Biocalcification in the Eastern Oyster (<Emphasis Type="Italic">Crassostrea virginica)</Emphasis> in Relation to Long-term Trends in Chesapeake Bay pH

Anthropogenic carbon dioxide (CO₂) emissions reduce pH of marine waters due to the absorption of atmospheric CO₂ and formation of carbonic acid. Estuarine waters are more susceptible to acidification because they are subject to multiple acid sources and are less buffered than marine waters. Consequently, estuarine shell forming species may experience acidification sooner than marine species although the tolerance of estuarine calcifiers to pH changes is poorly understood. We analyzed 23 years of Chesapeake Bay water quality monitoring data and found that daytime average pH significantly decreased across polyhaline waters although pH has not significantly changed across mesohaline waters. In some tributaries that once supported large oyster populations, pH is increasing. Current average conditions within some tributaries however correspond to values that we found in laboratory studies to reduce oyster biocalcification rates or resulted in net shell dissolution. Calcification rates of juvenile eastern oysters, Crassostrea virginica, were measured in laboratory studies in a three-way factorial design with 3 pH levels, two salinities, and two temperatures. Biocalcification declined significantly with a reduction of ∼0.5 pH units and higher temperature and salinity mitigated the decrease in biocalcification.     

Hydrochemical and Multivariate Statistical Evaluation of Heavy Metals in Shallow Alluvial Aquifers of North Brahmaputra Plain,India

The aim of this study was to display distribution and relationships of heavy elements in the unconfined, shallow alluvial aquifers of the lower Jia Bharali catchment and adjoining areas in central part of North Brahmaputra Plain (NBP), India using hydrochemical as well as multivariate statistical techniques such as principal component analysis (PCA) and cluster analysis. The original matrix was made up of 10 trace elements (As, Cd, Cu, Co, Cr, Fe, Mn, Pb, Ni and Zn) estimated from 50 shallow alluvial dug wells in both the wet and the dry season for a duration of 3 hydrological years (2008–2011). Except As, Cu and Zn all the other toxic metals in the shallow aquifers were found exceeding the WHO maximum permissible limits for drinking water. PCA extracted five varimax factors as geogenic, agricultural and anthropogenic explaining about 71.2% of the total variance in the wet season and 69.3% total variance in the dry season. Hierarchical cluster analysis classified the dug wells into two groups in the wet season and three groups in the dry season with respect to the heavy elements. The results emphasized the need for routine monitoring and management in order to avoid contamination of groundwater sources in the NBP with respect to the dissolved trace elements.     

Site Specific Ground Motion Modeling and Seismic Response Analysis for Microzonation of Baku,Azerbaijan

We investigated ground response for Baku (Azerbaijan) from two earthquakes of magnitude M6.3 occurred in Caspian Sea (characterized as a near event) and M7.5 in Shamakhi (characterized as a remote extreme event). S-wave velocity with the average shear wave velocity over the topmost 30 m of soil is obtained by experimental method from the V _P values measured for the soils. The downtown part of Baku city is characterized by low V_S30 values (< 250 m/s), related to sand, water-saturated sand, gravel-pebble, and limestone with clay. High surface PGA of 240 gal for the M7.5 event and of about 190 gal for the M6.3 event, and hence a high ground motion amplification, is observed in the shoreline area, through downtown, in the north-west, and in the east parts of Baku city with soft clays, loamy sands, gravel, sediments.     

Seasonal variation of volatile organic iodine compounds in the water column of Funka Bay,Hokkaido, Japan

Volatile organic iodine compounds (VOIs) emitted from the ocean surface to the air play an important role in atmospheric chemistry. Shipboard observations were conducted in Funka Bay, Hokkaido, Japan, bimonthly or monthly from March 2012 to December 2014, to elucidate the seasonal variations of VOI concentrations in seawater and their sea-to-air iodine fluxes. The bay water exchanges with the open ocean water of the North Pacific twice a year (early spring and autumn). Vertical profiles of CH₂I₂, CH₂ClI, CH₃I, and C₂H₅I concentrations in the bay water were measured bimonthly or monthly within an identified water mass. The VOI concentrations began to increase after early April at the end of the diatom spring bloom, and represented substantial peaks in June or July. The temporal variation of the C₂H₅I profile, which showed a distinct peak in the bottom layer from April to July, was similar to the PO₄ ^3? variation profile. Correlation between C₂H₅I and PO₄ ^3? concentrations (r = 0.93) suggests that C₂H₅I production was associated with degradation of organic matter deposited on the bottom after the spring bloom. CH₂I₂ and CH₂ClI concentrations increased substantially in the surface and subsurface layers (0–60 m) in June or July resulted in a clear seasonal variation of the sea-to-air iodine flux of the VOIs (high in summer or autumn and low in spring).     

Assessment of small-diameter shallow wells for managed aquifer recharge at a site in southern Styria,Austria

An approach to establish the recharge component of managed aquifer recharge (MAR) has recently been proposed that uses small-diameter shallow wells installed using relatively inexpensive drilling methods such as direct push. As part of further development of that approach, a generalized procedure is presented for a technical and economic assessment of the approach’s potential in comparison to other systems. Following this procedure, the use of small-diameter wells was evaluated both experimentally and numerically for a site located in southern Styria, Austria. MAR is currently done at the site using a horizontal pipe infiltration system, and system expansion has been proposed with a target rate of 12 l/s using small-diameter wells as one possible option. A short-duration single-well field recharge experiment (recharge rate 1.3–3.5 l/s) was performed (recharge by gravity only). Numerical modeling of the injection test was used to estimate hydraulic conductivity (K). Quasi-steady-state, single-well recharge simulations for different locations, as well as a long-term transient simulation, were performed using the K value calibrated from the field injection test. Results indicate that a recharge capacity of 4.1 l/s was achievable with a maximum head rise of 0.2 m at the injection well. Finally, simulations were performed for three different well fields (4, 6 and 8 wells, respectively) designed to infiltrate a target rate of 12 l/s. The experimental and numerical assessments, supported by a cost analysis of the small-diameter wells, indicate that the small-diameter wells are a viable, cost-effective recharge approach at this and other similar sites.     

