Effect of Pumice and Sand on the Sustainability of Granular Iron Beds for the Aqueous Removal of CuII,NiII, and ZnII

Current knowledge of the basic principles underlying the design of Fe⁰ beds is weak. The volumetric expansive nature of iron corrosion was identified as the major factor determining the sustainability of Fe⁰ beds. This work attempts to systematically verify developed concepts. Pumice and sand were admixed to 200 g of Fe⁰ in column studies (50:50 volumetric proportion). Reference systems containing 100% of each material have been also investigated. The mean grain size of the used materials (in mm) were 0.28 (sand), 0.30 (pumice), and 0.50 (Fe⁰). The five studied systems were characterized (i) by the time dependent evolution of their hydraulic conductivity (permeability) and (ii) for their efficiency for aqueous removal of Cu^II, Ni^II, and Zn^II (about 0.3 mM of each). Results showed unequivocally that (i) quantitative contaminant removal was coupled to the presence of Fe⁰, (ii) additive admixture lengthened the service life of Fe⁰ beds, and (iii) pumice was the best admixing agent for sustaining permeability while the Fe⁰/sand column was the most efficient for contaminant removal. The evolution of the permeability was well‐fitted by the approach that the inflowing solution contained dissolved O₂. The achieved results are regarded as starting point for a systematic research to optimize/support Fe⁰ filter design.     

SARAL/AltiKa Global Statistical Assessment and Cross-Calibration with Jason-2

The CNES/ISRO mission SARAL/AltiKa was successfully launched on 25 February 2013. It reached its nominal orbit on 13 March 2013. AltiKa is the first altimeter using the Ka-band frequency. This article presents the results of the calibration and validation activities perfromed on the first year of the SARAL/AltiKa mission. The main objective of the article is to assess the SARAL/AltiKa data quality and to estimate the altimeter system performance using GDR products. To achieve this goal, we present mono-mission metrics and compare them with Jason-2 over the same period. Even if these missions do not have the same ground track, precise comparisons are still possible. They allow assessing parameter discrepancies and SSH consistency between both missions in order to detect geographically correlated biases, jumps or drifts. These results show that SARAL/AltiKa data quality is excellent: ocean data coverage is greater than 99.5%, standard deviation at cross-overs is 5.4 cm. The mission therefore fulfills the requirements of high precision altimetry and can be used (in conjunction with Jason-2) to monitor the global mean sea level, ensuring the continuity of the record over ERS/Envisat historical ground track. Possible improvements and open issues are also identified, foreseeing an even better mission performance.     

How to Find Aquifer Statistics Utilizing Pumping Tests? Two Field Studies Using welltestpy

We present a workflow to estimate geostatistical aquifer parameters from pumping test data using the Python package welltestpy . The procedure of pumping test analysis is exemplified for two data sets from the Horkheimer Insel site and from the Lauswiesen site, Germany. The analysis is based on a semi-analytical drawdown solution from the upscaling approach Radial Coarse Graining, which enables to infer log-transmissivity variance and horizontal correlation length, beside mean transmissivity, and storativity, from pumping test data. We estimate these parameters of aquifer heterogeneity from type-curve analysis and determine their sensitivity. This procedure, implemented in welltestpy , is a template for analyzing any pumping test. It goes beyond the possibilities of standard methods, for example, based on Theis' equation, which are limited to mean transmissivity and storativity. A sensitivity study showed the impact of observation well positions on the parameter estimation quality. The insights of this study help to optimize future test setups for geostatistical aquifer analysis and provides guidance for investigating pumping tests with regard to aquifer statistics using the open-source software package welltestpy .     

Particle fluxes and recent sediment accumulation on the Aquitanian margin of Bay of Biscay

As a part of the ANR-Forclim experiment, particle mass fluxes and sedimentation processes were investigated on the slope of Aquitanian margin of the Bay of Biscay, between the canyons of Cap-Breton and Cap-Ferret. Interface sediments were collected along a depth transect from 145 to 2000 m; simultaneously a mooring line was deployed at the deepest station (WH, 2000 m) with two traps (800 and 1700 m) for a 16-month period (June 2006–November 2007). ²¹⁰Pb activities of settling particles and of interface sediments were determined to study transport processes of particles. Sediment and mass accumulation rates, calculated from excess ²¹⁰Pb profiles in the sediment column, show the expected decreasing trend with depth, as usually observed on margins. Mean particulate mass fluxes at 800 and 1700-m depth at site WH are, respectively, 27 and 70 g m^?2 a^?1.The ²¹⁰Pb budget points out events of temporary high lateral input of particles. The comparison of mass and ²¹⁰Pb fluxes between the water column and the seabed indicates that lateral transport plays an important role in particle accumulation on the Aquitanian margin. Regarding the objectives of the ANR-Forclim program, which aims to improve significantly the interpretation of fossil foraminifera signals, as a proxy for hydrological changes in the North Atlantic ocean, these results highlight advection processes must be considered when interpreting fluxes of foraminifers on the Aquitanian margin.     

