Early Bartonian orthophragminids (Foraminiferida) from Reineche Limestone,north African platform,Tunisia: taxonomy and paleobiogeographic implications

The orthophragminids in lower Bartonian Reineche Limestone member, a fossiliferous shallow-marine unit exposed in Cap Bon peninsula in Tunisia, are represented by 17 species assigned to Discocyclinidae Galloway 1928 and Orbitoclypeidae Brönnimann 1946. These taxa, associated with nummulitids and alveolinids, belong to the lineages of Discocyclina Gümbel 1870, Nemkovella, 1987, Orbitoclypeus Silvestri 1907, and Asterocyclina Gümbel 1870, described for the first time from north Africa lying at the southern margin of Tethyan ocean during Paleogene. We identified Nemkovella evae, previously not recorded in upper Lutetian/lower Bartonian and younger Eocene deposits of northern Tethyan platforms, and erected a new subspecies, N. evae reinechensis n. ssp. A comparison of Reineche orthophraminids, assigned to orthophragmines zone (OZ) 12 and shallow benthic zone (SBZ 17), to the well-described coeval assemblages at northern Tethyan platforms in Italy, Hungary, Turkey, and to those in Kutch Basin in the Indian subcontinent suggests that some species are confined to certain paleogeographic domains. Orbitoclypeus haynesi, the only orbitoclypeid and the most abundant orthophragminid in lower Bartonian deposits in Kutch, appears to be the most common orbitoclypeid in Reineche Limestone. In Europe, this species is not known and is replaced by Orbitoclypeus varians, the most common orbitoclypeid in middle Eocene of central Europe. Both species occur in varying proportions in marine successions in Turkey. Asterocyclina sireli, identified so far only in Turkey, occurs in Reineche Limestone and in lower Bartonian deposits in Kutch. This species is recorded for the first time in the Indian subcontinent. Relying on present study, as well as our recent studies in Kutch Basin, we conclude that the generic and specific diversity of orthophragminids decreases eastward from the peri-Mediterranean region to Indian subcontinent and to the western Pacific.     

Climate change in Turkey for the last half century

Climate change and its urban-induced bias in selected Turkish cities is studied with a quality controlled temperature and precipitation data of Turkish stations in the period of 1950–2004. These stations are classified into two groups according to their populations; S1, including rural and suburban stations and S2, including large urban stations. Moving average signals, 365-day, and their digital low pass filtered versions are produced to eliminate the short term fluctuations and examine the possible trends or anomalies in climate data. Furthermore, ‘relative difference’ signals are introduced and applied to temperature and precipitation series to observe the actual local changes in the climate data independent from large-scale effects. Mann–Kendall test statistics are calculated for maximum, minimum, mean temperature and precipitation series and plotted on maps to determine any spatial trend patterns. Signal analysis show a cool period extending from early 1960s till 1993, generally with the lowest temperature values on 1992–1993 owing to the eruption of Mount Pinatubo. A last decade significant warming trend is observed in both of the series, S1 and S2, leading to 2000–2002 temperatures to be recorded as maximums in record history. The variability of urban precipitation series is generally larger than the rural ones, suggesting that urban stations can experience more frequent and severe droughts and floods. Though not significant, an increase in the urban precipitation compared to the rural one is also found. Spatial analysis resulted in significant warming in southern and southeastern parts of the country. Particularly, minimum temperature series show significant warming in almost all of the regions indicating the effect of urbanization. Significant decreases of precipitation amounts in the western parts of Turkey, such as Aegean and Trachea regions, are found. On the other hand, some Turkish northern stations show increases in precipitation of which some are significant.     

Petrology of Al- and Cr-rich ophiolitic chromitites from the Muğla,SW Turkey: implications from composition of chromite,solid inclusions of platinum-group mineral,silicate, and base-metal mineral,and Os-isotope geochemistry

