Chemical stabilization of sabkha soils at high moisture contents

Vast expanses of arid, saline soils that occur along the Arabian Gulf seaboard and elsewhere possess a very low density and strength that necessitate improvement before any actual construction takesplace. For large-scale constructions, several field improvement techniques have recently been implemented with various degrees of success. In surficial, small-scale applications, chemical stabilization provides a potential technique to improve the inferior properties of these soils, known locally as sabkha. A literature search indicates that chemical stabilization of soils usingasphalt, lime and cement is usually conducted at lower moisture contents than the optimum. Such moisture contents are also much lower than the natural moisture content of sabkha, and if applied to sabkha in the field, this wouldrequire lowering the moisture content before any stabilization commenced; whichwould be neither feasible nor economical.

In this investigation, an eastern Saudi sabkha soil was chemically stabilized at its natural moisture level, which varies from 16% to 22%. In addition to the characterization of the soil and standard compaction tests, cement and lime sabkha mixtures were prepared at five additions and cured for up to 90 days in plastic wrap. Results indicate that cement-stabilized sabkha gained high strength with time and proved to have a potential use in construction.     

Magnetic Resonance Imaging of Nonaqueous Phase Liquid Distribution in Unconsolidated Soils Using Discriminatory Freezing

Organic contaminants present as nonaqueous phase liquids (NAPLs) in the subsurface often pose a long-term risk to human health and the environment. Investigating the distribution of NAPLs in porous media remains a major challenge in risk assessment and management of contaminated sites. Conventional soil coring and monitoring wells have been widely used over past decades as the primary means of subsurface investigation to determine NAPL extent. Known limitations of conventional approaches have led us to explore an alternative or a complementary technique to provide high-quality information of NAPL source zone architecture. This work advances an imaging tool for a variety of organic NAPL contaminants in unconsolidated soils through magnetic resonance imaging (MRI) of frozen cores. Using trichloroethylene (TCE) and o-xylene as model species, we illustrate that discriminatory freezing of water, while keeping the NAPL in a liquid state, enables high-resolution qualitative delineation of NAPL distribution within porous media. This novel approach may help improve site conceptual models and consequentially lead to highly tailored, more efficient remedial measures.     

Timing of Late Neoproterozoic glaciation on Baltica constrained by detrital zircon geochronology in the Hedmark Group, south-east Norway

The Moelv Tillite is the Late Neoproterozoic Varanger glacial deposit recorded in the Hedmark Group, SE Norway. Paired U–Pb and Lu–Hf data collected on detrital zircons in the Rendalen Formation underlying the Moelv Tillite have identified an uncommon 677 ± 15 to 620 ± 14 Ma population, that constrain the deposition of the Moelv Tillite to be younger than 620 ± 14 Ma. The youngest detrital zircons may be derived from granite magmatism related to the 616 ± 3 Ma Egersund dolerite magmatism, situated in the western part of the Sveconorwegian orogen. The Moelv Tillite, which is not overlain by a cap carbonate, possibly correlates with the c. 580 Ma Squantum-Gaskiers glacial deposits of Avalonia. Available palaeomagnetic data for the Late Neoproterozoic suggest that Baltica was located at intermediate to high latitude between 620 and 555 Ma.     

Lithostratigraphic subdivision of the Kuhlan Formation in Yemen

The lithostratigraphic subdivision of the Kuhlan Formation in Yemen is reviewed based on the previous literature and new examination of five widely spaced outcrops in the Kuhlan Affar, Jabal Maswar, Jabal Salab, Wadi Hajar, and Ras Falanj areas. Following the guidelines set by the North American Commission on Stratigraphic Nomenclature, Kuhlan Formation, with an age as latest Triassic to the Middle Jurassic, includes three members, Azzan, Souq, and Hesn, in an ascending order. Azzan member consists mainly of about 40 m of whitish coarse grained sandstone with many conglomeratic horizons. The Souq member is characterized by its reddish to brownish sandstones as well as the presence of polygonal structures at in the central part of this member, with a thickness of about 70 m. The Hesn member consists dominantly (80 m) of whitish sandstones with some marl intercalations at its topmost part. The Kuhlan Formation was deposited in a fluviatile environment.     

