Road traffic nanoparticle characteristics:Sustainable environment and mobility

Human effects and environment impacts associated with nanoparticles generated from road traffic have recently attracted wide attention.Knowledge of the influencing variables on both number and mass of nanoparticles,sources,characteristics and limitations of advanced commercially accessible instruments for monitoring nanoparticles,are still scarce and not sufficient to make regulatory decision on solid particles smaller than 23 nm(SPN<23 nm).Given the harmful effects of nanoparticles on human health(i.e.visibility impairment,cardiac-rhythm disturbance,heart attacks,premature death,etc.),their control and assessment seem to be an absolute priority.In this overview,we classify and analyze the existing knowledge of nanoparticles in road traffic atmosphere,recent progress,and emerging priorities in research related to these topics.The major aspects of ongoing research in this field,and a brief discussion of the main sources of atmosphere nanoparticles are presented.The subsequent section focuses on the influencing parameters of nanoparticles including climate conditions,height above the road surface and distance between source(road traffic)and sampling site.The next section provides a comprehensive summary on sampling measurement methodologies and instrumental techniques.We also review the health and environment implications associated with particle exposure.Finally,an evaluation of the state of research related to nanoparticles together with highlights for future research activities are also presented.     

Reliability-based design of spread footings on fibre-reinforced clay

The potential use of fibres in a number of geotechnical engineering applications is gaining more interest in the geotechnical community. A select application consists of the improvement of soft grounds to mitigate their problematic shear strength characteristics. Extensive experimental work has been reported on the response/behaviour of fibre-reinforced clay (FRC) and was recently complemented by several strength prediction models. The effectiveness of these models has not been thoroughly evaluated yet. The objectives of this study are to (1) quantify the model uncertainty of a newly developed FRC model that is aimed exclusively at predicting the “undrained” shear strength of FRCs, (2) combine the model uncertainty with other conventional sources of uncertainty to assess the reliability levels that are inherent in the ultimate limit state design of spread footings that rest on a top FRC layer underlain by weaker natural soft clay, and (3) recommend factors of safety that would ensure a target reliability level for these footings. Results indicate that the traditional safety factor of 3 should be used with caution as it may not be sufficient to yield the desired level of reliability, particularly for smaller footings, lower applied stresses, larger scales of fluctuation, and larger target reliability indices.     

Les minéralisations ferrifères du Sahara Algerien: le gisement de fer oolithique de Mecheri Abdelaziz (bassin de Tindouf)

Résumé Le gisement de fer oolithique de Mecheri Abdelaziz (Famennien terminal du bassin de Tindouf), présente des caractères morphologiques et sédimentologiques qui permettent de penser que la minéralisation s'est mise en place dans des édifices deltaïques progradants.La minéralisation est complexe et comprend trois paragenèses principales; maghémite-magnétite, bavalite-hématite, bavalite-magnétite et quatre faciès types: faciès microconglomératique (FMC), faciès à oolithes dispersées dans une matrice détritique (FOD), faciès à oolithes dispersées dans une matrice non détritique (FOND) et faciès à oolithes jointives, cimentées (FOC).Les caractères des oolithes et de la mésostase montrent que les corps minéralisés résultent de l'accumulation d'oolithes, développées essentiellement par concrétionnement intrasédimentaire et ayant subi, avant le dépôt définitif, des phases alternantes d'oolithisation et de remise en suspension.Sur l'ensemble du gisement, les teneurs moyennes sont les suivantes: Fe total: 43,49%; SiO₂=13,66%; P₂O₅=2,31%; CaO=5,35%.En ce qui concerne la source du fer, il semble que la mise en place du minerai soit liée aux importantes réserves de quartzites ferrugineux situées dans le Précambrien du socle Réguibat, dont le stock métal initial a subi des remobilisations successives.

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The Mecheri Abdelaziz oolitic iron deposit (late Famennian of Tindouf Basin) shows morphological and sedimentological features of prograding deltaic sequences.The mineralization is complex and allows the recognition of 3 types of paragenesis: maghemite-magnetite, bavalite-hematite, bavalite-magnetite; and 4 types of facies: microconglomerate facies, oolites dispersed in a matrix with detritic elements, oolites dispersed in a matrix without detritic elements and oolites with cement.The comparison of oolites and matrix suggests that the orebodies are the result of oolites deposition, developed by intrasedimentary processes and before the final deposition, by alternating phases of oolitization and suspension.For the whole ore deposit, the main composition is: total Fe=43.49%; SiO₂=13.66%; P₂O₅=2.31%; CaO=5.35%.The major portion of iron was probably provided by continental leaching of the very important iron formations of the Precambrien Reguibat shield.