Seismic prediction method of multiscale fractured reservoir

Common prestack fracture prediction methods cannot clearly distinguish multiplescale fractures. In this study, we propose a prediction method for macro- and mesoscale fractures based on fracture density distribution in reservoirs. First, we detect the macroscale fractures (larger than 1/4 wavelength) using the multidirectional coherence technique that is based on the curvelet transform and the mesoscale fractures (1/4–1/100 wavelength) using the seismic azimuthal anisotropy technique and prestack attenuation attributes, e.g., frequency attenuation gradient. Then, we combine the obtained fracture density distributions into a map and evaluate the variably scaled fractures. Application of the method to a seismic physical model of a fractured reservoir shows that the method overcomes the problem of discontinuous fracture density distribution generated by the prestack seismic azimuthal anisotropy method, distinguishes the fracture scales, and identifies the fractured zones accurately.     

On the use of the autocorrelation function: the constraint of using frequency band-limited signals for monitoring relative velocity changes

Correlations of seismic noise are commonly used to monitor temporal variations of relative seismic velocity in period ranges from 1 s up to 100 s. Of particular interest is the detection of small changes in the order of 0.01–0.1 % in propagation speeds. Measuring such small differences can, however, be significantly biased by temporal variations in the properties of the noise sources within the corresponding frequency band. Using synthetic data, we show that apparent relative velocity variations might appear only due to changes in the amplitude and frequency content caused by source variations. Removing such unwanted effects by applying narrow bandpass filters in the preprocessing restricts the high-resolution analysis of any signal due to Gabor’s uncertainty limit, i.e., the correlation function suffers a limited resolution to time delay estimates for small correlation times, low-frequency ranges, and in narrow frequency bands. Better understanding of spatiotemporal noise source properties and the theoretical limitations of time–frequency analysis is critical for accurate and reliable passive monitoring.     

Momentum- and Heat-Flux Parametrization at Dome C,Antarctica: A Sensitivity Study

An extensive meteorological observational dataset at Dome C, East Antarctic Plateau, enabled estimation of the sensitivity of surface momentum and sensible heat fluxes to aerodynamic roughness length and atmospheric stability in this region. Our study reveals that (1) because of the preferential orientation of snow micro-reliefs (sastrugi), the aerodynamic roughness length \(z_{0}\) varies by more than two orders of magnitude depending on the wind direction; consequently, estimating the turbulent fluxes with a realistic but constant \(z_{0}\) of 1 mm leads to a mean friction velocity bias of \(24\,\%\) in near-neutral conditions; (2) the dependence of the ratio of the roughness length for heat \(z_{0t}\) to \(z_{0}\) on the roughness Reynolds number is shown to be in reasonable agreement with previous models; (3) the wide range of atmospheric stability at Dome C makes the flux very sensitive to the choice of the stability functions; stability function models presumed to be suitable for stable conditions were evaluated and shown to generally underestimate the dimensionless vertical temperature gradient; as these models differ increasingly with increases in the stability parameter z / L, heat flux and friction velocity relative differences reached \(100\,\%\) when \(z/L > 1\); (4) the shallowness of the stable boundary layer is responsible for significant sensitivity to the height of the observed temperature and wind data used to estimate the fluxes. Consistent flux results were obtained with atmospheric measurements at heights up to 2 m. Our sensitivity study revealed the need to include a dynamical parametrization of roughness length over Antarctica in climate models and to develop new parametrizations of the surface fluxes in very stable conditions, accounting, for instance, for the divergence in both radiative and turbulent fluxes in the first few metres of the boundary layer.     

Transformation between surface spherical harmonic expansion of arbitrary high degree and order and double Fourier series on sphere

In order to accelerate the spherical harmonic synthesis and/or analysis of arbitrary function on the unit sphere, we developed a pair of procedures to transform between a truncated spherical harmonic expansion and the corresponding two-dimensional Fourier series. First, we obtained an analytic expression of the sine/cosine series coefficient of the \(4 \pi \) fully normalized associated Legendre function in terms of the rectangle values of the Wigner d function. Then, we elaborated the existing method to transform the coefficients of the surface spherical harmonic expansion to those of the double Fourier series so as to be capable with arbitrary high degree and order. Next, we created a new method to transform inversely a given double Fourier series to the corresponding surface spherical harmonic expansion. The key of the new method is a couple of new recurrence formulas to compute the inverse transformation coefficients: a decreasing-order, fixed-degree, and fixed-wavenumber three-term formula for general terms, and an increasing-degree-and-order and fixed-wavenumber two-term formula for diagonal terms. Meanwhile, the two seed values are analytically prepared. Both of the forward and inverse transformation procedures are confirmed to be sufficiently accurate and applicable to an extremely high degree/order/wavenumber as \(2^{30}\,{\approx }\,10^9\). The developed procedures will be useful not only in the synthesis and analysis of the spherical harmonic expansion of arbitrary high degree and order, but also in the evaluation of the derivatives and integrals of the spherical harmonic expansion.