Suggestion for searh of ethylene oxide ($$-C2H4O) in a osmi objet

Ethylene oxide (\(c\)-C₂H₄O) and its isomer acetaldehyde (CH₃CHO) are important organic molecules because of their potential role in the formation of amino acids. The \(c\)-C₂H₄O molecule is a \(b\)-type asymmetric top molecule and owing to half-spin of each of the four hydrogen atoms, it has two distinct ortho (nuclear spin one) and para (nuclear spin zero and two) species. It has been detected in the Sgr B2N. Using the rotational and centrifugal distortion constants along with the electric dipole moment, we have calculated energies of 100 rotational levels of each of the ortho and para species of \(c\)-C₂H₄O molecule and the Einstein \(A\)-coefficients for radiative transitions between the levels. The values of Einstein \(A\)-coefficients along with the scaled values for the collisional rate coefficients are used for solving a set of statistical equilibrium equations coupled with the equations of radiative transfer.Brightness-temperatures of five rotational transitions of each of the ortho and para species of \(c\)-C₂H₄O molecule are investigated. Out of these ten transitions, three transitions are found to show the anomalous absorption and rest seven are found to show the emission feature. We have also investigated seven transitions observed unblended in the Sgr B2(N). We have found that the transitions \(3_{3 0} - 3_{2 1}\) (23.134 GHz), \(2_{2 0} - 2_{1 1}\) (15.603 GHz), \(3_{3 1} - 3_{2 2}\) (39.680 GHz) and \(1_{1 1} - 0_{0 0}\) (39.582 GHz) may play important role for the identification of ethylene oxide in a cosmic object.     

Fundamental yet simplified model for liquefaction instability

A fundamental procedure is proposed for the identification of liquefaction in saturated soils based on the instability in the material's microstructure. The disturbed state concept (DSC) provides a unified constitutive model for the characterization of entire stress–strain behaviour under cyclic loading, and the values of disturbance at threshold states in the deforming microstructure provides the basis for the identification of liquefaction. The procedure is verified with respect to laboratory behaviour of two sands, saturated Ottawa and Reid Bedford. A mathematical analysis of the DSC constitutive matrix is also performed. Procedures for the application of the DSC for simplified analysis and design, and in finite element procedures are presented. It is believed that the proposed model can provide a fundamental yet simplified procedure for liquefaction analysis, and as a result, it is considered to be an improvement over the available empirical and energy-based procedures. © 1998 John Wiley & Sons, Ltd.     

Mortality during Hurricane Sandy: the effects of waterfront flood protection on Staten Island,New York

Natural Hazards - Hard defenses, such as levees or land berms, are often considered the most effective approach to reduce flood risk. This study reveals a potential increase in mortality when hard...     

A copula-based closed-form binary logit choice model for accommodating spatial correlation across observational units

This study focuses on accommodating spatial dependency in data indexed by geographic location. In particular, the emphasis is on accommodating spatial error correlation across observational units in binary discrete choice models. We propose a copula-based approach to spatial dependence modeling based on a spatial logit structure rather than a spatial probit structure. In this approach, the dependence between the logistic error terms of different observational units is directly accommodated using a multivariate logistic distribution based on the Farlie-Gumbel-Morgenstein (FGM) copula. The approach represents a simple and powerful technique that results in a closed-form analytic expression for the joint probability of choice across observational units, and is straightforward to apply using a standard and direct maximum likelihood inference procedure. There is no simulation machinery involved, leading to substantial computation gains relative to current methods to address spatial correlation. The approach is applied to teenagers’ physical activity participation levels, a subject of considerable interest in the public health, transportation, sociology, and adolescence development fields. The results indicate that failing to accommodate heteroscedasticity and spatial correlation can lead to inconsistent and inefficient parameter estimates, as well as incorrect conclusions regarding the elasticity effects of exogenous variables.

Utilization of Basic Oxygen Furnace (BOF) slag in the production of a hydraulic cement binder

Basic Oxygen Furnace (BOF) slag is a major waste product generated during the steelmaking process. In India and in most industrial countries, the use of BOF slag as a road ballast and land filler has had a very long history. This being a low end use, a study was conducted to examine the possibility of converting the slag into a hydraulic binder. This paper describes the effect of cooling rate on mineralogy and cementing characteristics of normal BOF slag as well as iron oxide-devoid BOF slag. Specifically, the mineralogy and compressive strengths of heat-treated slags were compared with a conventional ordinary Portland cement. It was found that the slowly cooled slags did not show any cementing properties. The iron oxide-devoid slag, on slow cooling, disintegrated into fine powder. The water-cured cubic specimens of quenched slag products were tested for their compressive strengths. The cementing properties of the quenched slag products were improved by formation of hydraulic phases and showed considerable strength after 28 days of water curing.     

Excitation equilibrium for low lying levels in Cii,Niii, Oiv,Nevi, Mgviii,Six, and Siii

The populations of the excited state ² P _3/2 relative to the ground state ² P _1/2 have been investigated in C ii, N iii, O iv, Ne vi, Mg viii, Si x, and Si ii by considering all the radiative and collisional processes including the collisional transitions to the higher states which cascade to the upper level. The relative populations are used for the calculation of the line emissivities. The intensities of 76 320, 30 258 and 14 302 lines of Nevi, Mgviii, and Six ions respectively in the chromosphere-corona transition region are also calculated.     

Cometary impacts and ice-ages

Cycles of glaciation with an average period of 100 kyr are mediatedby impacts of cometary bolides. Ice-age conditions are dry and dusty withlow rates of precipitation. Comets in the mass range 10¹⁵ -10¹⁶ gimpacting the oceans could release enough water vapour into the atmosphereto enhance a depleted greenhouse effect. The energy deposited in the oceanswould also warm the surface layers, thus starting up anevaporation-precipitation cycle which ushers in warmer interglacialinterludes. The latter have neutral stability and are necessarilyshort-lived, eventually drifting back to glacial conditions on timescalesof 10 kyr.     

GEOLOGICAL STUDIES OF METAMORPHIC ROCKS IN THE VICINITY OF M.C.T./LESSER HIMALAYAN SHEAR ZONE, PARTS OF SIKKIM HIMALAYAS

GEOLOGICAL STUDIES OF METAMORPHIC ROCKS IN THE VICINITY OF M.C.T./LESSER HIMALAYAN SHEAR ZONE, PARTS OF SIKKIM HIMALAYAS