Fluvial transport of suspended sediment and organic carbon during flood events in a large agricultural catchment in southwest France

Water draining from a large agricultural catchment of 1 110 km² in southwest France was sampled over an 18‐month period to determine the temporal variability in suspended sediment (SS) and dissolved (DOC) and particulate organic carbon (POC) transport during flood events, with quantification of fluxes and controlling factors, and to analyze the relationships between discharge and SS, DOC and POC. A total of 15 flood events were analyzed, providing extensive data on SS, POC and DOC during floods. There was high variability in SS, POC and DOC transport during different seasonal floods, with SS varying by event from 513 to 41 750 t; POC from 12 to 748 t and DOC from 9 to 218 t. Overall, 76 and 62% of total fluxes of POC and DOC occurred within 22% of the study period. POC and DOC export from the Save catchment amounted to 3090 t and 1240 t, equivalent to 1·8 t km^?2 y^?1 and 0·7 t km^?2 y^?1, respectively. Statistical analyses showed that total precipitation, flood discharge and total water yield were the major factors controlling SS, POC and DOC transport from the catchment. The relationships between SS, POC and DOC and discharge over temporal flood events resulted in different hysteresis patterns, which were used to deduce dissolved and particulate origins. In both clockwise and anticlockwise hysteresis, POC mainly followed the same patterns as discharge and SS. The DOC‐discharge relationship was mainly characterized by alternating clockwise and anticlockwise hysteresis due to dilution effects of water originating from different sources in the whole catchment. Copyright © 2011 John Wiley & Sons, Ltd.     

Insights into cation exchange selectivity of a natural clinoptilolite by means of dielectric relaxation spectroscopy

Purified natural clinoptilolite from the Tasajeras deposit, Cuba, and some of its metal exchanged forms are studied, at the dehydrated state, by means of dielectric relaxation spectroscopy (DRS) using two different modus operandi: complex impedance spectroscopy and dielectric dynamic thermal analysis. Data analysis yields the determination of the extra-framework cation (EFC) population into the various possible crystallographic sites of the zeolitic framework as well as of the activation energy characterizing the localized hopping mechanism of EFC. First, it is shown that the DRS responses obtained here match well with the previous reported data, which were previously localized EFCs in positions close to M1 and M2 sites when the clinoptilolite is modified to almost homoionic form. From this outcome, it can be concluded that all EFCs are in the same crystallographic situation regarding solvation or, in other terms, that no steric effect can be taken into account to explain cationic selectivity. Second, based on the assumption that the activation energy for EFC hopping is directly connected to the EFC/framework interaction and on simple thermodynamics consideration, we show this interaction does not govern the EFC exchange reaction. So, it is emphasized that EFC/H₂O interaction is the key factor for cation exchange selectivity.     

An improved methodology to measure flag performance for the shipping industry

The subject of measuring the performance of registries has been a topic of policy discussions in recent years at the regional level due to the recasting of the European Union (EU) port state control (PSC) directive which introduces incentives for flags which perform better. Since the current method used in the EU region entails some shortcomings, it has therefore been the subject of substantial scrutiny. Furthermore, the International Maritime Organization (IMO) developed a set of performance indicators which however lacks the ability to measure compliance as set out in one of its strategic directions towards fostering global compliance. This article develops a methodology to measure flag state performance which can be applied on the regional or global level and to other areas of legislative interest (e.g. recognized organizations, Document of Compliance Companies). The proposed methodology overcomes some of the shortcomings of the present method and presents a more refined, less biased approach of measuring performance. To demonstrate its usefulness, it is applied to a sample of 207,821 observations for a 3-year time frame and compared to the current method.     