Probabilistic seismic hazard assessment for Thailand

A set of probabilistic seismic hazard maps for Thailand has been derived using procedures developed for the latest US National Seismic Hazard Maps. In contrast to earlier hazard maps for this region, which are mostly computed using seismic source zone delineations, the presented maps are based on the combination of smoothed gridded seismicity, crustal-fault, and subduction source models. Thailand’s composite earthquake catalogue is revisited and expanded, covering a study area limited by 0°–30°N Latitude and 88°–110°E Longitude and the instrumental period from 1912 to 2007. The long-term slip rates and estimates of earthquake size from paleoseismological studies are incorporated through a crustal fault source model. Furthermore, the subduction source model is used to model the megathrust Sunda subduction zones, with variable characteristics along the strike of the faults. Epistemic uncertainty is taken into consideration by the logic tree framework incorporating basic quantities, such as different source modelling, maximum cut-off magnitudes and ground motion prediction equations. The ground motion hazard map is presented over a 10 km grid in terms of peak ground acceleration and spectral acceleration at 0.2, 1.0, and 2.0 undamped natural periods and a 5% critical damping ratio for 10 and 2% probabilities of exceedance in 50 years. The presented maps give expected ground motions that are based on more extensive data sources than applied in the development of previous maps. The main findings are that northern and western Thailand are subjected to the highest hazard. The largest contributors to short- and long-period ground motion hazard in the Bangkok region are from the nearby active faults and Sunda subduction zones, respectively.     

Identifying sky conditions in Iran from MODIS Terra and Aqua cloud products

Clouds can influence climate through many complex interactions within the hydrological cycle. Due to the important effects of cloud cover on climate, it is essential to study its variability over certain geographical areas. This study provides a spatial and temporal distribution of sky conditions, cloudy, partly cloudy, and clear days, in Iran. Cloud fraction parameters were calculated based on the cloud product(collection 6_L2) obtained from the Moderate Resolution Imaging Spectroradiometer(MODIS) sensors on board the Terra(MOD06) and Aqua(MYD06) satellites. The cloud products were collected daily from January 1, 2003 to December 31, 2014(12 years) with a spatial resolution of 5 km × 5 km. First, the cloud fraction data were converted into a regular geographic coordinate network over Iran. Then, the estimations from both sensors were analyzed. Results revealed that the maximum annual frequency of cloudy days occurs along the southern shores of the Caspian Sea, while the minimum annual frequency occurs in southeast Iran. On average, the annual number of cloudy and clear-sky days was 88 and 256 d from MODIS Terra, as compared to 96 and 244 d from MODIS Aqua. Generally, cloudy and partly cloudy days decrease from north to south, and MODIS Aqua overestimates the cloudy and partly cloudy days compared to MODIS Terra.     

Application of GAINS model for assessing selected air pollutants in Khyber Pakhtunkhwa and Balochistan,Pakistan

Pakistan is a developing country existing geographically at a pivoted location between two of the world’s largest pollution emitting countries (China and India) which adds to the severity of environmental issues faced by the country. These concerns include air pollution, climate change, and extreme weather situations prevailing in Pakistan. This increasing air pollution is deteriorating the health, threatening the food security and adding up its share to the already existing global warming. The initial step in devising a wide ranging, multifaceted, economically feasible, and sustainable solution to deal with the severity of this issue is the quantification of the air pollution and greenhouse gas emission in Pakistan. The GAINS model is one of the most comprehensive tools, dealing with the air pollutants and greenhouse gases covered by the Kyoto Protocol. This study has utilized this model to analyze the source-based anthropogenic emissions of air pollutants (NH₃ and SO₂), volatile organic compounds (VOCs), and greenhouse gases (CH₄ and CO₂), their impacts and abatement cost, for the duration of 1990–2030, in the Khyber Pakhtunkhwa and Balochistan regions of Pakistan. An overall increasing trend was observed during 1990–2030 for (a) air pollutants: NH₃ (223.52–568.87kT/Y); SO₂ (50.52–332.95kT/Y), (b) VOCs (121.76–246.81kT/Y), and (c) greenhouse gases: CO₂ (7.83–62.45MT/Y) and CH₄ (1120-2314kT/Y). The emission inventories created for all greenhouse gases together estimated the increase of 42.37 to 138.57 MTCO₂eq. for greenhouse gases over the time duration of 1990–2030.     

