Th sorption and export models in the water column: A review

Over the past few decades, the radioisotope pair of ²³⁸U / ²³⁴Th has been widely and increasingly used to describe particle dynamics and particle export fluxes in a variety of aquatic systems. The present paper is one of five review articles dedicated to ²³⁴Th. It is focused on the models associated with ²³⁴Th whereas the companion papers (same issue) are focused on present and future methodologies and techniques (Rutgers van der Loeff et al.), C / ²³⁴Th ratios (Buesseler et al.), ²³⁴Th speciation (Santschi et al.) and present and future applications of ²³⁴Th [Waples, J.T., Benitez-Nelson, C.R., Savoye, N., Rutgers van der Loeff, M., Baskaran, M., Gustafsson, Ö., this issue. An Introduction to the application and future use of ²³⁴Th in aquatic systems. Marine Chemistry, FATE special issue]. In this paper, we review current ²³⁴Th scavenging models and discuss the relative importance of the non-steady state and physical terms associated with the most commonly used model to estimate ²³⁴Th flux. Based on this discussion we recommend that for future work the use of models should be accompanied by a discussion of the effect that model and data uncertainty have on the model results. We also suggest that future field work incorporate repeat occupations of sample sites on time scales of 1–4 weeks in order to evaluate steady state versus non-steady state estimates of ²³⁴Th export, especially during high flux events (> ca. 800 dpm m^− 2 d^− 1). Finally, knowledge of the physical oceanography of the study area is essential, particularly in ocean margins and in areas of established upwelling (e.g., Equatorial Pacific). These suggestions will greatly enhance the application of ²³⁴Th as a tracer of particle dynamics and flux in more complicated regimes.     

Palaeoecology and Archaeology of the Kärlich–Seeufer Open-Air Site (Middle Pleistocene) in the Central Rhineland, Germany

The Kärlich–Seeufer archaeological site in Germany's central Rhineland was excavated between 1980 and 1992. The site provides evidence for hominid activity during a Middle Pleistocene interglaciation known up to now only from the Kärlich clay pit and therefore defined as the Kärlich Interglaciation, which is considered to be post-Cromer IV and pre-Holstein (sensu stricto) in age. The site is characterized by Acheulean artifacts, a fauna dominated byElephas (Palaeoloxodon) antiquus,and a unique and outstanding preservation of wooden and other palaeobotanical remains. Assuming all finds are associated, the site previously was interpreted as an elephant hunting camp with a wooden structure, together with wood and bone implements preservedin situ.Recent analysis of the same features has shown that the site can also be interpreted as a reworked archaeological sample. Hominid occupation occurred in the vicinity of a small lake with prevailing meso-oligotrophic conditions. Expanding boreal forests and fen vegetation characterized the landscape.     

滇西保山地块金厂河矿集区铁铜金铅锌多金属矿床成矿系统

滇西保山地块是西南“三江”特提斯构造带的重要组成部分,其大地构造位置处于藏-滇-泰-马中间板块中段,是近年来科学研究和地质找矿的热点地区之一。受区域构造演化的影响,保山地块先后历经原、古、中、新特提斯演化,并发生了多期成岩成矿事件,在北部形成了以金厂河铁铜铅锌矿、核桃坪铅锌矿、陡崖铁铜多金属矿、黑牛凹金矿、黄家地金矿等为代表的金厂河铁铜金铅锌多金属矿集区。区内矿床在成矿空间上具有明显的分带性,单个矿床在垂向上、平面上均呈有规律地分布,其分带标志除了矿床类型外,还表现在有用矿物组合及元素分带。由下往上、由内向外均有Fe→Cu-Fe→Cu-Pb-Zn→Au矿种分带及“矽卡岩型→构造蚀变岩型→石英脉型”的矿床类型分带,成矿元素均从高温到中低温变化。成矿系统的分析表明,区内各代表性矿床中矿石的硫、铅同位素组成和变化范围较为一致性,矿床的形成具有相似的成矿流体,表明不同类型的矿化可能形成于早白垩世中特提斯洋的闭合过程。本文综合区内构造演化、典型矿床地质特征、各地质事件发生的先后关系,建立了金厂河矿集区铁铜金铅锌多金属矿床成矿模式,以期为该区深边部地质找矿提供科学依据。     

An Alternative Protocol for Single Zircon Dissolution with Application to (U‐Th‐Sm)/He Thermochronometry

Zircon (U‐Th‐Sm)/He (ZHe) thermochronometry is a powerful tool that has been widely used in geology to constrain the exhumation histories of orogens. In this study, we present an alternative protocol for dissolving zircon grains for determination of parent nuclides. This new alkali fusion procedure developed at the SARM (Service d'Analyse des Roches et des Minéraux) in Nancy, France, is fast (requiring only 2 d, including cleaning steps) and offers several advantages over conventional methods by avoiding: (i) use of HF pressure dissolution and (ii) complete removing of grains from the metal microvials. After dissolution, U, Th and Sm were measured using an ICP‐MS. We tested the new procedure on two different ZHe reference materials, the Fish Canyon Tuff and Buluk Tuff; these provided precision values for ZHe‐age estimations of 9 and 6% (1s), respectively. In addition, using this method, zircons from the Buluk Tuff are shown to be chemically more homogenous and more suitable for assessing the uncertainty of the entire integrated procedure.     

