Geodetic techniques applied to the study of the Etna volcano area (Italy)

Volcanic behaviour of Mt. Etna is due to the complex interaction between both the local and the regional stress field involving the eastern Sicily. Eruptions could trigger (be triggered?) during crust extension and/or compression, which are strictly linked with the dynamics of the lower mantle. In this study, very long baseline interferometry (VLBI) space geodesy technique has been used in order to study Etna volcano’s activity by means of the crustal deformations between Noto and Matera (located on the African and the Eurasian Plates, respectively). By analysing VLBI data, we obtained the behaviour of the baseline which crosses the Etnean area, from 1990 December to 2003 March, representing the time variations of the distance between the two geodetic stations; the linear trend of the baseline shows a general increasing, pointing out an extension of the crust between them. A detailed analysis of the Noto-Matera baseline allows the identification of three parts of the VLBI curve in the considered period. In the first part of the curve (from 20/12/90 to 09/02/94), VLBI data are rather poor and therefore no reliable consideration about correlation between crust movements and volcanic and seismicity activity has been made. In the second part of the curve (from 09/02/94 to 04/09/00), VLBI data are more frequent and show slightly fluctuations in the distance. Increasing in the extension and compression were observed in the central and in the final part of this period. In the third period (from 04/09/00 to 25/03/03), VLBI data are very sparse even if the time series was quite long; therefore, to fill gaps in the information, we analysed global positioning system (GPS) data. GPS technique performs continuous observations, and we were able to highlight both extensions and compressions in detail. Comparisons between the trend of Noto-Matera baseline length variations, volcanic activity and seismicity in the Etna area show the complexity of the development over time and space of the phenomenology determined by a deep cause which can be traced, in our opinion, to the interaction between the asthenospheric mantle, deep crust and surface crust. Therefore, we state that crustal distension and compression are determined by the lower pulsating mantle.     

Efficiency of calcein tagging on juveniles of the sea urchins Diadema africanum and Paracentrotus lividus

We evaluated the effectiveness of chemical tagging with the fluorescent marker calcein for two key species of herbivorous sea urchins, Diadema africanum and Paracentrotus lividus, to facilitate medium‐ and long‐term ecological experiments. In total, 98 juveniles of D. africanum and 98 P. lividus were tagged with this fluorescent marker, with 12 combinations of different tagging techniques (chemical bath or injection), concentrations of calcein (2, 10 and 20 mg · l^?1), and soaking times (2, 4 and 24 h). Respective control treatments were conducted by means of seawater injection and bathing. The success of tagging was assessed after a month of feeding individuals ad libitum with the algae Dictyota sp. Sea urchins were dissected and their Aristotle's lanterns cleaned with 10% sodium hypochlorite to examine these structures under UV light using a binocular microscope. Each species was evaluated in terms of survival, percentage of tagged individuals and intensity of the resulting tag. The results showed that the method of soaking individuals of both species for 24 h in concentrations of calcein of 10 and 20 mg · l^?1 gave the highest percentage survival (100%) and the resulting tags were clearly visible.     

On the detection of (habitable) super-Earths around low-mass stars using Kepler and transit timing variation method

We present the results of an extensive study of the detectability of Earth-sized planets and super-Earths in the habitable zones of cool and low-mass stars using transit timing variation method. We have considered a system consisting of a star, a transiting giant planet, and a terrestrial-class perturber, and calculated TTVs for different values of the parameters of the system. To identify ranges of the parameters for which these variations would be detectable by Kepler, we considered the analysis presented by Ford et?al. (Transit timing observations from Kepler: I. Statistical analysis of the first four months. ArXiv:1102.0544, 2011) and assumed that a peak-to-peak variation of 20 s would be within the range of the photometric sensitivity of this telescope. We carried out simulations for resonant and non-resonant orbits, and identified ranges of the semimajor axes and eccentricities of the transiting and perturbing bodies for which an Earth-sized planet or a super-Earth in the habitable zone of a low-mass star would produce such TTVs. Results of our simulations indicate that in general, outer perturbers near first- and second-order resonances show a higher prospect for detection. Inner perturbers are potentially detectable only when near 1:2 and 1:3 mean-motion resonances. For a typical M star with a Jupiter-mass transiting planet, for instance, an Earth-mass perturber in the habitable zone can produce detectable TTVs when the orbit of the transiting planet is between 15 and 80 days. We present the details of our simulations and discuss the implication of the results for the detection of terrestrial planets around different low-mass stars.     

