GIS-based mapping for marine geohazards in seabed fluid leakage areas (Gulf of Cadiz, Spain)

This paper applies, for the first time in offshore deepwater, a method based on geographic information systems for seafloor susceptibility assessment as a first approach to marine geohazard mapping in fluid leakage areas (slope instabilities, gas escapes, seabed collapses, pockmarks, etc.). The assessment was carried out in a known seabed fluid-flow province located on the Iberian margin of the Gulf of C??diz, Spain. The method (based on statistical bivariate analysis) creates a susceptibility map that defines the likelihood of occurrence of seafloor features related to fluid flow: crater-like depressions and submarine landslides. It is based on the statistical index (Wi) method (Van Westen in Statistical landslide hazard analysis. ILWIS 2.1 for Windows application guide. ITC Publication, Enschede, pp 73?C84, 1997), in which Wi is a function of the cartographic density of seafloor features on ??factor maps??. The factors selected monitor the seafloor??s capability to store and transfer hydrocarbon gases and gravitational instability triggers: geology-lithology, gas hydrate stability zone thickness (temperature, pressure?Cwater depth and geothermal gradient), occurrence of diapirs, proximity to faults or lineaments, and slope angle of the seafloor. Results show that the occurrence of seafloor features related to fluid flow is highest where the factors ??gas source and storage?? and ??pathways of fluid escape?? converge. This means that they are particularly abundant over diapirs in contourite deposits, in the vicinity of faults, and inside theoretical gas hydrate stability fields thinned by warm undercurrents. Furthermore, the submarine landslides located on the Palaeozoic-Toarcian basement are not related to fluid leakage. This methodology provides helpful information for hazard mitigation in regional selection of potential drill sites, deep-water construction sites or pipeline routes. It is an easily applied and useful tool for taking the first step in risk assessment on a regional scale for vast areas where fluid leakage may be present, the geological model is known, and the geologically hazardous features have already been mapped.     

A comparison of climatological observing windows and their impact on detecting daily temperature extrema

Climatological observing window (COW) is defined as a time frame over which continuous or extreme air temperature measurements are collected. A 24-h time interval, ending at 00UTC or shifted to end at 06UTC, has been associated with difficulties in characterizing daily temperature extrema. A fixed 24-h COW used to obtain the temperature minima leads to potential misidentification due to fragmentation of “nighttime” into two subsequent nighttime periods due to the time discretization interval. The correct identification of air temperature extrema is achievable using a COW that identifies daily minimum over a single nighttime period and maximum over a single daytime period, as determined by sunrise and sunset. Due to a common absence of hourly air temperature observations, the accuracy of the mean temperature estimation is dependent on the accuracy of determination of diurnal air temperature extrema. Qualitative and quantitative criteria were used to examine the impact of the COW on detecting daily air temperature extrema. The timing of the 24-h observing window occasionally affects the determination of daily extrema through a mischaracterization of the diurnal minima and by extension can lead to errors in determining daily mean temperature. Hourly air temperature data for the time period from year 1987 to 2014, obtained from Toronto Buttonville Municipal Airport weather station, were used in analysis of COW impacts on detection of daily temperature extrema and calculation of annual temperature averages based on such extrema.     

Spatial distribution of climatic conditions from the Middle Eocene to Late Miocene based on palynoflora in Central,Eastern and Western Anatolia

The continental climatic evolution of Anatolia has been reconstructed quantitatively for the last 45 million years using the coexistence approach. Although there were some regional effects, the Anatolian Cenozoic continental climate record correlated with the European climatic condition and the global oxygen isotope record from marine environments. From middle Eocene to late Miocene, continental warming in Anatolia was pronounced for inferred winter temperature and mean annual temperature as in Europe. Generally, the palaeoclimatic property of Anatolia resembles the European climatic changing and marine temperature changing based on the oxygen isotope record; however, climatic values of the terrestrial area in Anatolia are higher from Lutetian to Aquitanian and these values are lower than European values from Aquitanian to Tortonian. Correspondingly, Cenozoic climatic cooling in Anatolia is directly associated with an increase of seasonality, palaeogeographic position and terrestrial condition. Furthermore, mean annual precipitation values of Anatolia remained relatively stable during the Eocene–Oligocene; however, these values indicated changing throughout middle–late Miocene. Moreover, in this study, decline of abundance and variables for the mangrove and back mangrove palaeocommunities during the last 45 million years is recorded because of the decreasing of humidity, temperature and increasing of terrestrial condition.     