Ultramafic rocks around the city of Muğla in SW Turkey are represented by mantle peridotites depleted to various degrees, ranging from cpx-rich harzburgites to depleted harzburgite and dunite. Cpx-rich harzburgites are thought to be the residua left after extraction of MORB-type basalt, from which high-Al chromitite [49.2 < Cr# = 100 × Cr/(Cr + Al) < 53.5] crystallised with a higher proportion of ¹⁸⁷Os/¹⁸⁸Os (average of 0.1361). However, depleted harzburgites are assumed to be the residua left after extraction of hydrous boninitic melt produced by second stage partial melting of already depleted mantle due to a subducting slab, from which high-Cr chromitites (64.2 < Cr# < 85.9) with lower and heterogeneous ¹⁸⁷Os/¹⁸⁸Os ratio (average of 0.1324) were crystallised as a result of melt–rock interaction in a supra-subduction environment. Dunites around the chromite deposits are considered to be the product of melt–peridotite interaction. Most of the chromitites contain high-Cr chromite and display enrichment in IPGE (Os, Ir, Ru) over PPGE (Rh, Pt, Pd), with PGE concentrations between 61 and 1,305 ppb. Consistently, laurite-erlichmanite series minerals with various Os concentrations are found to be the most abundant PGM inclusions in chromite. Os–Ir–Ru alloy, irarsite, and kashinite, as well as Pt–Fe alloy and Pt-oxide, which are not common in ophiolitic chromitites, were also detected as magmatic PGM inclusions. Pentlandite, millerite, and, rarely heazlewoodite form the magmatic inclusions of base-metal sulphide. The presence of olivine and clinopyroxene, as well as hydrous silicate inclusions such as amphibole and phlogopite, in high-Cr chromitite supports the idea that high-Cr chromitites were formed in a supra-subduction environment.     

An Easy Method for Interpretation of Gravity Anomalies Due to Vertical Finite Lines

A new method is introduced to determine the top and bottom depth of a vertical line using gravity anomalies. For this, gravity at a distance x from the origin and horizontal derivative at that point are utilized. A numerical value is obtained dividing the gravity at point x by horizontal derivative. Then a new equation is obtained dividing the theoretical gravity equation by the derivative equation. In that equation, assigning various values to the depth and length of vertical line, several new numerical values are obtained. Among these values, a curve is obtained for the one that is closest to the first value from attending the depth and length values. The intersection point of these curves obtained by repeating this procedure several times for different points x yield the real depth and length values of the line. The method is tested on two synthetics and field examples. Successful results are obtained in both applications.     

Phosphorus removal in low alkalinity secondary effluent using alum

The alkalinity plays an important role in phosphorus removal using coagulant. The dosage of coagulant in the low alkalinity wastewater is limited due to rapid pH changes. In the present study, a series of jar test was conducted using low alkalinity wastewater (50 mg/L) to evaluate the optimum pH, dosage and performance parameters (slow mixing and settling time) for the common coagulant alum. From the experiment, it was found that the dosage of coagulant and removal of phosphorus depend upon the pH of the wastewater after adding coagulant. The final optimum pH for efficient P removal was found to be within the range of 5.7–5.9. This range acts as an indicator and it is the maximum tolerable pH range for phosphorus removal for low alkalinity wastewater. The optimum time for slow mix and settling was found to be 20 min. The optimum mole ratio of alum to remove one mole of phosphorous was found to be 2.3. The alum coagulation at pH 7 produced effluent with the total residual phosphorus and reactive phosphorus content of 0.3 and 0.9 mg/L, respectively.     

Age and tectonomagmatic setting of the Eocene Çöpler–Kabataş magmatic complex and porphyry-epithermal Au deposit, East Central Anatolia, Turkey

The Çöpler epithermal Au deposit and related subeconomic porphyry Cu–Au deposit is hosted by the middle Eocene Çöpler–Kabata? magmatic complex in central eastern Anatolia. The intrusive rocks of the complex were emplaced into Late Paleozoic–Mesozoic metamorphosed sedimentary basement rocks near the northeastern margin of the Tauride-Anatolide Block. Igneous biotite from two samples of the magmatic complex yielded ⁴⁰Ar/³⁹Ar plateau ages of 43.75?±?0.26 Ma and 44.19?±?0.23, whereas igneous hornblende from a third sample yielded a plateau age of 44.13?±?0.38. These ages closely overlap with ⁴⁰Ar/³⁹Ar ages of hydrothermal sericite (44.44?±?0.28 Ma) and biotite (43.84?±?0.26 Ma), and Re–Os ages from two molybdenite samples (44.6?±?0.2 and 43.9?±?0.2 Ma) suggesting a short-lived (<1 my) magmatic and hydrothermal history at Çöpler. No suitable minerals were found that could be used to date the epithermal system, but it is inferred to be close in age to the precursor porphyry system. The Çöpler–Kabata? intrusive rocks show I-type calc-alkaline affinities. Their normalized trace element patterns show enrichments in large ion lithophile and light rare earth elements and relative depletions in middle and heavy rare earth elements, resembling magmas generated in convergent margins. However, given its distance from the coeval Eocene Maden–Helete volcanic arc, the complex is interpreted to be formed in a back-arc setting, in response to Paleocene slab roll-back and upper-plate extension. The tectonomagmatic environment of porphyry-epithermal mineralization at Çöpler is comparable to some other isolated back-arc porphyry systems such as Bajo de la Alumbrera (Argentina) or Bingham Canyon (USA).     

