Volcanisme de l'ı̂le aux Pingouins,archipel Crozet,témoin de l'hétérogénéité du manteau fertile au sud de l'océan IndienPenguins Island,Crozet archipelago,volcanic evidence for a heterogeneous mantle in the southern Indian Ocean

Despite its small area (5.6 km²), the Penguins Island brings magmatic information concerning mantle geochemical heterogeneities in southwestern Indian Ocean. The volcanism that built the island was firstly associated with marine deposits, and secondly with aerial, giving then abundant volcanic breccias and lava flows. The rocks are weakly differentiated and result of magmatic fractionation from picritic to tephritic types. KAr ages are near 1.1 Ma. The magmatic source may be related to a HIMU reservoir or to EMI ± EMII ones, depending on the geochemical evidences that are taken into account. However, comparisons with the Marion Island, on the same oceanic plateau and far to the west, as well as with Kerguelen Islands, far to the east, suggest a very heterogeneous mantle source. To cite this article: A. Giret et al., C. R. Geoscience 334 (2002) 481–488.     

Predicting selenite adsorption by soils using soil chemical parameters in the constant capacitance model

The constant capacitance model, a chemical surface complexation model, was applied to selenite, Se(IV), adsorption on 36 soils selected for variation in soil chemical properties. The constant capacitance model was able to fit Se(IV) adsorption by optimizing one monodentate Se(IV) surface complexation constant and the surface protonation constant. A general regression model was developed for predicting these surface complexation constants for Se(IV) from easily measured soil chemical characteristics. These chemical properties were inorganic carbon content, organic carbon content, iron oxide content, aluminum oxide content, and surface area. The prediction equations were used to obtain values for the surface complexation constants for four additional soils, thereby providing a completely independent evaluation of the ability of the constant capacitance model to describe Se(IV) adsorption. The model’s ability to predict Se(IV) adsorption was quantitative on one soil and semi-quantitative on three soils. Incorporation of these prediction equations into chemical speciation-transport models will allow simulation of soil solution Se(IV) concentrations under diverse non-calcareous agricultural and environmental conditions without the requirement of soil specific adsorption data and subsequent parameter optimization.     

Hunter–Bowen deformation in South Percy Island,northeastern Australia

South Percy Island is located approximately 50 km off the central Queensland coast and comprises a disrupted ophiolite mass alongside a diverse array of metamorphosed felsic and mafic rocks that record several episodes of magmatism, volcanism and deformation from the Permian to Early Cretaceous. This paper aims to constrain the age, affinity and deformation history of these units, as well as to establish the tectonic significance of the terrane. The trace-element compositions of mafic and felsic meta-igneous rocks record a change from MORB-like prior to ca 277 Ma to subduction-related by ca 258 Ma. Overprinting relationships between intrusive phases and deformation features reveal a relative chronology for the tectonothermal evolution of the area, while U–Pb and ⁴⁰Ar/³⁹Ar geochronology provides absolute age constraints. Deformation is localised around a NNE-striking tectonic contact that separates serpentinised ultramafic rocks from metamorphosed pillow lavas. Early formed ductile fabrics associated with the main episode of deformation (D₁) preserve bulk flattening strains at greenschist-facies conditions. Emplacement and post-kinematic cooling ages of a pre-D₁ quartz-monzonite dyke constrain the age of D₁/M₁ deformation and metamorphism to the period between ca 258 and ca 248 Ma. Minor brittle deformation (D₂) occurred at ca 230 Ma, based on U–Pb dating of a syn-D₂ diorite dyke (ca 231 ± 10 Ma) and several ca 230 Ma ⁴⁰Ar/³⁹Ar cooling ages. The deformation, metamorphism, and supra-subduction zone magmatism preserved on South Percy Island is correlated with the nearby Marlborough Terrane and more broadly with the second pulse of the Hunter–Bowen Orogeny, which affected much of the central and northern parts of eastern Australia in the late Permian and Early Triassic. Our results support previous suggestions that the second pulse of the Hunter–Bowen Orogeny involved coeval thrust systems in both the inboard and outboard parts of the orogen.     

A Critical Analysis of Transverse Dispersivity Field Data

Transverse dispersion, or tracer spreading orthogonal to the mean flow direction, which is relevant e.g, for quantifying bio-degradation of contaminant plumes or mixing of reactive solutes, has been studied in the literature less than the longitudinal one. Inferring transverse dispersion coefficients from field experiments is a difficult and error-prone task, requiring a spatial resolution of solute plumes which is not easily achievable in applications. In absence of field data, it is a questionable common practice to set transverse dispersivities as a fraction of the longitudinal one, with the ratio 1/10 being the most prevalent. We collected estimates of field-scale transverse dispersivities from existing publications and explored possible scale relationships as guidance criteria for applications. Our investigation showed that a large number of estimates available in the literature are of low reliability and should be discarded from further analysis. The remaining reliable estimates are formation-specific, span three orders of magnitude and do not show any clear scale-dependence on the plume traveled distance. The ratios with the longitudinal dispersivity are also site specific and vary widely. The reliability of transverse dispersivities depends significantly on the type of field experiment and method of data analysis. In applications where transverse dispersion plays a significant role, inference of transverse dispersivities should be part of site characterization with the transverse dispersivity estimated as an independent parameter rather than related heuristically to longitudinal dispersivity.     