The role of climate in the spread of modern humans into Europe

The spread of anatomically modern humans (AMH) into Europe occurred when shifts in the North Atlantic meridional overturning circulation triggered a series of large and abrupt climate changes during the last glacial. However, the role of climate forcing in this process has remained unclear. Here we present a last glacial record that provides insight into climate-related environmental shifts in the eastern Mediterranean region, i.e. the gateway for the colonisation of Europe by AMH. We show that the environmental impact of the Heinrich Event H5 climatic deterioration c. 48 kyr ago was as extreme as that of the glacial maximum of Marine Isotope Stage (MIS) 4 when most of Europe was deserted by Neanderthals. We argue that Heinrich H5 resulted in a similar demographic vacuum so that invasive AMH populations had the opportunity to spread into Europe and occupy large parts before the Neanderthals were able to reoccupy this territory. This spread followed the resumption of the Atlantic meridional overturning circulation at the beginning of Greenland Interstadial (GIS) 12 c. 47 kyr ago that triggered an extreme and rapid shift from desert-steppe to open woodland biomes in the gateway to Europe. We conclude that the extreme environmental impact of Heinrich H5 within a situation of competitive exclusion between two closely related hominids species shifted the balance in favour of modern humans.     

Does ratification matter and do major conventions improve safety and decrease pollution in shipping?

This article develops a method to measure the effect of the major international conventions in the area of safety, pollution, search and rescue and work related measures. It further distinguishes between the effect of entry into force and the status of ratification of a convention by its parties. Standard econometric models are used and the analysis is based on a unique dataset of 30 years of monthly data where the models also correct for other factors which can influence safety such as safety inspections and ship economic cycles. The results show a complex picture where the average time between adoption and entry into force was calculated to be 3.1 years. Overall, the more parties ratify a convention, the more likely safety is improved and pollution is decreased although one can detect a certain level of non-compliance. The immediate effect of entry into force presents a mixed picture where most negative effects can be found with legislation in the area of safety management and pollution, followed by technical areas. The effect of legislation in the areas related to working and living conditions and certification and training is smallest. Seasonality can be found with peaks in December and January for all conventions but are less important for pollution.     

Improving estuarine net flux estimates for dissolved cadmium export at the annual timescale: Application to the Gironde Estuary

Dissolved Cd (Cd_D) concentrations along the salinity gradient were measured in surface water of the Gironde Estuary during 15 cruises (2001–2007), covering a wide range of contrasting situations in terms of hydrology, turbidity and season. During all situations dissolved Cd concentrations displayed maximum values in the mid-salinity range, reflecting Cd addition by chloride-induced desorption and complexation. The daily net Cd_D fluxes from the Gironde Estuary to the coastal ocean were estimated using Boyle's method. Extrapolating Cd_D concentrations in the high salinity range to the freshwater end member using a theoretical dilution line produced 15 theoretical Cd concentrations (Cd_D⁰), each representative of one distinct situation. The obtained Cd_D⁰ concentrations were relatively similar (201 ± 28 ng L⁻¹) when freshwater discharge Q was >500 m³ s⁻¹ (508 ≤ Q ≤ 2600 m³ s⁻¹), but were highly variable (340 ± 80 ng L⁻¹; 247–490 ng L⁻¹) for low discharge situations (169 ≤ Q ≤ 368 m³ s⁻¹). The respective daily Cd_D net fluxes were 5–39 kg day⁻¹, mainly depending on freshwater discharge. As this observation invalidates the existing method of estimating annual Cd_D net fluxes, we proposed an empirical model, using representative Cd_D⁰ values and daily freshwater discharges for the 2001–2007 period. Subsequent integration produced reliable Cd_D net flux estimates for the Gironde Estuary at the annual timescale that ranged between 3.8–5.0 t a⁻¹ in 2005 and 6.0–7.2 t a⁻¹ in 2004, depending on freshwater discharge. Comparing Cd_D net fluxes with the incoming Cd_D fluxes suggested that the annual net Cd_D addition in the Gironde Estuary ranged from 3.5 to 6.7 t a⁻¹, without any clear temporal trend during the past seven years. The annual Cd_D net fluxes did not show a clearly decreasing trend in spite of an overall decrease by a factor 6 in Cd gross fluxes during the past decade. Furthermore, in six years out of seven (except 2003), the annual Cd_D net fluxes even exceeded river borne total (dissolved + particulate) gross Cd fluxes into the estuary. These observations were attributed to progressive Cd desorption from both suspended particles and bottom sediment during various sedimentation–resuspension cycles induced by tidal currents and/or continuous dredging (navigation channel) and diverse intra-estuarine sources (wet deposition, urban sources, and agriculture). Provided that gross fluxes remain stable over time, dissolved Cd exportation from the Gironde Estuary to the coastal ocean may remain at the present level for the coming decade and the estuarine sedimentary Cd stock is forecast to decrease slowly.     

