The effect of different second-phase particle regimes on grain growth in two-phase aggregates: insights from in situ rock analogue experiments

The aim of the study was to investigate the effect of rigid second phases on grain growth of a matrix phase. For this purpose, variable mixtures of norcamphor as the matrix phase, with glass beads (0.08–0.51 volume fraction) as second phase, were used to perform see-through rock-analogue experiments under static conditions at constant temperatures (50°C). Irrespective of the second-phase content, grain-size evolution of all mixtures can be subdivided into a stage of continuous grain growth, a transient stage and a stage of a finally stabilized grain size. On the grain-scale, the second phases affect the migrating grain boundaries either by pinning by single particles, by multiple particles or even by particle clusters. Summed up over the entire aggregate, these pinning regimes affect the average bulk grain size of the matrix grains, such that the changes in matrix grain size directly correlate with the amount of second phases, their dispersion and their degree of clustering. In this way, the matrix grain size decreases with increasing second-phase content, which can be expressed as a Zener relationship. Originating from the modification of an ordinary grain growth law, a new mathematical expression is defined, which allows the calculation of changes in the matrix grain size as a function of different second-phase volume fractions and particle sizes. Such models will be helpful in the future to predict microstructural changes in polymineralic rocks at depth.     

Gas in Groups and Clusters of Galaxies

Groups and clusters contain a large fraction of hot gas which emitsX-ray radiation. This gas yields information on the dynamical stateand on the total mass of these systems. X-ray spectra show that heavyelements are present in the gas. As these metals must have beenproduced in the cluster/group galaxies and later transported into thegas, the metallicity is a good tracer for the transport processes. Severalpossible processes, that transport gas from the small potential wellsof the galaxies into the clusters and groups, are discussed.     

Long‐Term Sediment Export Estimates from Northern Jordan using Roman Cisterns as Sediment Traps

Roman cisterns served as rainwater storage devices for centuries and are densely distributed in parts of northern Jordan. A major earthquake hit the region ca. A.D. 750 and in a short time many settlements were abandoned. As a consequence, most cisterns were not maintained, and they filled with sediments that today provide a postabandonment depositional record. In two field surveys, we mapped the locations of more than 100 cisterns in the Wadi Al‐Arab basin and selected two for detailed stratigraphic analysis that included ¹⁴C and optically stimulated luminescence dating. Catchment basin area for each cistern was determined by differential GPS. Both cisterns filled with sediments after the great earthquake and consequent abandonment of the region. Calculated sediment volumes are translated to long‐term average sediment export rates of 2.6–6.6 t ha⁻¹a⁻¹, which are comparable to erosion and sediment yield rates from other studies within the Mediterranean region. Our pilot study suggests that this approach can be applied elsewhere to calculate long‐term sediment export rates on hill slopes containing relict cisterns.     

Numerical dynamo models of Uranus' and Neptune's magnetic fields

The non-axisymmetric, non-dipolar magnetic fields of Uranus and Neptune are markedly different from the axially-dipolar dominated fields of the other planets in our Solar System with active dynamos. Stanley and Bloxham [Stanley, S., Bloxham, J., 2004. Nature 428, 151-153] used numerical modeling to demonstrate that Uranus' and Neptune's unusual fields could be the result of a different convective region geometry in these planets. They found that a numerical dynamo operating in a thin shell surrounding a stably-stratified fluid interior produces magnetic field morphologies similar to those of Uranus and Neptune. This geometry for the convective region was initially proposed by Hubbard et al. [Hubbard, W.B., Podolak, M., Stevenson, D.J., 1995. In: Cruickshank, D. (Ed.), Neptune and Triton. Univ. of Arizona Press, Tucson, pp. 109-138] to explain both the magnetic field morphology as well as the low intrinsic heat flows from these planets. Here we examine the influence of varying the stable layer radius in numerical models and compare the results to thin shell models surrounding solid inner cores. We find that a limited range of stable-layer shell thicknesses exist in which Uranus/Neptune-like field morphologies result. This allows us to put constraints on the size of the convective layers in Uranus and Neptune.     