Characterization of microstructural and physical properties changes in biocemented sand using 3D X-ray microtomography

An experimental study has been performed to investigate the effect of the biocalcification process on the microstructural and the physical properties of biocemented Fontainebleau sand samples. The microstructural properties (porosity, volume fraction of calcite, total specific surface area, specific surface area of calcite, etc.) and the physical properties (permeability, effective diffusion) of the biocemented samples were computed for the first time from 3D images with a high-resolution images obtained by X-ray synchrotron microtomography. The evolution of all these properties with respect to the volume fraction of calcite is analysed and compared with success to experimental data, when it is possible. In general, our results point out that all the properties are strongly affected by the biocalcification process. Finally, all these numerical results from 3D images and experimental data were compared to numerical values or analytical estimates computed on idealized microstructures constituted of periodic overlapping and random non-overlapping arrangements of coated spheres. These comparisons show that these simple microstructures are sufficient to capture and to predict the main evolution of both microstructural and physical properties of biocemented sands for the whole range of volume fraction of calcite investigated.     

Bioturbation, short-lived radioisotopes, and the tracer-dependence of biodiffusion coefficients

Bioturbation refers to the mixing of sediment particles resulting from benthic faunal activity. It is the dominant particle mixing process in most marine sediments and exerts an important control on diagenetic processes. In models, bioturbation is usually treated as a diffusive process where the biodiffusion coefficient (D_b) characterizes the biological mixing intensity. Biodiffusion coefficients are classically computed by fitting a diffusive model to vertical profiles of particle-bound radioisotopes. One peculiar observation is tracer-dependence: D_b values from short-lived tracers tend to be larger than those obtained from long-lived tracers from the same site. Recent theoretical work, based on random walk theory and Lattice Automaton Bioturbation Simulations (LABS), has suggested that this tracer-dependence is simply a model artifact and has concluded that the biodiffusion model is not applicable to the short observational time scales associated with short-lived radioisotopes. Here we have compiled a global dataset of D_b values obtained from different radiotracers to assess tracer-dependence from a data perspective. Tracer-dependence is significant in low-mixing environments like slope and deep-sea sediments, but is not present in intensely mixed coastal areas. Tracer-dependence is absent when the number of mixing events is larger than 20, or the potential length scale is greater than 0.5 cm. Roughly this comes down to tracer-derived D_b values greater than 2 cm² yr⁻¹. This condition is met for 68%, 50%, and 8% of published D_b values obtained from coastal, continental slope, and abyssal environments, respectively. These results show that short-lived radioisotopes are suitable to quantify biodiffusion mixing in sedimentary environments featuring intense bioturbation.     

Polychaetes from Jan Mayen (Annelida, Polychaeta)

A thorough literature review has been undertaken to establish the first complete account of polychaetes recorded from the area around the volcanic island of Jan Mayen. The annotated checklist lists 121 species-level taxa, representing an increase from the 75 species previously recorded. The checklist is based on existing records, supplemented with material sampled in 1999, from which 42 species new to the area were reported. Some previously reported species from the area have been excluded because of inadequate documentation. The polychaete fauna of Jan Mayen is comparable with that of the mainland Norwegian coast and the Svalbard area. No taxa unique to the island were found. However, knowledge of the marine invertebrate fauna in general at Jan Mayen is sparse because few surveys have been undertaken there. It is expected that future expeditions will reveal further new taxon records for the area.     

Distribution of heavy metals in marine bivalves, fish and coastal sediments in the Gulf and Gulf of Oman

An assessment of marine contamination due to heavy metals was made in the Gulf and Gulf of Oman based on marine biota (fish and various bivalves) and coastal sediment collected in Bahrain, Oman, Qatar, and the United Arab Emirates (UAE) during 2000-2001. Sediment metal loadings were generally not remarkable, although hot spots were noted in Bahrain (Cu, Hg, Pb, Zn) and on the east coast of the UAE (As, Co, Cr, Ni). Concentrations of As and Hg were typically low in sediments and the total Hg levels in top predator fish commonly consumed in the region were < 0.5 microg g(-1) and posed no threat to public health. Very high Cd concentrations (up to 195 microg g(-1)) in the liver of some fish from southern Oman may result from food-chain bioaccumulation of elevated Cd levels brought into the productive surface waters by upwelling in the region. Very high As concentrations (up to 156 microg g(-1)) were measured in certain bivalve species from the region. Although not certain, the As is probably derived from natural origins rather than anthropogenic contamination.     