Benthic geochemistry of manganese in the Bay of Biscay,and sediment mass accumulation rate

Manganese is a major redox reactive element of benthic metabolism. We have built a database of existing knowledge on the benthic geochemistry of Mn in the Bay of Biscay, in order to comprehensively assess the behaviour of Mn in a variety of environments during early diagenesis. The database contains vertical profiles of particulate and dissolved Mn species of 59 cores collected during 17 cruises between 1997 and 2006 at nine stations positioned between 140 and 4,800 m water depths. At all studied stations, Mn species follow the conventional distribution, where Mn(III,IV) species are enriched in the oxic layer, and dissolved Mn is present in the anoxic sediments. A minor part of Mn-oxides originates from sedimenting particles. The major part is of diagenetic origin, and derives from the oxidation of upward-diffusing dissolved Mn(II). Mn-oxide inventories are higher at the deeper stations than at the shallower ones. This difference cannot be attributed to different sources of sedimenting particles, but it must depend on sedimentation rate and diagenetic processes. At depth, dissolved Mn(II) concentrations are constant. This probably reflects equilibrium with an authigenic Mn(II) phase, which is the ultimate phase into which Mn is fossilized. The Mn content of deeper anoxic sediments is similarly low in all the cores studied, associated with corresponding trends of Mn content in sedimenting particles of the Bay of Biscay. Bioturbation, rather than redox oscillations, can convey Mn(III,IV) species downwards into the anoxic sediments where they are reduced, associated with a peak of dissolved Mn. Because dissolved Mn(II) is re-oxidized when it diffuses towards the oxic layer, the inventory of the diagenetic Mn(III,IV) phase remains at steady state, especially at stations where the oxic layer is thick. It then becomes possible to calculate the residence time of diagenetic Mn(III,IV) particles within the oxic layer, using the upward-directed flux of pore water Mn(II). By applying this residence time to the accumulation of sediments within the oxic layer, we obtain the sediment mass accumulation rate. The values calculated for the sediments of the Bay of Biscay fit well with accumulation rates obtained from radionuclides or sediment traps. The method has also been validated with data collected in other marine sedimentary environments. Electronic supplementary material  The online version of this article (doi:) contains supplementary material, which is available to authorized users.     

链状硅酸盐矿物中57Fe同质异能移和二级多普勒移

以德拜特性温度为可调参量,用德拜理论近似分析了某些链状硅酸盐矿物在不同温度、压力下的＾５７Ｆｅ中心移数据。二级多普勒移δＳＯＤ用德拜理论估计,并由δＣＳ的实验值与δＳＯＤ的估计值之差获得同质异能移δＩＳ。结果表明,对中心移的主要贡献来自同质异能移,在室温下,二级多勒移仅为中心移的１６％,室温下δＳＯＤ的压力系数比δＩＳ的小一个数量级以上,故压力改变时δＣＳ的变化主要是δＩＳ的变化引起的。反之,在常     

Temporal Trends in Apparent Oxygen Utilization in the Upper Pycnocline of the North Pacific: 1980–2000

We present a compilation of apparent oxygen utilization (AOU) changes observed in the upper pycnocline of the North Pacific Ocean over the last several decades. The goal here is to place previously-published data in a common format, and assess the causes of the observed changes. The general trend along repeat cross sections of the eastern and western subtropical ocean and the subarctic ocean is an increase in AOU from the mid 1980s to the mid 1990s. AOU has also been increasing in a time-series study in the northwest subarctic Ocean off of Japan since the late 1960s. Observed AOU changes south of 35°N in the subtropical ocean are 10–20 μmol kg⁻¹, with much greater changes, reaching 60–80 μmol kg⁻¹ in isolated areas, in the subtropical/subarctic boundary and the subarctic ocean. Analysis of changes in both AOU and salinity on isopycnals suggests that there are significant salinity-normalized increases that must be due to alteration in the rate of ventilation or organic matter degradation. A common feature in the data is that the maximum increase in AOU is centered near the density horizon σ_θ= 26.6. Time series results from the Oyashio Current region near the winter outcrop area of this density horizon indicate that surface waters there have become fresher with time, which may mean this density surface has ceased to outcrop in the latter decades of the 20th century. Whether this is due to natural decadal-scale changes or anthropogenic influences can be decided by determining future trends in AOU on these density surfaces. This revised version was published online in July 2006 with corrections to the Cover Date.