential toxicological risk for direct consumption. Thus, the accumulation of Pb in soybean was directly related to the translocation factor of the metal from roots to aerial parts of the plant. This was evidenced as a lower accumulation at early growth stages and a higher accumulation at maturity, with the distribution between organs coinciding with nutrient incorporation and remobilization in the plant. Moreover, the bioconcentration factor revealed that the bioaccumulation of lead in soybean was a consequence of the lead-recycling plant activity in the past. Taken together, results of the present study demonstrated that soybean crops can incorporate and accumulate potentially toxic metals, such as lead.     

Petrological and Geochemical Characteristics of the Cerro Colorado Plutonic Complex in the Precordillera of Northern Chile

Abstract. The Cerro Colorado intrusive stock in the northeastern Chilean Precordillera is a plutonic complex formed during Late Cretaceous (64–72 Ma), and consists predominantly of pyroxene-bearing biotite monzogabbro (Colorado Unit), with lesser amounts of pyroxene-bearing hornblende biotite diorite (Pucaquisca Unit) and biotite hornblende monzonite (Pabellón Unit). Compositional variations of major and trace elements suggest that the Cerro Colorado complex is composed of shoshonitic alkali granitoids generated at the active continental margin. The basic to intermediate rocks of the Colorado Unit are characterized by high contents of A1₂O₃ (>20 wt%), CaO and LIL elements (K, Sr, Ba), high Fe/Mg ratio and fairly low contents of Cr, Ni and Y. These characteristics suggest that the Colorado Unit was formed by plagioclase-free source magma originated from asthenospheric mantle or mafic lower crust. All the Cerro Colorado rocks generally display linear compositional trends, and the latest Pabellón Unit rocks are richer in SiO₂ than the Colorado Unit and Pucaquisca Unit rocks. These indicate that the Pabellón Unit rocks were produced by assimilation-fractional crystallization process of the basic to intermediate magma genetically related to the voluminous Colorado Unit.     

Age and magnetic fabric of the Três Córregos granite batholith: evidence for Ediacaran transtension in the Ribeira Belt (SE Brazil)

Anisotropy of magnetic susceptibility (AMS) and U–Pb (SHRIMP) zircon ages in the eastern part of the Três Córregos batholith (Ribeira belt, SE Brazil) indicate a well-defined fabric pattern acquired between 600 and 595 Ma. The batholith consists mostly of porphyritic granites distributed in the Ribeirão Branco, Barra do Chapéu and Itaóca plutons. Late fluorite-bearing alkaline granites, some containing Sn-polymetallic greisen-type deposits, intruded the Ribeirão Branco pluton and the low-grade metasedimentary host rocks. The magnetic fabric of the Ribeirão Branco granite is dominantly oblate and oblique to the pluton elongation while that in Barra do Chapéu is mostly concentric. On both plutons, AMS records the preferred orientation of coarse, homogeneous Ti-poor magnetite grains. Such fabric patterns indicate a partitioned strain field dominated by strike-slip left-lateral shear deformation in the Ribeirão Branco and extension in the Barra do Chapéu pluton. The zircon ages of these plutons are 600 ± 6 Ma and 595 ± 4 Ma. Likewise, the ages of alkaline plutons were in the range of 597 and 595 Ma, registering a fast transition between the typical syntectonic batholithic magmatism to the late, highly evolved and specialized magmas. These results indicate that the Ribeira belt was deformed by transtension in the Middle Ediacaran. The geological setting is consistent with a continental arc with the Três Córregos batholith emplacing at the middle-upper crust.     

Duality rotations and type D solutions of Einstein-Born-Infeld theory

Within the non-linear electrodynamics of Born-Infeld type, constrained by the condition that admits the freedom of the duality rotations the explicit type D solutions, which generalize the charged Taub-NUT metric with cosmological constant, are constructed. The obtained type D solution exhausts all solutions within the considered class, assumed that the real eigenvectors of the electromagnetic field are aligned along the geodesic and shear-free principa null directions.