Integrated geophysical and geological methods to investigate the inner and outer structures of the Quaternary Mýtina maar (W-Bohemia,Czech Republic)

The Mýtina maar is the first known Quaternary maar in the Bohemian Massif. Based on the results of Mrlina et al. (J Volcanol Geother Res 182:97–112, 2009), a multiparametric geophysical (electrical resistivity tomography, gravimetry, magnetometry, seismics) and geological/petrochemical research study had been carried out. The interpretation of the data has provided new information about the inner structure of the volcanic complex: (1) specification of the depth of post-volcanic sedimentary fill (up to ~100 m) and (2) magnetic and resistivity signs of one (or two) hidden volcanic structures interpreted as intrusions or remains of a scoria cone. The findings at the outer structure of the maar incorporate the (1) evidence of circular fracture zones outside the maar, (2) detection and distribution of volcanic ejecta and tephra-fall deposits at the surface, and (3) indications from electrical resistivity tomography and gravity data in the area between the Mýtina maar and ?elezná h?rka scoria cone, interpreted as a palaeovalley, filled by volcaniclastic rocks, and aligned along the strike line (NW–SE) of the Tachov fault zone. These findings are valuable contributions to extend the knowledge about structure of maar volcanoes in general. Because of ongoing active magmatic processes in the north-east part of the Cheb Basin (ca. 15–30 km north of the investigation area), the Mýtina maar-diatreme volcano and surroundings is a suitable key area for research directed to reconstruction of the palaeovolcanic evolution and assessment of possible future hazard potential in the Bohemian Massif.     

Methodology for determination of correction factors in direct gamma spectrometric measurement of radionuclides in sediments

In this study, the practical methodologies are described for the determination of the factors for the self-absorption effect (Fs), spectral interferences (Fcsi), and true coincidence summing effects (Fcoi), which are used in direct gamma-spectrometric measurement of radionuclides such as 210Pb, 238U, 234Th, 226Ra, 214Pb, 228Ac, 208Tl, 214Bi, 137Cs and 40K in samples. To validate the applied methods, certified reference materials (CRMs) of lake and stream sediments were measured with an n-type Germanium (Ge) detector-calibrated using a multinuclide reference source. The highest self-absorption correction factors ranged from Fs = 1.44–2.10 for 46.5 keV peak (210Pb) and Fs = 1.25–1.60 for 63.3 keV peak (234Th) lying in the low energy region of the spectrum. The systematic influence was observed for 186.2 keV (226Ra) peak due to spectral interferences with the 235U contribution. For this peak, Fcsi is changed from 0.921 to 0.955. Additionally, the present study suggests that true coincidence summing (TCS) effects are not dominant, except for 208Tl and 214Bi for which Fcoi ranged from 1.179 to 1.192 an ranged from 1.140 to 1.151, respectively.     

Mineral chemistry of ultramafic and mafic cumulates as an indicator of the arc-related origin of the Mersin ophiolite (southern Turkey)

The Mersin ophiolite, represented by approximately 6-km-thick oceanic lithospheric section on the southern flank of the Taurus calcareous axis, formed in the Mesozoic Neo-Tethyan ocean some time during Late Cretaceous in southern Turkey. The ultramafic and mafic cumulates having over 3 km thickness consist of dunite ± chromite, wehrlite, clinopyroxenite at the bottom and pass into gabbroic cumulates in which leucogabbro, olivine-gabbro and anorthosite are seen. Crystallization order is olivine (Fo₉₁₋₈₀) ± chromian spinel (Cr# 60-80), clinopyroxene (Mg#₉₅₋₇₇), plagioclase (An_95.6−91.6) and orthopyroxene (Mg#₆₈₋₇₇). Mineral chemistry of ultramafic and mafic cumulates suggest that highly magnesian olivines, clinopyroxenes and absence of plagioclase in the basal ultramafic cumulates are in good agreement with products of high-pressure crystal fractionation of primary basaltic melts beneath an island-arc environment. Major, trace element geochemistry of the cumulative rocks also indicate that Mersin ophiolite was formed in an arc environment. Coexisting Ca-rich plagioclase and Forich olivine in the gabbroic cumulates show arc cumulate gabbro characteristics. Field relations as well as the geochemical data support that Mersin ophiolite formed in a supra-subduction zone tectonic setting in the southern branch of the Neo-Tethys in southern Turkey.     