Star Formation in NGC 4038/4039 as seen in the NIR

We obtained various sets of near infrared observations of the prototypical merger, NGC 4038/4039 (‘the Antennae’). Integral field spectroscopy and broad- and narrow band imaging aimed at obtaining age and extinction estimates of the young star clusters seen in large numbers distributed throughout the disks of the interacting galaxies. High resolution spectroscopy led to estimates of the dynamical masses of the clusters. The clusters have ages ranging from 3.7 to ≈ 20 Myrs. Those in the ‘overlap region’ are very young (below 8 Myrs), while in the nothwestern loop ages are above that limit, and the nuclear starbursts are much older (∼ 100 Myrs). Some photometric cluster masses lie above 10⁶ M_⊙. The stellar velocity dispersions determined from the medium- to high resolution spectra yielded virial cluster masses again up to a few 10⁶ M_⊙. Large differences in the estimated photometric and virial masses suggest a variation of the IMF between the clusters. At least some of the clusters have masses, concentrations and IMFs that could allow them to evolve into globular clusters. This revised version was published online in September 2006 with corrections to the Cover Date.     

Resonant interaction between two planetary waves as a precursor for stratospheric warmings?

Stratospheric warmings are attributed to an enhanced planetary wave activity, occurring nearly each winter – at least in the northern hemisphere – with different strengths. The generation of stratospheric warmings is not totally understood. One of the most promising explanations is the interaction of planetary waves: in many cases, the amplitude of the quasi-stationary planetary wave 1 builds up, until it transmits its momentum and energy to the background wind field. The role of wave 2 is usually considered to be less important.Based on ERA-40 and DYANA temperature data (January–February 1990), we found evidence that a resonant wave–wave interaction between a travelling and a stationary wave 2 was responsible for a minor stratospheric warming in February 1990. The interaction being observed during four weeks can eventually be used as an indication for an upcoming stratospheric warming.     

Paleomagnetism of the Cu�CZn�CPb-bearing Kupferschiefer black shale (Upper Permian) at Sangerhausen, Germany

Syngenetic, diagenetic and epigenetic models have been proposed for the Cu?CZn?CPb Kupferschiefer mineralization at Sangerhausen, Germany. Paleomagnetic and rock magnetic measurements have been made on 205 specimens from mine workings on the margin of the Sangerhausen Syncline. The mineralization is richest in the ??0.5-m-thick Upper Permian (258?±?2?Ma) Kupferschiefer black marly shale (nine sites) and dies out over ??0.2?m in the underlying Weisliegend sandstones (three sites) and overlying Zechstein carbonates (two sites). Except for one site of fault zone gypsum, characteristic remanent magnetization directions were isolated for all 14 sites using alternating field and thermal step demagnetization. These directions provide a negative fold test, indicating that the remanence postdates Jurassic fault block tilting. Rock magnetic measurements show that the Kupferschiefer shale marks a redox front between the oxidized Weissliegend sandstones and non-oxidized Zechstein carbonates. The 14 site directions give a Late Jurassic paleopole at 149?±?3?Ma. It is significantly different from the paleopole reported by E.C. Jowett and others for primary or early diagenetic Rote F?ule alteration that gives an age of 254?±?6?Ma on the current apparent polar wander path and is associated with Kupferschiefer mineralization. We suggest that the Late Jurassic extensional tectonic event that formed the nearby North German Basin also reactivated Variscan basement faults and extended them up through the overlying strata, thereby allowing hydrothermal basement fluids to ascend and epigenetically mineralize the Kupferschiefer shale. The possibility of a 53?±?3?Ma mineralization age is also considered.     

