Long-core profiles of137Cs,134Cs,60Co and210Pb in sediment near the Rhône River (Northwestern Mediterranean Sea)

Various anthropogenic radionuclides and²¹⁰Pb were analyzed in a 4.3-m-long core, sampled near the Rhône River mouth in March 1991, to evaluate the extent of industrial releases that accumulate in this area. The whole core was significantly marked by radionuclide inputs from the nuclear facilities located along the river (¹³⁷Cs,¹³⁴Cs,⁶⁰Co). Irregular profiles in natural and artificial radionuclides should be related to variations in their respective inputs from the Rhône River to the Mediterranean Sea. Minimum concentrations were found during high flow periods. Using both the¹³⁷Cs/¹³⁴Cs profile in the core and the range of this ratio in Rhône waters, mean apparent accumulation rates were estimated to range between 37 cm yr^?1 and 48 cm yr^?1. This core would then represent a sedimentary record over a 7–10 year period. However, the presence of a signal from the Chernobyl accident, which occurred on April 26, 1986, was not clearly observed in the core. Inventories of both artificial and natural radionuclides were greater than expected from atmospheric inputs. The increased sedimentation occurring in close vicinity to the mouth of the Rhône River is thus responsible for trapping of elements transported by the river to the Mediterranean Sea. In this area, inventories of artificial radionuclides are well in excess of aerial deposition from Chernobyl and atmospheric weapons tests and are linked primarily to industrial releases.     

A Fully Depleted pn-Junction CCD for Infrared-, UV- and X- ray detection

This paper describes the performance of the Fully Depleted pn-junction CCD (pn-CCD) system, developed for ESA's XMM-satellite mission for soft x-ray imaging and spectroscopy in the single photon counting mode in the 100 eV to 10 keV photon range. The 58 mm x 60 mm large pn-CCD array, designed and fabricated at the Semiconductor Lab (Halbleiterlabor) of the Max-Planck-Institut, uses pn-junctions for registers and as backside structure. This concept naturally enables full depletion of the detector volume independent of the silicon wafer's resistivity and thickness, and as such make it an efficient detector for the x-ray region and the infrared. For high detection efficiency in the soft x-ray region and UV, an ultrathin pn-CCD backside deadlayer has been realized. Each pn-CCD-channel is equipped with its own on-chip JFET amplifier which, in combination with the CAMEX-amplifier and multiplexing chip, facilitates parallel readout and fast data rate: the cooled pn-CCD system can be read out at a data rate up to 3 MHz with an electronic noise floor of ENC < 5 e-.     

Feminism and the new multi-scaling in employment policy

In the last decades, employment policy design and implementation partly shifted from the national to local and regional scales in most European countries. In addition, the European Union appeared as an important new actor in this policy field in the late 1990s. We argue that the new geographical multi-scaling of employment policy can be used strategically by feminists to promote different aspects of gender equality simultaneously: Feminist claims related to gender equity, i.e., demands to secure equal participation of women and men in the labour market, should be advocated at the national scale. Claims related to the recognition of gender difference, i.e., demands related to typical female and male employment needs and their social recognition should be promoted at the local scale. The regional scale is the most appropriate one to advance gender plurality, i.e., non-traditional employment of women and men. In the empirical part of the paper we discuss how the ideal leverage of claims at different spatial scales and inter-linkage between scales could operate. We will show that the link to EU policy strengthens feminist claims in the highly gender-differentiated societies and political settings of Austria and Germany. This revised version was published online in July 2006 with corrections to the Cover Date.     

Modeling the Lyα radiation of high-redshift galaxies

The Lyα line emission of high-redshift galaxies depends on the density and temperature distribution of the gas, the kinematics and the dust content. We use a finite element method to model theLyα radiation of different 3D configurations considering complete frequency redistribution and the influence of velocity fields. Our results show that the central absorption feature of the double-peaked Lyα line profile observed in many radio galaxies with z=2-4 is probably the consequence of frequency redistribution rather than foreground absorption. The blue peak of the profile is enhanced for models with in fall motion and the red peak for models with outflow motion. In particular, we attempt to model the extendedLyα emission of high-redshift radio galaxies, where we consider results of corresponding hydrodynamical simulations to select possible model configurations. We find that Lyα photons scattered outside a jet-influenced low-density region are able to produce an extended Lyα halo. This revised version was published online in August 2006 with corrections to the Cover Date.     