     

Experimental Investigation of Frictional Behavior Between Cohesive Soils and Solid Materials Using Direct Shear Apparatus

Soil shearing resistance is very important while designing various structures which have direct contact with soil, for example, sheet piles, piles, retaining walls, reinforced earth structures and shallow foundations. Even though designers use empirical values for their design, it is very important to obtain more accurate values for soil–solid materials shearing resistance. In this work, laboratory tests have been carried out to investigate the effect of roughness interface and texture models on friction angle between cohesive soils and steel, as well as abrasive paper material, using direct shear tests. All tests were carried out under consolidated drained shear conditions. The behavior at the soils–solid interface was found to vary according to surface roughness. It also seems that the type of material (steel or paper of abrasive) used does not have a major influence on the shear strength. As far as roughness is concerned, friction behavior is likely to be generally classified into three failure modes, namely full sliding at the interface, shear failure within the soil, and a mixed behavior where interface sliding and shear deformation of the soil specimen proceed simultaneously. However, for the second mode, the shear strength at the interface soil-rough solid materials steel was found to be lower than the shear strength of the soil, for a soil that is classified as high plasticity clay. Furthermore, it was found that the interfacial shear strength is independent of the texture surface for a given roughness.     

Anthropogenic contamination of groundwater with nitrate in arid region: case study of southern Hodna (Algeria)

In southern Hodna, an arid region of Algeria, the extension of irrigated agriculture and overexploitation of groundwaters have led to a rupture with traditional land use by pastoralism. Due to the arid conditions, groundwaters are the only water resources for man and irrigation. This study focuses on nitrate contamination of groundwaters and its increase since the last 40 years, on the basis of two archives and recent analyses. The chemical facies of waters is sulphate-chloride, the risk of salinity is moderate to large. The sodicity risk, as estimated by the SAR, is low due to the large salinity and the sandy soil texture. Nitrate contamination of deep groundwater is a clear evidence when recent data are compared to the historical data. From 1996 to 2008, the proportion of samples with NO ₃ ^? concentrations larger than 50 mg/L increases from 24 to 61 %, the proportion of samples with NO ₃ ^? concentrations larger than 100 mg/L increases from 12 to 27 %. The study points at a general contamination of aquifers from anthropic origin: phreatic water was already contaminated when pastoralism was dominant (1967); as population increased and irrigation agriculture developed with large use of N-fertilizers and organic amendments, contamination extended spatially and vertically to deep aquifer. To remediate this contamination, fertilizers should be fractionated and limited to plant requirements on the basis of soil and plant analyses. Excess of irrigation should be avoided. Soil surface should be continuously covered to prevent nitrate leaching. Secondly, more efficient irrigation techniques, such as localized irrigation, should be implemented, with adaptation of crop systems and fertilizer inputs to arid conditions. Farmers should then be trained; simultaneously, local agronomic references that are presently lacking should be acquired.     

Phosphorite-hosted zinc and lead mineralization in the Sekarna deposit (Central Tunisia)

The Sekarna Zn–Pb deposit is located in Central Tunisia at the northeastern edge of the Cenozoic Rohia graben. Mineralization comprises two major ore types: (1) disseminated Zn–Pb sulfides that occur as lenses in sedimentary phosphorite layers and (2) cavity-filling zinc oxides (calamine-type ores) that crosscut Late Cretaceous and Early Eocene limestone. We studied Zn sulfide mineralization in the Saint Pierre ore body, which is hosted in a 5-m-thick sedimentary phosphorite unit of Early Eocene age. The sulfide mineralization occurs as replacements of carbonate cement in phosphorite. The ores comprise stratiform lenses rich in sphalerite with minor galena, Fe sulfides, and earlier diagenetic barite. Laser ablation–inductively coupled plasma mass spectrometry analyses of sphalerite and galena show a wide range of minor element contents with significant enrichment of cadmium in both sphalerite (6,000–20,000 ppm) and galena (12–189 ppm). The minor element enrichments likely reflect the influence of the immediate organic-rich host rocks. Fluid inclusions in sphalerite give homogenization temperatures of 80–130°C. The final ice melting temperatures range from −22°C to −11°C, which correspond to salinities of 15–24 wt.% NaCl eq. and suggest a basinal brine origin for the fluids. Sulfur isotope analyses show uniformly negative values for sphalerite (−11.2‰ to −9.3‰) and galena (−16‰ to −12.3‰). The δ³⁴S of barite, which averages 25.1‰, is 4‰ higher than the value for Eocene seawater sulfate. The sulfur isotopic compositions are inferred to reflect sulfur derivation through bacterial reduction of contemporaneous seawater sulfate, possibly in restricted basins where organic matter was abundant. The Pb isotopes suggest an upper crustal lead source.     

A new class of relativistic stellar models

Einstein field equations for a static and spherically symmetric perfect fluid are considered. A formulation given by Patiño and Rago is used to obtain a class of nine solutions, two of them are Tolman solutions I, IV and the remaining seven are new. The solutions are the correct ones corresponding to expressions derived by Patiño and Rago which have been shown by Knutsen to be incorrect. Similar to Tolman solution IV each of the new solutions satisfies energy conditions inside a sphere in some range of two independent parameters. Besides, each solution could be matched to the exterior Schwarzschild solution at a boundary where the pressure vanishes and thus the solutions constitute a class of new physically reasonable stellar models.     

A static axisymmetric anisotropic fluid solution in general relativity

Einstein's interior field equations in general relativity are considered when spacetime is static and axisymmetric and the energy-momentum tensor represents an anisotropic fluid. After imposing a set of simplifying assumptions a two-parameter solution is derived and its properties are discussed. The solution is found to be physically reasonable in a certain range of the parameters in which case the metric could represent a core of anisotropic matter.