Petroleum source rocks of the Tarfaya Basin and adjacent areas, Morocco

This work characterizes the source rock potential of the Tarfaya Basin and enabled us to reconstruct its geochemical history. Outcrop samples covering different stratigraphic intervals, plus the northwestern part of the Zag/Tindouf Basin (Bas Draa area), were analyzed for total organic carbon (C_org) and total inorganic carbon contents and total sulfur content. Rock-Eval analysis and vitrinite reflectance measurements were performed on 56 samples chosen on the basis C_org content. A set of 45 samples were extracted and non-aromatic hydrocarbons were analyzed by way of gas chromatography-flame ionization detection (GC-FID) and GC-mass spectrometry (GC-MS). Non-isothermal open system pyrolysis at different heating rates was applied to obtain kinetic parameters for modelling petroleum generation from four different source rocks.High quality petroleum source rocks with high C_org content and hydrogen index (HI) values were found for samples of Eocene, Coniacian, Turonian and Cenomanian age. Most samples were carbonate rich and organic/sulfur values were high to moderate. Various maturity parameters indicated immature or possibly early mature organic matter. Based on organic geochemical and petrological data, the organic matter is of marine/aquatic origin (Cenomanian) or a mixture of aquatic and terrigenous material (Eocene). The Early Cretaceous interval did not contain high quality source rocks, but indications of petroleum impregnation were found.     

Phyllosilicates synthesis: a way of accessing edges contributions in NMR and FTIR spectroscopies. Example of synthetic talc

A series of new-generation synthetic talcs were prepared by varying the hydrothermal synthesis duration from a few hours up to 2 months. Crystallinity and particle size analysis of the synthetic products were evaluated by photon correlation spectroscopy, transmission electron microscopy, differential thermal analysis and unoriented X-ray diffraction, and then analyzed by various spectroscopic methods such as Fourier transformed infrared spectroscopy and solid-state ¹H and ²⁹Si magic angle spinning nuclear magnetic resonance. The new process for preparing synthetic talcs allows to obtain single-phased particles which after few hours grow heterogeneously and simultaneously in both the c* direction and the (ab) plan. Fine particles, observed for whatever the synthesis duration, lead to the presence of numerous sheet edges surfaces due to particle size which represents the main difference with natural talc. Spectroscopy data show the influence of the fine particles on signals and highlight that synthetic talc characterization is a potential tool for better understanding crystal chemistry of natural talc.     

Structure of the Texas Orocline beneath the sedimentary cover (southeast Queensland,Australia)

The New England Orogen in eastern Australia is characterised by orogenic-scale curvatures (oroclines). The largest and most prominent curvature in this system is the Texas Orocline, but its subsurface geometry is still poorly constrained. A large component of the orocline is covered by post-oroclinal sedimentary rocks, which obscure deeper sections of the orocline and make it difficult to understand how the structure is connected to other segments of the New England Orogen. Here, we present geophysical data that elucidate the structure of the Texas Orocline below the sedimentary cover. Using 2D seismic, aeromagnetic TMI (total magnetic intensity) and Bouguer gravity datasets, in combination with outcrop and well data, we identified the depth to the New England ‘basement’ and significant faults intersecting it. We also traced the strongly contorted subsurface continuation of the Peel-Yarrol Fault System, which is characterised by local gravity and magnetic anomalies associated with isolated serpentinite outcrops. Constraints on the timing of oroclinal bending were obtained from the interpretation of seismic transects, which showed that early Permian sedimentary rocks of the Bowen Basin were deposited in a subtrough that deviates from the general north–south trend of the Bowen Basin. The subtrough is oriented approximately parallel to the western limb of the Texas Orocline, thus suggesting that the orocline formed during and/or after early Permian rifting. Our analysis indicates that initial bending occurred contemporaneously with the development of the early Permian rift basins, most likely in the backarc region of a retreating subduction zone. Subsequently, phases of strike-slip and contractional deformation have further tightened the pre-existing curvatures.