The Central Andean gravity high, a relic of an old subduction complex?

The Central Andean gravity high (CAGH) is a positive anomaly in isostatic residual gravity with its center located at the western flank of the Central Andes at about 24°S. The gravity was analyzed by various methods to draw quantitative conclusions about the sources of this anomaly and their process of formation. Methods include the analysis of the gravity gradients, power spectrum, wavelength filters, and Euler deconvolution.Numerical investigations of gravity field in the area of the CAGH indicate the presence of a dense body of nearly 400 km length and about 100–140 km width, that masses lie at varying depths between 10 and 38 km. A correlation between the location of the residual anomalies and the topographic lows in the area between the Salars de Atacama and Pipanaco is observed, which indicates the strong influence of the anomalous-causing rocks of the CAGH within the formation process of the Andean orogen. An influence of these causing bodies of rock on the trend of Holocene volcanic arc is likely. Genesis of the anomalous dense formations of rock could be traced back to Ordovician–Silurian time when a pre-Andean subduction zone is postulated in the region of northern Chile with its corresponding volcanic arc in the region of the CAGH.

Zusammenfassung

El campo de gravedad alto de los Andes Centrales (CAGH) consiste en una pronunciada anomalía positiva de la gravedad isostática, cuyo centro se encuentra en el borde oeste de los Andes Centrales a los 24°S. En este estudio se analizó el campo de gravedad mediante distintos métodos, de manera de poder establecer conclusiones cuantitativas sobre el causante de esta anomalía y el proceso de formación de este causante.La investigación numérica de las anomalías gravimétricas del CAGH indica la presencia de un cuerpo de alta densidad con aproximadamente 400 km de largo y 100–140 km de ancho, que se encuentra a profundidades variables entre 10 y 38 km. Se observa una correlación entre la posición de la anomalía residual y los bajos topográficos en los areas de Salares de Atacama, Arizaro, Antofalla y Pipanaco, la cual indica una fuerte influencia de rocas productoras de la anomalía en el CAGH, dentro del proceso de formación del orógeno andino. Es probable que estos cuerpos de rocas causantes de la anomalía tengan incluso influencia en el alineamiento del arco volcánico holocénico. La generación de cuerpos de rocas con una densidad anómala puede remontarse al Ordovícico–Silúrico, tiempo para el que postula una subducción pre-Andina en la región del norte de Chile y que corresponde con el arco volcánico en la región del CAGH.     

Restoration of submerged vegetation in shallow eutrophic lakes – A guideline and state of the art in Germany

One of the most serious problems caused by eutrophication of shallow lakes is the disappearance of submerged macrophytes and the switch to a turbid, phytoplankton-dominated state. The reduction of external nutrient loads often does not result in a change back to the macrophyte-dominated state because stabilising mechanisms that cause resilience may delay a response. Additional internal lake restoration measures may therefore be needed to decrease the concentration of total phosphorus and increase water clarity. The re-establishment of submerged macrophytes required for a long-term stability of clear water conditions, however, may still fail, or mass developments of tall-growing species may cause nuisance for recreational use. Both cases are often not taken into account when restoration measures are planned in Germany, and existing schemes to reduce eutrophication consider the topic inadequately. Here we develop a step-by-step guideline to assess the chances of submerged macrophyte re-establishment in shallow lakes. We reviewed and rated the existing literature and case studies with special regard on (1) the impact of different internal lake restoration methods on the development of submerged macrophytes, (2) methods for the assessment of natural re-establishment, (3) requirements and methods for artificial support of submerged macrophyte development and (4) management options of macrophyte species diversity and abundance in Germany. This guideline is intended to help lake managers aiming to restore shallow lakes in Germany to critically asses and predict the potential development of submerged vegetation, taking into account the complex factors and interrelations that determine their occurrence, abundance and diversity.     

A disturbed molecular disc in the Circinus galaxy

We have used the Swedish ESO Submillimeter Telescope to observe the molecular gas in the Circinus galaxy using the CO(1 → 0) transition as a tracer. The central region and major axis have been mapped and several other points were also observed. The gas in the galaxy is concentrated towards the nucleus, the peak being coincident with the radio/optical core. The inclination of the molecular galactic disc is more comparable to that of the radio continuum than to that of the large-scale H  i emission. Evidence for an anomalous spur structure pointing radially away from the galactic centre is presented, and may indicate a causal link between it and similar features seen in optical lines and radio continuum. Our data suggest the presence of a central molecular ring or disc with radius 300 ± 50 pc and a rotation velocity of about 200 km s⁻¹ (assuming i  = 73°). The dynamical mass of the nucleus is estimated to be no greater than 3.9 × 10⁹ M_⊙. Assuming that the distribution of gas varies smoothly in the outer regions, we calculate the mass of molecular gas in the galaxy to be at least M _mol = 1.1 × 10⁹ M_⊙, and the star-forming efficiency to be 11 ± 2 L_⊙ M_⊙⁻¹. These results imply that Circinus is undergoing a massive central starburst which may be, at least partially, responsible for its extended minor axis emission seen in several wavebands.     