Crystal chemistry of amphiboles: implications for oxygen fugacity and water activity in lithospheric mantle beneath Victoria Land,Antarctica

Amphibole is the hydrous metasomatic phase in spinel-bearing mantle xenoliths from Baker Rocks, Northern Victoria Land, Antarctica. It occurs in veins or in disseminated form in spinel lherzolites. Both types derive from reaction between metasomatic melts and the pristine paragenesis of the continental lithospheric mantle beneath Northern Victoria Land. To determine the effective role of water circulation during the metasomatic process and amphibole formation, six amphibole samples were fully characterized. Accurate determination of the site population and the state of dehydrogenation in each of these amphiboles was carried out using single-crystal X-ray diffraction, electron microprobe and secondary ion mass spectroscopy on the same single crystal. The Fe³⁺/ΣFe ratio was determined by X-ray absorption near edge spectroscopy on amphibole powder. The degree of dehydrogenation determined by SIMS is 0.870–0.994 O3(O^2?) a.p.f.u., primary and ascribed to the Ti-oxy component of the amphibole, as indicated by atom site populations; post-crystallization H loss is negligible. Estimates of aH₂O (0.014–0.054) were determined from the dehydration equilibrium among end-member components assuming that amphiboles are in equilibrium with the anhydrous peridotitic phases. A difference up to 58 % in determination of aH₂O can be introduced if the chemical formula of the amphiboles is calculated based on 23 O a.p.f.u. without knowing the effective amount of dehydrogenation. The oxygen fugacity of the Baker Rocks amphibole-bearing mantle xenoliths calculated based upon the dissociation constant of water (by oxy-amphibole equilibrium) is between ?2.52 and ?1.32 log units below the fayalite–magnetite–quartz (FMQ) buffer. These results are systematically lower and in a narrow range of values relative to those obtained from anhydrous olivine–orthopyroxene–spinel equilibria (fO₂ between ?1.98 and ?0.30 log units). A comparative evaluation of the two methods suggests that when amphibole is present in mantle peridotites, the application of oxy-amphibole equilibrium is preferred, because ol–opx–sp oxy-calibrations are not “sensitive” enough in recording the effects (if any) of amphibole in the peridotite matrix. Amphibole acts as the main H acceptor among the peridotite minerals and may prevent fluid circulation and buffer oxygen fugacity. The important conclusion of this study is that amphibole within the lithospheric mantle does not always means high water activity and oxidizing conditions.     

Evolution of anisotropy with saturation and its implications for the elastoplastic responses of clay rocks

Many clay rocks have distinct bedding planes. Experimental studies have shown that their mechanical properties evolve with the degree of saturation (DOS), often with higher stiffness and strength after drying. For transversely isotropic rocks, the effects of saturation can differ between the bed-normal (BN) and bed-parallel (BP) directions, which gives rise to saturation-dependent stiffness and strength anisotropy. Accurate prediction of the mechanical behavior of clay rocks under partially saturated conditions requires numerical models that can capture the evolving elastic and plastic anisotropy with DOS. In this study, we present an anisotropy framework for coupled solid deformation-fluid flow in unsaturated elastoplastic media. We incorporate saturation-dependent strength anisotropy into an anisotropic modified Cam-Clay (MCC) model and consider the evolving anisotropy in both the elastic and plastic responses. The model was calibrated using experimental data from triaxial tests to demonstrate its capability in capturing strength anisotropy at various levels of saturation. Through numerical simulations, we demonstrate the role of evolving stiffness and strength anisotropy in the mechanical behavior of clay rocks. Plane strain simulations of triaxial compression tests were also conducted to demonstrate the impacts of material anisotropy and DOS on the mechanical and fluid flow responses.     

Paleoenvironmental dynamics in central-eastern Brazil during the last 23 000 years: tropical peatland record in the Cerrado biome

The Cerrado biome is the second largest in Brazil, but the evolution of the Cerrado during the late Quaternary is not yet fully known. This study identifies paleoenvironmental changes during the last 23 000 years, based on a tropical mountain peatland record, in the Serra do Espinhaço Meridional in central-eastern Brazil. A multi-proxy approach was used that involved palynological analysis, stable isotopes (δ¹³C, δ¹⁵N), geochemistry, radiocarbon dating and multivariate statistics derived from a peatland core from Rio Preto (Minas Gerais state). The study reveals a very humid and cold climate during the late Pleistocene, with an increase in temperature and decrease in humidity at the Pleistocene–Holocene transition. During this period there was strong instability in the landscape (episodes of erosion). At the beginning of the Holocene there was a reduction in humidity with greater landscape stability. The current sub-humid climatic conditions seem to have been established in the mid-/late Holocene, with periods of landscape instability. Our findings agree with other Cerrado records that contradict previously established hypotheses, such as the Amazonian Refuge and the Pleistocene Arc.