The interannual precipitation variability in the southern part of Iran as linked to large-scale climate modes

The interannual variation of precipitation in the southern part of Iran and its link with the large-scale climate modes are examined using monthly data from 183 meteorological stations during 1974–2005. The majority of precipitation occurs during the rainy season from October to May. The interannual variation in fall and early winter during the first part of the rainy season shows apparently a significant positive correlation with the Indian Ocean Dipole (IOD) and El Ni?o-Southern Oscillation (ENSO). However, a partial correlation analysis used to extract the respective influence of IOD and ENSO shows a significant positive correlation only with the IOD and not with ENSO. The southeasterly moisture flux anomaly over the Arabian Sea turns anti-cyclonically and transport more moisture to the southern part of Iran from the Arabian Sea, the Red Sea, and the Persian Gulf during the positive IOD. On the other hand, the moisture flux has northerly anomaly over Iran during the negative IOD, which results in reduced moisture supply from the south. During the latter part of the rainy season in late winter and spring, the interannual variation of precipitation is more strongly influenced by modes of variability over the Mediterranean Sea. The induced large-scale atmospheric circulation anomaly controls moisture supply from the Red Sea and the Persian Gulf.     

Proposed algorithm for optimization of directional additional exploratory drill holes and computer coding

Block model estimated based on the drill hole information gathered during exploration stage is not appropriate for short- and medium-term mine planning. Additional information prior to mining is required for various purposes, that the source of this information is drill holes. In most situations, reducing the overall uncertainty on the estimation is the major objective of additional drilling and collecting samples from them. The topic of selecting the optimum location for additional exploratory drill holes has been of interest to mining engineers and geostatisticians in the second half of last century, but all of them are not able to optimize directional drill holes because they are based on the 2D space and do not consider the 3D extension of drill holes and block model. This study introduces a methodology to optimize the dip and location of additional exploratory drill holes based on the defined objective function with considering 3D extension of ore body and drill holes. Direct search simulated annealing used that is efficient and robust method for solving the nonlinear unconstrained global optimization problems. This method is very useful in the case that drilling the drill holes with different dips has been obligated due to topography condition and ore body situation. A case study in gold resource illustrates the method.     

Biodegradation of phenol from a synthetic aqueous system using acclimatized activated sludge

Phenol is one of the aromatic hydrocarbons. Phenol and its derivatives are highly toxic. These pollutants can be observed in the effluents of many industries. This research investigates the removal of phenol by the use of activated sludge in a batch system. The effects of influencing factors on biodegradation efficiency have been evaluated. The main factors considered in this study were the volume of acclimatized activated sludge inoculation, pH, temperature, and initial concentration of phenol. The inoculation volumes of 1, 3, and 5 mL of acclimatized activated sludge were taken into account. Different pH values of 3, 5, 7, 9, and 11 were examined. The experiments were conducted for temperatures of 25, 30, 35, and 40 °C and initial phenol concentrations of 400, 800, 1,000, and 1,500 ppm. The results show that the acclimatized activated sludge has a high capacity for the removal of phenol. From a 100-mL aqueous solution was removed 1,500 ppm of phenol after 80 h. Furthermore, maximum phenol removal was observed for an inoculation volume of 5 mL for three different phenol concentrations of 100, 400, and 800 ppm. The best pH was 7 for the biodegradation process, and the optimum temperature was 30 °C. It was further found that an increase in the phenol concentration increased its removal time. Moreover, the activated sludge could effectively remove about 99.9 % of phenol from a synthetic aqueous solution in a batch system.