Morpho-tectonic evolution of the Marmara Sea inferred from multi-beam bathymetric and seismic data

In an initial stage, the Sea of Marmara developed as a graben and, in due course, considerable volumes of sediments were deposited in this basin. Before 200 ka, a new fault (New Marmara Fault) cutting through the whole basin developed, which postdated large sub-marine land sliding in the western part of the basin. This mass movement created the Western Ridge. The initiation of this strike-slip fault indicates that the extensional stress regime was replaced by a new, shearing stress field. In the eastern part of the Marmara Basin, the New Marmara Fault consists of two branches. The northern one replaces the normal faulting at the bottom of the northeastern slope of the basin. As a result, this slope has been rejuvenated. The southern branch is located along the central axis of the basin, forming the major extension of the North Anatolian Fault Zone within the region. Two restraining bends were formed because of the counterclockwise rotation of that part of the Anatolian Block. This resulted the uplifting of the Eastern Ridge and the formation of the positive flower structure within the Tekirdag Basin. The establishment of the compressional regime around the Sea of Marmara also resulted in the northwest–southeast shortening of the initial Marmara Basin.     

Heavy metal distribution in karst soils from Croatia and Slovakia

With the use of the optimised three-step BCR sequential-extraction procedure it was possible to assess the mobility of selected elements in soil profiles from Croatian and Slovakian karst terrains. The soils in the Croatian karst were enriched in Cr, Ni, V, Mn, Cu, Cd and Mo, while soils from the Slovak Karst had high Pb and Zn concentrations. It was determined that the elements were most readily mobilised from the topsoil and the degree of mobility decreased with depth. Cr and Ni were mainly bound to the residual fraction, and Pb in the oxidisable fraction. Cu mobility was high in samples treated with agrochemicals throughout the soil profile.     

Effect of lateral variation and model parameterization on surface wave dispersion inversion to estimate the average shallow structure in the Paraná Basin

The average layered structure of the intracratonic Paraná Basin, SE Brazil, is investigated with surface-wave group velocities from a small regional earthquake recorded by two broadband stations. Rayleigh and Love waves in the period range 1–4.2 s are used to infer average properties down to about 4 km. Genetic algorithm techniques are used to find the best fitting 1-D S-wave model. The inverted 1-D models show fair correlation with the average properties of the propagation paths as expected from geology and borehole information. However, different S-wave velocity models are obtained for the different inversion parameterizations. Since lateral heterogeneities are expected along the paths, several synthetic tests are performed with heterogeneous propagation paths. For approximately homogenous path (i.e., little lateral variation), the main features of the average synthetic model can be retrieved for different model parameterizations. For strong lateral variations, however, the average dispersion curve can produce very different 1-D inverted models depending on the parameterization. Also, the 1-D inverted models may differ significantly from the average properties of the inhomogeneous path, and wrong depths to interfaces may be inferred. For real data inversions, it is then suggested that various different parameterizations should be tested. If the resulting models show consistent features, this probably indicates homogeneity in the propagation path. But, if very different and unstable features are obtained in the 1-D inversions, then strong lateral variation may be present in the propagation path, and the average 1-D model may not represent average properties along the path.     

Relationships Between Fundamental Seismic Hazard Parameters for the Different Source Regions in Turkey

Turkey has been divided into eight different seismic regions taking into consideration the tectonic environments and epicenters of the earthquakes to examine relationships of the modal values (a/b), the expected maximum magnitudes (M_max) and the maximum intensities (I_max). For this purpose, the earthquakes for the time period 1900–1992 from the Global Hypocenter Data Base CD-ROM prepared by USGS, and for the time period 1993–2001 from the PDE data and IRIS data are used. Concerning the relationships developed between different magnitude scales and between surface wave magnitudes (M_S) and intensity for different source regions in Turkey, we have constructed a uniform catalog of M_S. We have estimated the values of M_max and I_max using the Gumbel III asymptotic distribution. Highest a-values are observed in the Aegean region and the lowest b-values are estimated for the North Anatolian Fault. Maximum values of a/b, M_max and I_max are related to the eastern and western part of the North Anatolian Fault and the Aegean Arc. The lowest values of all parameters are observed near the Mid Anatolian Fault system. Linear relationships have been calculated between a/b, M_max and I_max using orthogonal regression. If one of the three parameters is computed, two other parameters can be calculated empirically using these linear relationships. Hazard maps of M_max and I_max values are produced using these relationships for a grid of equally spaced points at 1°. It is observed that the maps produced empirically may be used as a measure of seismic hazard in Turkey.