Geochemical distribution and removal of As,Fe, Mn and Al in a surface water system affected by acid mine drainage at a coalfield in Southwestern China

The chemical characteristics, formation and natural attenuation of pollutants in the coal acid mine drainage (AMD) at Xingren coalfield, Southwest China, are discussed in this paper based on the results of a geochemical investigation as well as geological and hydrogeological background information. The chemical composition of the AMD is controlled by the dissolution of sulfide minerals in the coal seam, the initial composition of the groundwater and the water–rock interaction. The AMD is characterized by high sulfate concentrations, high levels of dissolved metals (Fe, Al, Mn, etc.) and low pH values. Ca²⁺ and SO₄ ²⁻ are the dominant cation and anion in the AMD, respectively, while Ca²⁺ and HCO₃ ⁻ are present at significant levels in background water and surface water after the drainage leaves the mine site. The pH and alkalinity increase asymptotically with the distance along the flow path, while concentrations of sulfate, ferrous iron, aluminum and manganese are typically controlled by the deposition of secondary minerals. Low concentrations of As and other pollutants in the surface waters of the Xingren coalfield could be due to relatively low quantities being released from coal seams, to adsorption and coprecipitation on secondary minerals in stream sediments, and to dilution by unpolluted surface recharge. Although As is not the most serious water quality problem in the Xingren region at present, it is still a potential environmental problem. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Experimental superensemble forecasts of tropical cyclones over the Bay of Bengal

This study entails the implementation of an experimental real time forecast capability for tropical cyclones over the Bay of Bengal basin of North Indian Ocean. This work is being built on the experience gained from a number of recent studies using the concept of superensemble developed at the Florida State University (FSU). Real time hurricane forecasts are one of the major components of superensemble modeling at FSU. The superensemble approach of training followed by real time forecasts produces the best forecasts for tracks and intensity (up to 5 days) of Atlantic hurricanes and Pacific typhoons. Improvements in track forecasts of about 25–35% compared to current operational forecast models has been noted over the Atlantic Ocean basin. The intensity forecasts for hurricanes are only marginally better than the best models. In this paper, we address tropical cyclone forecasts over the Bay of Bengal for the years 1996–2000. The main result from this study is that the position and intensity errors for tropical cyclone forecasts over the Bay of Bengal from the multimodel superensemble are generally less than those of all of the participating models during 1- to 3-day forecasts. Some of the major tropical cyclones, such as the November 1996 Andhra Pradesh cyclone and October 1999 Orissa super cyclone were well handled by this superensemble approach. A conclusion from this study is that the proposed approach may be a viable way to construct improved forecasts of Bay of Bengal tropical cyclone positions and intensity.     

A technical note on seismic microzonation in the central United States

Microzonation is an effort to evaluate and map potential hazards found in an area, urban area in particular, that could be induced by strong ground shaking during an earthquake. These hazards include: ground motion amplification, liquefaction, and slope failure. The microzonation maps, depicting ground-motion amplification, liquefaction, and landslide potentials, can be produced if the ground motion on bedrock (input) and the site conditions are known. These maps, in combination with ground-motion hazard maps (on bedrock), can be used to develop a variety of hazard mitigation strategies such as seismic risk assessment, emergency response and preparedness, and land-use planning. However, these maps have certain limitations that result from the nature of regional mapping, data limitations, generalization, and computer modeling. These microzonations show that when strong ground shaking occurs, damage is more likely to occur, or be more severe, in the higher hazard areas. The zones shown on the hazard maps should not serve as a substitute for site-specific evaluations.     

Analysis of Circular Elastic Plate Resting on Pasternak Foundation by Strain Energy Approach

In this paper, an analytical expression for the deflection of a thin circular elastic plate resting on the Pasternak foundation is derived by adopting the strain energy approach. The parametric study is carried out to observe the location of the plate lift-off and the variation of the deflection profiles for comparing the variation pattern reported in the literature based on an approximate solution technique. It is found that the radial distance of the point of lift-off of the plate decreases with increase in the values of both the shear modulus and the modulus of subgrade reaction of the foundation soil; the reduction being more for their lower values. It is also observed that the variation in deflection of the plate at any radial distance due to change in soil subgrade conditions is significant for lower values of modulus of subgrade reaction.     