Seismic gaps and plate tectonics: Seismic potential for major boundaries

The theory of plate tectonics provides a basic framework for evaluating the potential for future great earthquakes to occur along major plate boundaries. Along most of the transform and convergent plate boundaries considered in this paper, the majority of seismic slip occurs during large earthquakes, i.e., those of magnitude 7 or greater. The concepts that rupture zones, as delineated by aftershocks, tend to abut rather than overlap, and large events occur in regions with histories of both long- and short-term seismic quiescence are used in this paper to delineate major seismic gaps.In detail, however, the distribution of large shallow earthquakes along convergent plate margins is not always consistent with a simple model derived from plate tectonics. Certain plate boundaries, for example, appear in the long term to be nearly aseismic with respect to large earthquakes. The identification of specific tectonic regimes, as defined by dip of the inclined seismic zone, the presence or absence of aseismic ridges and seamounts on the downgoing lithospheric plate, the age contrast between the overthrust and underthrust plates, and the presence or absence of back-arc spreading, have led to a refinement in the application of plate tectonic theory to the evaluation of seismic potential.The term seismic gap is taken to refer to any region along an active plate boundary that has not experienced a large thrust or strike-slip earthquake for more than 30 years. A region of high seismic potential is a seismic gap that, for historic or tectonic reasons, is considered likely to produce a large shock during the next few decades. The seismic gap technique provides estimates of the location, size of future events and origin time to within a few tens of years at best.The accompanying map summarizes six categories of seismic potential for major plate boundaries in and around the margins of the Pacific Ocean and the Caribbean, South Sandwich and Sunda (Indonesia) regions for the next few decades. These categories range from what we consider high to low potential for being the site of large earthquakes during that period of time. Categories 1, 2 and 6 define a time-dependent potential based on the amount of time elapsed since the last large earthquake. The remaining categories, 3, 4, and 5, are used for areas that have ambiguous histories for large earthquakes; their seismic potential is inferred from various tectonic criteria. These six categories are meant to be interpreted as forecasts of the location and size of future large shocks and should not be considered to be predictions in which a precise estimate of the time of occurrence is specified.Several of the segments of major plate boundaries that are assigned the highest potential, i.e., category 1, are located along continental margins, adjacent to centers of population. Some of them are hundreds of kilometers long. High priority should be given to instrumenting and studying several of these major seismic gaps since many are now poorly instrumented. The categories of potential assigned here provide a rationale for assigning prorities for instrumentation, for future studies aimed at predicting large earthquakes and for making estimates of tsunami potential.Lamont-Doherty Geological Observatory Contribution No. 2906.     

Nitratbestimmung im Trinkwasser nach dem flow-stream-Prinzip mittels einer ionensensitiven Meßzelle

Beschrieben wird eine automatisierte Methode zur Bestimmung des Nitrats in Trinkwässern mittels einer ionensensitiven Meßzelle. Mit dem vorgestellten Verfahren können 80 Proben pro Stunde auf ihren Nitratgehalt im Konzentrationsbereich von 1,5 · 10^–5 bis 1,0 · 10^–3 Mol/l analysiert werden. Der Aufbau der Automateneinheit, der Durchflußmeßzelle, sowie das Meßprinzip weiden erläutert.     

Options to overcome the barriers to pricing European agricultural emissions

Although agriculture could contribute substantially to European emission reductions, its mitigation potential lies untapped and dormant. Market-based instruments could be pivotal in incentivizing cost-effective abatement. However, sector specificities in transaction costs, leakage risks and distributional impacts impede its implementation. The significance of such barriers critically hinges on the dimensions of policy design. This article synthesizes the work on emissions pricing in agriculture together with the literature on the design of market-based instruments. To structure the discussion, an options space is suggested to map policy options, focusing on three key dimensions of policy design. More specifically, it examines the role of policy coverage, instruments and transfers to farmers in overcoming the barriers. First, the results show that a significant proportion of agricultural emissions and mitigation potential could be covered by a policy targeting large farms and few emission sources, thereby reducing transaction costs. Second, whether an instrument is voluntary or mandatory influences distributional outcomes and leakage. Voluntary instruments can mitigate distributional concerns and leakage risks but can lead to subsidy lock-in and carbon price distortion. Third, the impact on transfers resulting from the interaction of the Common Agricultural Policy (CAP) with emissions pricing will play a key role in shaping political feasibility and has so far been underappreciated.