50-year record and solid state speciation of mercury in natural and contaminated reservoir sediment

Contaminated fluvial sediments represent both temporary sinks for river-borne pollutants and potential sources in case of natural and/or anthropogenic resuspension. Reservoir lakes play a very important role in sediment dynamics of watersheds and may offer great opportunities to study historical records of river-borne particles and associated elements transported in the past. The fate and potential environmental impact of Hg depends on its abundance, its carrier phases and its chemical speciation. Historical Hg records and solid state Hg speciation were compared in sediments from two contrasting reservoirs of the Lot River (France) upstream and downstream from a major polymetallic pollution (e.g. Cd, Zn) source. Natural (geochemical background) and anthropogenic Hg concentrations and their relationships with predominant carrier phases were determined. The results reveal important historical Hg contamination (up to 35 mg kg⁻¹) of the downstream sediment, reflecting the historical evolution of industrial activity at the point source, i.e. former coal mining, Zn ore treatment and post-industrial remediation work. Single chemical extractions (ascorbate, H₂O₂, KOH) suggest that at both sites most (∼75%) of the Hg is bound to organic and/or reactive sulphide phases. Organo-chelated (KOH-extracted) Hg, representing an important fraction in the uncontaminated sediment, shows similar concentrations (∼0.02 mg kg⁻¹) at both sites and may be mainly attributed to natural inputs and/or processes. Although, total Hg concentrations in recent surface sediments at both sites are still very different, similar mono-methylmercury concentrations (up to 4 μg kg⁻¹) and vertical distributions were observed, suggesting comparable methylation-demethylation processes. High mono-methylmercury concentrations (4–15 μg kg⁻¹) in 10–40 a-old, sulphide-rich, contaminated sediment suggest long-term persistence of mono-methylmercury. Beyond historical records of total concentrations, the studied reservoir sediments provided new insights in solid state speciation and carrier phases of natural and anthropogenic Hg. In case of sediment resuspension, the major part of the Hg historically stored in the Lot River sediments will be accessible to biogeochemical recycling in the downstream fluvial-estuarine environment.     

Modeling Hysteresis in Porous Media Flow via Relaxation

Two-phase flow in a porous medium can be modeled, using Darcy's law, in terms of the relative permeability functions of the two fluids (say, oil and water). The relative permeabilities generally depend not only on the fluid saturations but also on the direction in which the saturations are changing. During water injection, for example, the relative oil permeability k _ro falls gradually until a threshold is reached, at which stage the k _ro begins to decrease sharply. The latter stage is termed imbibition. If oil is subsequently injected, then k _ro does not recover along the imbibition path, but rather increases only gradually until another threshold is reached, whereupon it rises sharply. This second stage is called drainage, and the type of flow that occurs between the imbibition and drainage stages is called scanning flow. Changes in permeability during scanning flow are approximately reversible, whereas changes during drainage and imbibition are irreversible. Thus there is hysteresis, or memory, exhibited by the two-phase flow in the porous medium. In this work, we describe two models of permeability hysteresis. Common to both models is that the scanning flow regime is modeled with a family of curves along which the flow is reversible. In the Scanning Hysteresis Model (SHM), the scanning curves are bounded by two curves, the drainage and imbibition curves, where the flow can only occur in a specific direction. The SHM is a heuristic model consistent with experiments, but it does not have a nice mathematical specification. For instance, the algorithm for constructing solutions of Riemann problems involves several ad hoc assumptions. The Scanning Hysteresis Model with Relaxation (SHMR) augments the SHM by (a) allowing the scanning flow to extend beyond the drainage and imbibition curves and (b) treating these two curves merely as attractors of states outside the scanning region. The attraction, or relaxation, occurs on a time scale that corresponds to the redistribution of phases within the pores of the medium driven by capillary forces. By means of a formal Chapman–Enskog expansion, we show that the SHM with additional viscosity arises from the SHMR in the limit of vanishing relaxation time, provided that the diffusion associated with capillarity exceeds that induced by relaxation. Moreover, through a rigorous study of traveling waves in the SHMR, we show that the shock waves used to solve Riemann problems in the SHM are precisely those that have diffusive profiles. Thus the analysis of the SHMR justifies the SHM model. Simulations based on a simple numerical method for the simulation of flow with hysteresis confirm our analysis.     

