This work concludes the investigations into the stability of haline flows in saturated porous media. In the first part [33] a stability criterion for density-driven flow in a saturated homogeneous medium was derived excluding dispersion. In the second part [34], the effects of dispersion were included. The latter criterion made reasonable predictions of the stability regimes (indicated by the number of fingers present) as a function of density and dispersivity variations. We found out that destabilising variables caused an increase in the number of fingers and vice versa. The investigation is extended here for the effects of the medium heterogeneity. The cell problem derived via homogenization theory [20] is solved and its solution used to evaluate the elements of the macrodispersion tensor as functions of time for flow aligned parallel to gravity. The longitudinal coefficient exhibits asymptotic behaviour for favourable and moderately unfavourable density contrasts while it grows indefinitely for higher density contrasts. The range of densities stabilised by medium heterogeneities can thus be estimated from the behaviour of the coefficient. The d3f software program is used for the numerical simulations. The code uses the cell-centred finite volume and the implicit Euler techniques for the spatial and temporal discretisations respectively. 相似文献
Arid and Alpine ecosystems are known for extreme environmental changes during the Late Quaternary. We hypothesize that the world's largest Alpine arid ecosystem however, the Alpine Steppes of the Tibetan highlands, remained ecologically stable during the LGM and the mid-Holocene. This hypothesis is tested by distributional range of plant species, plant life forms and rate of endemism. The set of character species has a precipitation gradient between 50 and 350 mm/a, testifying for resilience to precipitation changes. 83% of the species have a wider vertical range than 1000 m used as a proxy for resilience to temperature changes. 30% of the species are endemic with 10 endemic genera, including plate-shaped cushions as a unique plant life form. These findings are in line with palaeo-ecological proxies (δ18O, pollen) allowing the assumption that Alpine Steppes persisted during the LGM with 3 to 4 K lower summer temperatures.During the mid-Holocene, forests could have replaced Alpine Steppes in the upper catchments of the Huang He, Yangtze, Mekong, Salween and Yarlung Zhangbo, but not in the interior basins of the north-western highlands, because the basins were then flooded, suppressing forests and supporting the environmental stability of this arid Alpine grassland biome. 相似文献
Purified natural clinoptilolite from the Tasajeras deposit, Cuba, and some of its metal exchanged forms are studied, at the
dehydrated state, by means of dielectric relaxation spectroscopy (DRS) using two different modus operandi: complex impedance
spectroscopy and dielectric dynamic thermal analysis. Data analysis yields the determination of the extra-framework cation
(EFC) population into the various possible crystallographic sites of the zeolitic framework as well as of the activation energy
characterizing the localized hopping mechanism of EFC. First, it is shown that the DRS responses obtained here match well
with the previous reported data, which were previously localized EFCs in positions close to M1 and M2 sites when the clinoptilolite
is modified to almost homoionic form. From this outcome, it can be concluded that all EFCs are in the same crystallographic
situation regarding solvation or, in other terms, that no steric effect can be taken into account to explain cationic selectivity.
Second, based on the assumption that the activation energy for EFC hopping is directly connected to the EFC/framework interaction
and on simple thermodynamics consideration, we show this interaction does not govern the EFC exchange reaction. So, it is
emphasized that EFC/H2O interaction is the key factor for cation exchange selectivity. 相似文献
Subduction of high bathymetric relief, such as aseismic ridges and magmatic plateaus, is considered to be responsible for dramatic changes in the dynamics and kinematics of the subduction zone. For example, the buoyancy of high bathymetric relief is thought to flatten the dip of the subducting slab, modifying the structural and magmatic evolution of the overriding plate and terminating arc volcanism. In addition, the effect of ridge subduction in retreating plate boundaries can inhibit subduction rollback, a process that could locally pin the subduction hinge and lead to the development of cusps and slab tearing. Here we discuss the tectonic response to subduction of high bathymetric relief using examples from the circum-Pacific subduction systems. We demonstrate that flattening of the subduction dip angle is only significant in the eastern Pacific, where the average slab dip angle is relatively shallow. In the western Pacific, in contrast, the average subduction dip angle is steeper and there is no significant flattening of the dip angle in areas of ridge subduction. Subduction of high bathymetric relief in the circum-Pacific is commonly associated with reduced arc volcanism, and in many cases, the area of ridge subduction coincides with a volcanic gap. In the overriding plate, ridge subduction is associated with pronounced changes in the style of deformation, involving uplift, reactivation of basement thrusts, development of orogen-perpendicular tear faults and block rotations leading to oroclinal bending. The discussed characteristic patterns associated with ridge subduction provide important guidelines for reconstructing past plate tectonic processes, and could help constraining the geodynamics of ancient subduction systems. 相似文献