Strategies to improve the explanatory power of a dynamic slope stability model by enhancing land cover parameterisation and model complexity

Despite the importance of land cover on landscape hydrology and slope stability, the representation of land cover dynamics in physically based models and their associated ecohydrological effects on slope stability is rather scarce. In this study, we assess the impact of different levels of complexity in land cover parameterisation on the explanatory power of a dynamic and process-based spatial slope stability model. Firstly, we present available and collected data sets and account for the stepwise parameterisation of the model. Secondly, we present approaches to simulate land cover: 1) a grassland landscape without forest coverage; 2) spatially static forest conditions, in which we assume limited knowledge about forest composition; 3) more detailed information of forested areas based on the computation of leaf area development and the implementation of vegetation-related processes; 4) similar to the third approach but with the additional consideration of the spatial expansion and vertical growth of vegetation. Lastly, the model is calibrated based on meteorological data sets and groundwater measurements. The model results are quantitatively validated for two landslide-triggering events that occurred in Western Austria. Predictive performances are estimated using the Area Under the receiver operating characteristic Curve (AUC). Our findings indicate that the performance of the slope stability model was strongly determined by model complexity and land cover parameterisation. The implementation of leaf area development and land cover dynamics further yield an acceptable predictive performance (AUC ~0.71-0.75) and a better conservativeness of the predicted unstable areas (FoC ~0.71). The consideration of dynamic land cover expansion provided better performances than the solely consideration of leaf area development. The results of this study highlight that an increase of effort in the land cover parameterisation of a dynamic slope stability model can increase the explanatory power of the model. © 2018 The Authors. Earth Surface Processes and Landforms published by John Wiley & Sons Ltd.     

Factors controlling aggregate formation in the benthic boundary layer of the Mecklenburg Bight (western Baltic Sea)

Studies on aggregate formation and size distribution in relation to bottom water composition and flow regime were carried out in November 1994 at two transects in the inner and outer Mecklenburg Bight (Baltic Sea). The bottom water sampler ‘BIOPROBE' (BWS) was used to collect 10-dm³ water samples at 5, 10, 20 and 40 cm above the seabed. The outer transect samples tended to be more influenced by the open western Baltic Sea, whereas the inner transect samples were more affected by the coastal hydrography. Aggregate size distribution was investigated using a newly developed particle camera allowing identification of particles down to 150 μm size. Increasing concentrations of total particulate matter (TPM), particulate organic carbon (POC) and chlorophyll pigment equivalents (CPE) towards the seafloor together with a low proportion of POC/TPM (<5%) implied that the material was of resuspended origin. Aggregate size in both transects was positively correlated with TPM, transparent exopolymer particles (TEP) and bacterial cell abundance. Higher particle concentrations and aggregate numbers in the outer transect indicated a higher resuspension frequency, or lateral advection processes. The higher concentration of aggregates at the outer transect may reflect the larger amount of near-bottom transported material.     

Gas hydrates in shallow deposits of the Amsterdam mud volcano, Anaximander Mountains, Northeastern Mediterranean Sea

We investigated gas hydrate in situ inventories as well as the composition and principal transport mechanisms of fluids expelled at the Amsterdam mud volcano (AMV; 2,025 m water depth) in the Eastern Mediterranean Sea. Pressure coring (the only technique preventing hydrates from decomposition during recovery) was used for the quantification of light hydrocarbons in near-surface deposits. The cores (up to 2.5 m in length) were retrieved with an autoclave piston corer, and served for analyses of gas quantities and compositions, and pore-water chemistry. For comparison, gravity cores from sites at the summit and beyond the AMV were analyzed. A prevalence of thermogenic light hydrocarbons was inferred from average C₁/C₂₊ ratios <35 and δ¹³C-CH₄ values of ?50.6‰. Gas venting from the seafloor indicated methane oversaturation, and volumetric gas–sediment ratios of up to 17.0 in pressure cores taken from the center demonstrated hydrate presence at the time of sampling. Relative enrichments in ethane, propane, and iso-butane in gas released from pressure cores, and from an intact hydrate piece compared to venting gas suggest incipient crystallization of hydrate structure II (sII). Nonetheless, the co-existence of sI hydrate can not be excluded from our dataset. Hydrates fill up to 16.7% of pore volume within the sediment interval between the base of the sulfate zone and the maximum sampling depth at the summit. The concave-down shapes of pore-water concentration profiles recorded in the center indicate the influence of upward-directed advection of low-salinity fluids/fluidized mud. Furthermore, the SO ₄ ^2? and Ba²⁺ pore-water profiles in the central part of the AMV demonstrate that sulfate reduction driven by the anaerobic oxidation of methane is complete at depths between 30 cm and 70 cm below seafloor. Our results indicate that methane oversaturation, high hydrostatic pressure, and elevated pore-water activity caused by low salinity promote fixing of considerable proportions of light hydrocarbons in shallow hydrates even at the summit of the AMV, and possibly also of other MVs in the region. Depending on their crystallographic structure, however, hydrates will already decompose and release hydrocarbon masses if sediment temperatures exceed ca. 19.3°C and 21.0°C, respectively. Based on observations from other mud volcanoes, the common occurrence of such temperatures induced by heat flux from below into the immediate subsurface appears likely for the AMV.     