Do extrusion ages reflect magma generation processes at depth? An example from the Neogene Volcanic Province of SE Spain

The high-K calc-alkaline volcanic rocks along the Neogene Volcanic Province of SE Spain represent crustal anatectic melts mixed with mantle components during the opening of the Alborán Sea. Partially melted metapelitic enclaves, along with the geochemical signature, provide evidence of their crustal source. U–Pb SHRIMP geochronology on monazite and zircon from enclaves and their hosting lavas in the localities of El Hoyazo, Mazarrón and Mar Menor reveals variable delays between the melting at depth and the eruption of the volcanics. These data indicate that: (1) the most important event of anatexis in the Neogene spanned at least the 3 m.y. interval between 12 and 9 Ma; (2) there is no trend in age of crustal melting; and (3) the delay between magma generation and extrusion varies from more than 3 m.y. at El Hoyazo to ~0.5 m.y. and possibly 2.5 m.y. at Mar Menor, with no significant delay measurable at Mazarrón. The variable time delay between anatexis and lava extrusion indicates that radiometric ages of volcanics may provide misleading information on the timing of magma genesis occurring at depth. This highlights the pitfall of basing detailed geodynamic models on volcanic extrusion ages alone. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

Tin partition behavior and implications for the Furong tin ore formation associated with peralkaline intrusive granite in Hunan Province,China

Tin deposits are often closely associated with granitic intrusions. In this study, we analyzed tin partition coefficients between different fluids and melts (\({\text{D}}_{Sn}^{aq.fl./melt}\)) as well as various crystals and melts \({\text{D}}_{Sn}^{aq.fl./melt}\)(\({\text{D}}_{Sn}^{crystal/melt}\)) from the Furong tin deposit associated with the Qitianling A-type granite. Our experimental results indicate that tin partition behavior is affected by the chemical compositions of fluids, melts, and minerals. Tin is prone to partitioning into the residual magma in fractional crystallization or other differential magmatic processes if the magma originated from crustal sources with high alkali content, high volatile content, and low oxygen fugacity. Highly evolved residual peralkaline granitic magma enriched in tin can lead to tin mineralization in a later stage. Furthermore, the volatiles F and Cl in the magma play important roles in tin partitioning behavior. Low F contents in the melt phase and high Cl content in the aqueous fluid phase are favorable factors for tin partitioning in the aqueous fluid phase. High Cl content in the aqueous fluid catalyzes water–rock interaction and leads to the extraction of tin from tin-bearing minerals. All these findings support a hydrothermal origin for the tin deposits. In light of the geotectonic setting, petrochemical characteristics, and mineralizing physicochemical conditions of the Furong tin deposit, it is inferred that the ore-forming fluid of the Furong tin ore deposit could have derived from the Qitianling peralkaline intrusion.     

Prediction of Land Subsidence Under Cyclic Pumping Based on Laboratory and Numerical Simulations

In this study subsidence due to groundwater withdrawal was investigated. Kerman Province in Iran is struggling with land subsidence problem due to extensive groundwater withdrawal mainly for farming. The rate and type of groundwater withdrawal has very important impact on settlement rate. In this research, effective parameters on land subsidence caused by groundwater withdrawal were determined by laboratory tests. Sampling had done up to depth of 300 m mainly with remolded specimens from Shams-abad, Nouq plain in Kerman province. Similar to the field preconsolidation pressure was applied on specimens in the laboratory. Rate of applied stress on prepared specimens was similar to effect of oscillation of groundwater level. In order to model the actual soil behavior in the laboratory, one-dimensional consolidation device (odometer) was adopted for testing. In these tests, the effect of loading caused by seasonal oscillation of groundwater table is considered by means of cyclic loading in the testing which has great effect on rate of settlements. The results of tests show that when the water table level periodically increases and decreases the amount of settlement decrease, comparing with the case when the groundwater table drop to a constant level. In order to predict the further effects of groundwater level oscillation and actual field condition on land subsidence, a finite element model based on Biots’ three-dimensional consolidation theory was developed. After calibration of finite element model with laboratory tests, this model was used for prediction the effect of groundwater level oscillation on actual field conditions.     