Subduction,ophiolite genesis and collision history of Tethys adjacent to the Eurasian continental margin: new evidence from the Eastern Pontides,Turkey

This paper presents several types of new information including U–Pb radiometric dating of ophiolitic rocks and an intrusive granite, micropalaeontological dating of siliceous and calcareous sedimentary rocks, together with sedimentological, petrographic and structural data. The new information is synthesised with existing results from the study area and adjacent regions (Central Pontides and Lesser Caucasus) to produce a new tectonic model for the Mesozoic–Cenozoic tectonic development of this key Tethyan suture zone.

The Tethyan suture zone in NE Turkey (Ankara–Erzincan–Kars suture zone) exemplifies stages in the subduction, suturing and post-collisional deformation of a Mesozoic ocean basin that existed between the Eurasian (Pontide) and Gondwanan (Tauride) continents. Ophiolitic rocks, both as intact and as dismembered sequences, together with an intrusive granite (tonalite), formed during the Early Jurassic in a supra-subduction zone (SSZ) setting within the ?zmir–Ankara–Erzincan ocean. Basalts also occur as blocks and dismembered thrust sheets within Cretaceous accretionary melange. During the Early Jurassic, these basalts erupted in both a SSZ-type setting and in an intra-plate (seamount-type) setting. The volcanic-sedimentary melange accreted in an open-ocean setting in response to Cretaceous northward subduction beneath a backstop made up of Early Jurassic forearc ophiolitic crust. The Early Jurassic SSZ basalts in the melange were later detached from the overriding Early Jurassic ophiolitic crust.

Sedimentary melange (debris-flow deposits) locally includes ophiolitic extrusive rocks of boninitic composition that were metamorphosed under high-pressure low-temperature conditions. Slices of mainly Cretaceous clastic sedimentary rocks within the suture zone are interpreted as a deformed forearc basin that bordered the Eurasian active margin. The basin received a copious supply of sediments derived from Late Cretaceous arc volcanism together with input of ophiolitic detritus from accreted oceanic crust.

Accretionary melange was emplaced southwards onto the leading edge of the Tauride continent (Munzur Massif) during latest Cretaceous time. Accretionary melange was also emplaced northwards over the collapsed southern edge of the Eurasian continental margin (continental backstop) during the latest Cretaceous. Sedimentation persisted into the Early Eocene in more northerly areas of the Eurasian margin.

Collision of the Tauride and Eurasian continents took place progressively during latest Late Palaeocene–Early Eocene. The Jurassic SSZ ophiolites and the Cretaceous accretionary melange finally docked with the Eurasian margin. Coarse clastic sediments were shed from the uplifted Eurasian margin and infilled a narrow peripheral basin. Gravity flows accumulated in thrust-top piggyback basins above accretionary melange and dismembered ophiolites and also in a post-collisional peripheral basin above Eurasian crust. Thickening of the accretionary wedge triggered large-scale out-of-sequence thrusting and re-thrusting of continental margin and ophiolitic units. Collision culminated in detachment and northward thrusting on a regional scale.

Collisional deformation of the suture zone ended prior to the Mid-Eocene (~45?Ma) when the Eurasian margin was transgressed by non-marine and/or shallow-marine sediments. The foreland became volcanically active and subsided strongly during Mid-Eocene, possibly related to post-collisional slab rollback and/or delamination. The present structure and morphology of the suture zone was strongly influenced by several phases of mostly S-directed suture zone tightening (Late Eocene; pre-Pliocene), possible slab break-off and right-lateral strike-slip along the North Anatolian Transform Fault.

In the wider regional context, a double subduction zone model is preferred, in which northward subduction was active during the Jurassic and Cretaceous, both within the Tethyan ocean and bordering the Eurasian continental margin.     

A different method for interpretation of magnetic anomalies due to 2-D dipping dikes

In this study a new method is presented to determine model parameters from magnetic anomalies caused by dipping dikes. The proposed method is applied by employing only the even component of the anomaly. First, the maximum of the even component is divided to its value at any distance x in order to obtain S1. Then, theoretical even component values are computed for the minimal depth (h) and half-width (b) values. S2 is obtained by dividing their maximum to the value computed for the same distance x. A set of S2 values is calculated by slowly increasing the half-width, and h and b for the S2 closest to S1 are determined. The same procedure is repeated by increasing the depth. The determined b values are plotted against the corresponding values of h. After repeating the process and plotting curves for different distances, it is possible to determine the actual depth and half-width values.