Cooperite and braggite from the Bushveld Complex: implications for the miscibility gap and identification

Analyses of the Pt-Pd-Ni sulphides cooperite, braggite, and vysotskite reported from worldwide occurrences seem to imply a continuum of compositions between vysotskite and cooperite, with no obvious miscibility gap. This is contrary to the experimentally confirmed miscibility gap between cooperite and braggite, and the established compositional gap between co-existing cooperite and braggite from the Merensky Reef. Although the only unambiguous way of distinguishing between cooperite and braggite is to obtain structural information through X-ray diffraction or equivalent techniques, most identification of Pt-Pd-Ni sulphides is based on microanalytical techniques due to the small grain size of most platinum-group minerals. Ni contents also have to be considered because a classification based on the Pt/Pd ratio alone can be very misleading. Naming of Pt-Pd-Ni sulphide compositions with high Pt contents based on qualitative or semi-quantitative analyses should be avoided. Natural Pt-Pd-Ni sulphides which project into the compositional gap (established by experimental work) cannot be named without supporting structural information. Compositions of grains, which plot inside the gap, are considered to be metastable and to result from the loss of Pd through interaction with hydrothermal fluids.     

Numerical dynamo models of Uranus' and Neptune's magnetic fields

The non-axisymmetric, non-dipolar magnetic fields of Uranus and Neptune are markedly different from the axially-dipolar dominated fields of the other planets in our Solar System with active dynamos. Stanley and Bloxham [Stanley, S., Bloxham, J., 2004. Nature 428, 151-153] used numerical modeling to demonstrate that Uranus' and Neptune's unusual fields could be the result of a different convective region geometry in these planets. They found that a numerical dynamo operating in a thin shell surrounding a stably-stratified fluid interior produces magnetic field morphologies similar to those of Uranus and Neptune. This geometry for the convective region was initially proposed by Hubbard et al. [Hubbard, W.B., Podolak, M., Stevenson, D.J., 1995. In: Cruickshank, D. (Ed.), Neptune and Triton. Univ. of Arizona Press, Tucson, pp. 109-138] to explain both the magnetic field morphology as well as the low intrinsic heat flows from these planets. Here we examine the influence of varying the stable layer radius in numerical models and compare the results to thin shell models surrounding solid inner cores. We find that a limited range of stable-layer shell thicknesses exist in which Uranus/Neptune-like field morphologies result. This allows us to put constraints on the size of the convective layers in Uranus and Neptune.     

Analysis of undisturbed layers of a waste deposit landfill – Insights into the transformation and transport of organic contaminants

Comprehensive GC/MS analysis was applied to both the mobile liquid phase (seepage water) and the immobile solid matter of discrete layers derived from a waste deposit landfill. The vertical distribution of organic compounds supports information on the transport, transfer and transformation processes with depth and, consequently, with time.Numerous low molecular weight organic contaminants of natural and xenobiotic origin were identified and partially quantified. Several were selected to act as molecular indicators for different processes. Interpretation of their occurrence and concentration profiles (considering possible waste sources) and their molecular properties allowed us to (i) differentiate immobile and mobile fractions, (ii) reveal restrictions in the vertical transport by transfer processes between particulate and water phase, (iii) identify dynamic accumulations of individual contaminants and (iv) estimate approximate residence times. In addition, intensive degradation processes were pointed out for the natural fraction of the organic matter by way of determination of specific transformation products. Besides the transformation of natural components, transformation of numerous xenobiotics was recognised. In particular, with respect to an important group of contaminants, the phthalate-based plasticisers, a detailed view of (i) the influence of transfer and transport phenomena on transformation processes as well as (ii) the consecutive appearance of different degradation steps in both seepage water and solid waste was pointed out. The information provides a valuable base for the prediction of the long term behaviour of organic contaminants in waste deposit landfills.