POLICY RELEVANCE

Following the 2015 Paris Agreement, European climate policy is at a crossroads. Achieving cost-effectively the 2030 and 2050 European targets requires all sectors to reduce their emissions. Yet, the cornerstone of European climate policy, the European Union Emissions Trading System (EU ETS), covers only about half of European emissions. Major sectors have been so far largely exempted from carbon pricing, in particular transport and agriculture. While transport has been increasingly under the spotlight as a possible candidate for an EU ETS sectoral expansion, policy discussions on pricing agricultural emissions have been virtually absent. This article attempts to fill this gap by investigating options for market-based instruments to reduce agricultural emissions while taking barriers to implementation into account.     

Origin of nickel in water solution of the chalk aquifer in the north of France and influence of geochemical factors

In the north of France, high registers of nickel are sometimes recorded within the chalk aquifer. In a confined context, the presence of pyrite in the covering clays or in the marcasite nodules encrusted in the clay may constitute a natural source of trace metals. With an objective of sanitary control, the limits of chemical contents regulating the quality of water destined for human consumption have been lowered by the European Framework Directive in the field of water policy (2000/60/EC). As a result, nickel limits have been reduced from 50 to 20 μg/l. The analyses, carried out on three water catchment fields in our area of study, were centred on variable parameters (Eh, O₂(d), pH, Conductivity, T°), major elements (SO₄, NO₃) and metals (Fe, Ni, Mn, Co). The acquired data enabled us to identify from one hand, the conditions which are presented within the site, special thanks to the evolution of nitrate and iron contents and on the other hand, the natural origin (geological) of nickel for two of the three sites studied based essentially on the evaluation of the Nickel/Cobalt ratio. Thus, on the first site, the evolution of nickel content and nitrate content showed the influence of the phenomenon of denitrification on the re-mobilisation of the nickel. Whereas on the second site, a high variation of total iron content and oxygen dissolved in solution highlighted a particular phenomenon of oxidation of the pyrite through molecular oxygen. Finally, the correlation with the sulphates clearly showed behaviour of the nickel, once released, that was entirely dependent on the phenomenon of adsorption on the iron and manganese hydroxides.     

Preliminary Interlaboratory Trial for ISO/DIS 12010: Determination of Short Chain Polychlorinated Alkanes (SCCP) in Water

A first preliminary interlaboratory trial was planned to prepare ISO/DIS 12010: Water quality – determination of short chain polychlorinated alkanes (SCCP) in water – method using GC/MS and electron capture negative ionisation (ECNI). The task was to determine the sum of short chain polychlorinated n‐alkanes with carbon chain lengths of C₁₀–C₁₃ and a chlorine content between 49 and 67% in water by GC‐ECNI‐MS and quantification by multiple linear regression described in ISO/DIS 12010 as the compulsory method. Distributed samples were obtained from a real water extract spiked with a target concentration of 0.4 µg/mL sum of SCCP, i.e. the environmental quality target level according to the Water Framework Directive. The interlaboratory trial included the calibration, a column chromatographic clean up, a concentration step and an integration of chromatographic unresolved humps as well as the quantification with multiple linear regression. Reproducibility standard deviations between 21.5 and 22.9% were achieved by 17 participating laboratories from four countries. The method outlined no significant difference of the results between the standard solution and a real water matrix extract. On the basis of this succeeded preliminary interlaboratory trial the final interlaboratory trial for validation of ISO 12010 was prepared in autumn 2010.     

On forecasting abnormal climatic events in the tropical Atlantic Ocean

Modelling and observational evidence indicate that interannual variabilities of dynamic height and sea surface temperature (SST) in the eastern part of the tropical Atlantic Ocean (Gulf of Guinea) are largely induced by preceding fluctuations in wind stress, mainly in the western equatorial basin. A wind-driven linear ocean model is used here to test the possibility of forecasting the abnormal dynamic heights. A control run of the model, forced by 1964–1993 wind stress monthly means, is first conducted. Yearly test runs (1964-1994) are subsequently performed from January to August by forcing the model with observed winds from January to May, and then by forcing with the May wind assumed to persist from June to August. During the last three decades the largest deviations of dynamic height simulated by the control run in the Gulf of Guinea in boreal summer would have been correctly forecast from wind data related only to conditions in May of each year. However, for weak climatic anomalies, the model may forecast overestimated values. For the most part (about 20 times during the last 30 years), the sign of the observed SST anomaly in the centre of the Gulf of Guinea during the boreal summer is identical to the sign of simulated anomalies of dynamic height deduced from both control and test runs. Along the eastern equatorial waveguide, the sea level forecasting skill slowly decreases from the first 2 weeks of June until the second 2 weeks of August, but remains high on both sides of the equator throughout boreal summer, as is expected from the adjustment in a linear ocean model. It is established that throughout the year in the Gulf of Guinea the accuracy of the 1-month forecast dynamic height anomaly provided by the simple linear method is greater than that of the 1-month forecast assuming persistence.