Additional coralline algae from the Lower Miocene to Late Holocene sediments of the Porbandar Group,Gujarat

The Neogene-Quaternary sediments well exposed in the Porbandar Basin are characterized by coralline algae. The limestone, calc-arenites and marls are the dominant lithology of this sequence. The present paper documents ten species of coralline algae. Among these, the nongeniculate coralline algae are represented by four species and geniculate coralline algae include six species. The sediments yielding this algal flora range in age from the Lower Miocene to Late Holocene.     

A grid-based tropospheric product for China using a GNSS network

Tropospheric delay accounts for one source of error in global navigation satellite systems (GNSS). To better characterize the tropospheric delays in the temporal and spatial domain and facilitate the safety-critical use of GNSS across China, a method is proposed to generate a grid-based tropospheric product (GTP) using the GNSS network with an empirical tropospheric model, known as IGGtrop. The prototype system generates the GTPs in post-processing and real-time modes and is based on the undifferenced and uncombined precise point positioning (UU-PPP) technique. GTPs are constructed for a grid form (\(2.0{^{\circ }}\times 2.5{^{\circ }}\) latitude–longitude) over China with a time resolution of 5 min. The real-time GTP messages are encoded in a self-defined RTCM3 format and broadcast to users using NTRIP (networked transport of RTCM via internet protocol), which enables efficient and safe transmission to real-time users. Our approach for GTP generation consists of three sequential steps. In the first step, GNSS-derived zenith tropospheric delays (ZTDs) for a network of GNSS stations are estimated using UU-PPP. In the second step, vertical adjustments for the GNSS-derived ZTDs are applied to address the height differences between the GNSS stations and grid points. The ZTD height corrections are provided by the IGGtrop model. Finally, an inverse distance weighting method is used to interpolate the GNSS-derived ZTDs from the surrounding GNSS stations to the location of the grid point. A total of 210 global positioning system (GPS) stations from the crustal movement observation network of China are used to generate the GTPs in both post-processing and real-time modes. The accuracies of the GTPs are assessed against with ERA-Interim-derived ZTDs and the GPS-derived ZTDs at 12 test GPS stations, respectively. The results show that the post-processing and real-time GTPs can provide the ZTDs with accuracies of 1.4 and 1.8 cm, respectively. We also apply the GTPs in real-time kinematic GPS PPP, and the results show that the convergence time of the PPP solutions is shortened. These results confirm that the GTPs can act as an efficient information source to augment GNSS positioning over China.     

On the accuracy of atmospheric forcing for extra-tropical storm surge prediction

The ability of the SMARA storm surge numerical prediction system to reproduce local effects in estuarine and coastal winds was recently improved by considering one-way coupling of the air–sea momentum exchange through the wave stress, and best forecasting practices for downscaling. The inclusion of long period atmospheric pressure forcing in tide and tide/surge calculations corrected a systematic error in the surge, produced by the South Atlantic Ocean quasi-stationary pressure patterns. The maximum forecast range for the storm surge at Buenos Aires provided by the real-time use of water level observations is approximately 12 h. The best available water level prediction is the 6-h forecast (nowcast) based on the closest water level observations. The 24-h forecast from the numerical models slightly improves this nowcast. Although the numerical forecast accuracy degrades after the first 48 h, the improvement to the full range observation-based prediction is maintained at the inner Río de la Plata area and extends to the first 3 days at the intermediate navigation channels.