Analysis of the Slab Ocean El Nino atmospheric feedbacks in observed and simulated ENSO dynamics

In a recent study it was illustrated that the El Nino Southern Oscillation (ENSO) mode can exist in the absence of any ocean dynamics. This oscillating mode exists just due to the interaction between atmospheric heat fluxes and ocean heat capacity. The primary purpose of this study is to further explore these atmospheric Slab Ocean ENSO dynamics and therefore the role of positive atmospheric feedbacks in model simulations and observations. The positive solar radiation feedback to sea surface temperature (SST), due to reduced cloud cover for anomalous warm SSTs, is the main positive feedback in the Slab Ocean El Nino dynamics. The strength of this positive cloud feedback is strongly related to the strength of the equatorial cold tongue. The combination of positive latent and sensible heat fluxes to the west and negative ones to the east of positive anomalies leads to the westward propagation of the SST anomalies, which allows for oscillating behavior with a preferred period of 6–7 years. Several indications are found that parts of these dynamics are indeed observed and simulated in other atmospheric or coupled general circulation models (AGCMs or CGCMs). The CMIP3 AGCM-slab ensemble of 13 different AGCM simulations shows unstable ocean–atmosphere interactions along the equatorial Pacific related to stronger cold tongues. In observations and in the CMIP3 and CMIP5 CGCM model ensemble the strength and sign of the cloud feedback is a function of the strength of the cold tongue. In summary, this indicates that the Slab Ocean El Nino dynamics are indeed a characteristic of the equatorial Pacific climate that is only dominant or significantly contributing to the ENSO dynamics if the SST cold tongue is sufficiently strong. In the observations this is only the case during strong La Nina conditions. The presence of the Slab Ocean ENSO atmospheric feedbacks in observations and CGCM model simulations implies that the family of physical ENSO modes does have another member, which is entirely driven by atmospheric processes and does not need to have the same spatial pattern nor the same time scales as the main ENSO dynamics.     

Ecological stability during the LGM and the mid-Holocene in the Alpine Steppes of Tibet?

Arid and Alpine ecosystems are known for extreme environmental changes during the Late Quaternary. We hypothesize that the world's largest Alpine arid ecosystem however, the Alpine Steppes of the Tibetan highlands, remained ecologically stable during the LGM and the mid-Holocene. This hypothesis is tested by distributional range of plant species, plant life forms and rate of endemism. The set of character species has a precipitation gradient between 50 and 350 mm/a, testifying for resilience to precipitation changes. 83% of the species have a wider vertical range than 1000 m used as a proxy for resilience to temperature changes. 30% of the species are endemic with 10 endemic genera, including plate-shaped cushions as a unique plant life form. These findings are in line with palaeo-ecological proxies (δ¹⁸O, pollen) allowing the assumption that Alpine Steppes persisted during the LGM with 3 to 4 K lower summer temperatures.During the mid-Holocene, forests could have replaced Alpine Steppes in the upper catchments of the Huang He, Yangtze, Mekong, Salween and Yarlung Zhangbo, but not in the interior basins of the north-western highlands, because the basins were then flooded, suppressing forests and supporting the environmental stability of this arid Alpine grassland biome.     

Improving benthic monitoring by combining trawl and grab surveys

Environmental monitoring is performed on seafloor communities since these organisms are relatively stationary and integrate the environmental conditions over many years. Standard practices involve sampling by grab. Epifaunal taxa, often missed by grab sampling, are likely to have different ecological functions. We investigate how current environmental assessments represent the benthic community as a whole by comparing taxonomic and functional components sampled by grabs and epibenthic trawls. Faunal communities sampled by trawl (filtrating or predator, epifauna) and grab (infaunal, detrivore) differs widely by sampling distinct functional components, and these may be expected to respond to different human-induced stressors. Neither component appears to be a good surrogate for the community as a whole. We suggest a benthic monitoring by combining both techniques. Sustainable ecosystem functioning is intimately tied to the health of both components of the benthic community, and is recognized as an important goal by signatories of the Convention on Biological Diversity.