Revised equipartition and minimum energy formula for magnetic field strength estimates from radio synchrotron observations

The commonly used classical equipartition or minimum‐energy estimate of total magnetic fields strengths from radio synchrotron intensities is of limited practical use because it is based on the hardly known ratio K of the total energies of cosmic ray protons and electrons and also has inherent problems. We present a revised formula, using the number density ratio K for which we give estimates. For particle acceleration in strong shocks K is about 40 and increases with decreasing shock strength. Our revised estimate for the field strength gives larger values than the classical estimate for flat radio spectra with spectral indices of about 0.5–0.6, but smaller values for steep spectra and total fields stronger than about 10 µG. In very young supernova remnants, for example, the classical estimate may be too large by up to 10×. On the other hand, if energy losses of cosmic ray electrons are important, K increases with particle energy and the equipartition field may be underestimated significantly. Our revised larger equipartition estimates in galaxy clusters and radio lobes are consistent with independent estimates from Faraday rotation measures, while estimates from the ratio between radio synchrotron and X‐ray inverse Compton intensities generally give much weaker fields. This may be explained e.g. by a concentration of the field in filaments. Our revised field strengths may also lead to major revisions of electron lifetimes in jets and radio lobes estimated from the synchrotron break frequency in the radio spectrum. (© 2005 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)     

Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Analysis of the Slab Ocean El Nino atmospheric feedbacks in observed and simulated ENSO dynamics

In a recent study it was illustrated that the El Nino Southern Oscillation (ENSO) mode can exist in the absence of any ocean dynamics. This oscillating mode exists just due to the interaction between atmospheric heat fluxes and ocean heat capacity. The primary purpose of this study is to further explore these atmospheric Slab Ocean ENSO dynamics and therefore the role of positive atmospheric feedbacks in model simulations and observations. The positive solar radiation feedback to sea surface temperature (SST), due to reduced cloud cover for anomalous warm SSTs, is the main positive feedback in the Slab Ocean El Nino dynamics. The strength of this positive cloud feedback is strongly related to the strength of the equatorial cold tongue. The combination of positive latent and sensible heat fluxes to the west and negative ones to the east of positive anomalies leads to the westward propagation of the SST anomalies, which allows for oscillating behavior with a preferred period of 6–7 years. Several indications are found that parts of these dynamics are indeed observed and simulated in other atmospheric or coupled general circulation models (AGCMs or CGCMs). The CMIP3 AGCM-slab ensemble of 13 different AGCM simulations shows unstable ocean–atmosphere interactions along the equatorial Pacific related to stronger cold tongues. In observations and in the CMIP3 and CMIP5 CGCM model ensemble the strength and sign of the cloud feedback is a function of the strength of the cold tongue. In summary, this indicates that the Slab Ocean El Nino dynamics are indeed a characteristic of the equatorial Pacific climate that is only dominant or significantly contributing to the ENSO dynamics if the SST cold tongue is sufficiently strong. In the observations this is only the case during strong La Nina conditions. The presence of the Slab Ocean ENSO atmospheric feedbacks in observations and CGCM model simulations implies that the family of physical ENSO modes does have another member, which is entirely driven by atmospheric processes and does not need to have the same spatial pattern nor the same time scales as the main ENSO dynamics.