Todorokite is considered to form from vernadite in nature and commonly concentrates nickel. However, this mineralogical transformation has never been imaged nor explained mechanistically, and its effect on the uptake of nickel has never been quantified at the molecular-level. We have characterized these reactions at the macroscopic, microscopic, nanoscopic and atomic scales in a marine manganese concretion by combining transmission electron microscopy, electron and X-ray microprobe analysis, powder and micro X-ray diffraction, and Mn and Ni K-edge EXAFS spectroscopy. The concretion was collected during the Ticoflux II expedition near the Nicoya Peninsula, Costa Rica, and is representative of Mn deposits in hemipelagic sediments. It consists of 5 to 25 μm aggregates, shaped like sea-urchins, with a core of 7Å-vernadite (1.0 wt% Ni), a rim of 10Å-vernadite (3.8 wt% Ni), and an outermost region of todorokite fibers (1.9 wt% Ni) that extend outwards. The crystallites of 7Å-vernadite are single- to bi-layered, with hexagonal layer symmetry (a = b = 2.83 Å), and an average structural formula of . The crystallites of 10Å-vernadite contain 10 to 20 layers semi-coherently stacked in the ab plane and uniformly separated in the [0 0 1] direction by ∼9 Å due to the intercalation of hydrated Mg2+ cations. The average structural formula of 10Å-vernadite is if the layers contain vacancy sites, or alternately , if they contain Mn3+. The average formula of todorokite is .A genetic model is proposed based on combining these new data with previously published results. The thermodynamically unstable 7Å-vernadite transforms via dissolution-recrystallization to semi-ordered Mg-rich 10Å-vernadite. Nickel is released from dissolved biogenic silica or reduced organic matter, and taken up mainly in the Mn layer of 10Å-vernadite. Interlayer magnesium serves as a template to the further topotactic transformation of 10Å-vernadite to todorokite. The dimension of the todorokite tunnels in the [0 0 1] direction is uniform and determined by the size of the hydrated Mg2+ ion (8.6 Å). The tunnel dimension in the [1 0 0] direction depends on the density of Mg2+ in the interlayer and the superstructure of the phyllomanganate layer. If the parent phyllomanganate contains high amounts of Mg2+ (i.e., high layer charge), or Mn3+ and Mn4+ cations ordered following the Mn3+-Mn4+-Mn4+ sequence as in synthetic triclinic birnessite, then the tunnel dimension is ideally 3 × 3 octahedral chain widths in both crystallographic directions. Otherwise, the tunnel dimension is incoherent in the [1 0 0] direction (i.e., T(3,n) tunnel structure), as has been observed in all natural todorokites. Natural todorokite is defective because the precursor natural phyllomanganates either have a layer charge deficit below 0.33e per octahedral site, or rarely are triclinic birnessite. The abundance of Mg in seawater and its key role in converting phyllomanganate to tectomanganate with T(3,n) tunnel structure explain why todorokite is common in marine ferromanganese oxides, and seldom present in terrestrial environments. The topotactic phase transformation described here is the only known route to todorokite crystallization. This implies that all natural todorokites may be authigenic because they are formed in situ from a phyllomanganate precursor. 相似文献
Garber Schlag (Q-GS) is one of the major springs of the Karwendel Mountains, Tyrol, Austria. This spring has a unique runoff pattern that is mainly controlled by the tectonic setting. The main aquifer is a moderately karstified and jointed limestone of the Wetterstein Formation that is underlain by nonkarstified limestone of the Reifling Formation, which acts as an aquitard. The aquifer and aquitard of the catchment of spring Q-GS form a large anticline that is bound by a major fault (aquitard) to the north. Discharge of this spring shows strong seasonal variations with three recharge origins, based on δ18O and electrical conductivity values. A clear seasonal trend is observed, caused by the continuously changing portions of water derived from snowmelt, rainfall and groundwater. At the onset of the snowmelt period in May, the discharge is composed mainly of groundwater. During the maximum snowmelt period, the water is dominantly composed of water derived from snowmelt and subordinately from rainfall. During July and August, water derived from snowmelt continuously decreases and water derived from rainfall increases. During September and October, the water released at the spring is mainly derived from groundwater and subordinately from rainfall. The distinct discharge plateau from August to December and the following recession until March is likely related to the large regional groundwater body in the fissured and moderately karstified aquifer of the Wetterstein Formation and the tectonic structures (anticline, major fault). Only a small portion of the water released at spring Q-GS is derived from permafrost.
The southwestern Pacific region consists of segmented and translated continental fragments of the Gondwanan margin. Tectonic reconstructions of this region are challenged by the fact that many fragmented continental blocks are submerged and/or concealed under younger sedimentary cover. The Queensland Plateau (offshore northeastern Australia) is one such submerged continental block. We present detrital zircon geochronological and morphological data, complemented by petrographic observations, from samples obtained from the only two drill cores that penetrated the Paleozoic metasedimentary strata of the Queensland Plateau (Ocean Drilling Program leg 133, sites 824 and 825). Results provide maximum age constraints of 319.4 ± 3.5 and 298.9 ± 2.5 Ma for the time of deposition, which in conjunction with evidence for deformation, indicate that the metasedimentary successions are most likely upper Carboniferous to lower Permian. A comparison of our results with a larger dataset of detrital zircon ages from the Tasmanides suggests that the Paleozoic successions of the Queensland Plateau formed in a backarc basin that was part of the northern continuation of the New England Orogen and/or the East Australian Rift System. However, unlike most of the New England Orogen, a distinctive component of the detrital zircon age spectra of the Mossman Orogen is also recognised, suggesting the existence of a late Paleozoic drainage system that crossed the northern Tasmanides en route from the North Australian Craton. A distinctive shift from abraded zircon grains to grains with well-preserved morphology at ca 305 Ma reflects a direct drainage of first-cycle sediments, most likely from an outboard arc and/or backarc magmatism. 相似文献
International Journal of Earth Sciences - Three-dimensional geophysical modelling of the early Late Miocene Pásztori volcano (ca. 11–10 Ma) and adjacent area in the Little... 相似文献
The occurrence of increasing blooms of toxic cyanobacteria in freshwaters has received much attention due to the ability of many cyanobacteria to produce potent cyanotoxins. In this paper, the occurrence of dominant cyanobacteria and the concentration of microcystins (MCs) analysis were investigated monthly from July 2008 to April 2009 in the Hoan Kiem Lake and from February to April 2009 in the Nui Coc reservoir. Concentrations of intracellular MCs from water, bloom samples, and isolated strains were quantified by using high performance liquid chromatography (HPLC). During the study period, the microscopic examination of the phytoplankton samples showed the dominance of the genus Microcystis in the water environment of the Hoan Kiem Lake and the Nui Coc reservoir. The toxin analysis by HPLC demonstrated the presence of two MC variants: MC-LR and MC-RR in water samples. Total concentrations of the toxins in filtered samples from surface water ranged from non-detected to 0.91 μg L?1 at Nui Coc reservoir and they ranged from 2.1 to 46.0 μg L?1 at Hoan Kiem Lake. The results of the HPLC analysis confirmed the production of MCs in bloom samples (ranged from 115.9 to 184.6 μg L?1 in the Hoan Kiem Lake and from 726.5 to 1116 μg L?1 in the Nui Coc reservoir) and isolated strains of Anabaena sp. and Microcystis with the concentration of MC ranging from 152 to 396.2 μg g?1 dry mass, respectively. 相似文献
Throughout much of Earth's history, marine carbonates have represented one of the most important geological archives of environmental change. Several pivotal events during the Phanerozoic, such as mass extinctions or hyperthermal events have recently been associated with ocean acidification. Nevertheless, well‐defined geological proxies for past ocean acidification events are, at best, scarce. Here, experimental work explores the response of bivalve shell ultrastructure and isotope geochemistry (δ13C, δ18O and δ26Mg) to stressful environments, in particular to sea water acidification. In this study, the common blue mussel, Mytilus edulis, was cultured (from early juvenile stages to one year of age) at four pH regimes (pHNBS 7·2 to pH 8·0). Shell growth rate and ultrastructure of mainly the calcitic portion of the shells were compared between experimental treatments. Specimens exposed to low‐pH environments show patches of disordered calcitic fibre orientation in otherwise well‐structured shells. Furthermore, the electron backscattered diffraction analyses reveal that, under acidified conditions, the c‐axis of the calcite prisms exhibits a bimodal or multi‐modal distribution pattern. Similar shell disorder patterns have been reported from mytilids kept under naturally acidified sea water conditions. In contrast, this study found no evidence that different pH regimes affect shell carbon, oxygen or magnesium isotope ratios. Based on these observations, it is proposed that: (i) stressful environments, in this case low sea water pH, predictably affect bivalve biomineralization patterns; and (ii) these findings bear potential as a novel (petrographic) proxy for ancient sea water acidification. An assessment of the applicability of these data to well‐preserved fossil shell material from selected time intervals requires additional work. 相似文献