High resolution radio images of the symbiotic system R aquarii

We present MERLIN images of the symbiotic system R Aquarii obtained at 1.7 and 5 GHz. We identify the emission from the binary system and derive a mass loss rate for the Mira that is commensurate with that in typical Miras. We show that variations in the radio emission over the last decade are consistent with the jet model for the system originally presented by Solf (1992). In addition, we calculate the spectral index distribution and find that there is no evidence of non-thermal emission.     

Fluid variability in 2 GPa eclogites as an indicator of fluid behavior during subduction

Fluid activity ratios calculated between millimeter- to centimeter-scale layers in banded mafic eclogites from the Tauern Window, Austria, indicate that variations in a _{H 2 O} existed between layers during equilibration at P approximately equal to 2GPa and T approximately equal to 625°C, whereas a _{CO 2} was nearly constant between the same layers. Model calculations in the system H₂O–CO₂–NaCl show that these results are consistent with the existence of different saturated saline brines, carbonic fluids, or immiscible pairs of both in different layers. The data cannot be explained by the exisience of water-rich fluids in all layers. The model fluid compositions agree with fluid inclusion compositions from eclogite-stage veins and segregations that contain (1) saline brines (up to 39 equivalent wt. % NaCl) with up to six silicate, oxide, and carbonate daughter phases, and (2) carbonic fluids. The formation of crystalline segregations from fluid-filled pockets or hydrofractures indicates high fluid pressures at 2 GPa; the record of fluid variability in the banded eclogite host rocks, however, implies that fluid transport was limited to local flow along individual layers and that there was no large-scale mixing of fluids during devolatilization at depths of 60–70 km. The lack of evidence for fluid mixing may, in part, reflect variations in wetting behavior of fluids of different composition; nonwetting fluids (water-rich or carbonic) would be confined to intergranular pore spaces and would be essentially immobile, whereas wetting fluids (saline brines) could migrate more easily along an interconnected fluid network. The heterogeneous distribution of chemically distinct fluids may influence chemical transport processes during subduction by affecting mineral-fluid element partitioning and by altering the migration properties of the fluid phase(s) in the downgoing slab.     

Experimental study of the atmospheric marine boundary layer from in-situ aircraft measurements (TOSCANE-T Campaign): Variability of boundary conditions and eddy flux parameterization

The need for a thorough knowledge of boundary conditions over the vast oceanic surfaces makes remote sensing appear as the most suitable tool for future development. Remote sensing techniques require calibration data and consequently in-situ experiments to yield those data. Over the sea, aircraft seem to be the most convenient means of conducting validation experiments because they allow exploration of a large range of scales (from local measurements to measurements of pixel scale). This paper reports on some in-situ atmospheric aircraft measurements that were conducted as part of the TOSCANE-T experiment organized by the European Space Agency to calibrate the scatterometer for launch on ERS-1 in the early 1990's for global ocean wind measurement.The data analysed are the thermodynamic and turbulent variables measured by an instrumented aircraft, the Hurel Dubois, flying at a constant level of 50 m over the sea surface. Special attention was drawn to the variability of the boundary conditions within areas of 25 × 30 km. In fact, the two-dimensional fields of fluxes and thermodynamic parameters were inhomogeneous with some rather strong wind distortion.The eddy fluxes were parameterized with the aid of bulk aerodynamic formulations at a basic scale of 30 km samples, which corresponds to the aircraft flux computation legs. The bulk aerodynamic coefficients for momentum and heat were found to remain independent of windspeed (for wind velocities less than 12 m/s). Fluxes and thermodynamic parameters were also investigated at two other scales: the integration scale was either reduced to small areas of which size always remains larger than several characteristic lengths of turbulent transfer, or extended to a large area of 25 × 30km. The results of the bulk aerodynamic relationships appeared to be scale invariant, which would therefore justify the application of average values, within the range of scales under study.     

Alteration de la fonction de reproduction chez Idotea balthica basteri (Crustacea,Isopoda) soumis a l'effet chronique d'un détergent non ionique

Reproduction is greatly affected when the crustacean isopod Idotea balthica basteri is exposed to detergents, maturation being considerably delayed. Adults suffer a significant decrease in fecundity, either through females failing to produce eggs or miscarrying, and so producing fewer juveniles. This decrease of fecundity is accompanied by hormonal changes. Many juveniles from animals exposed to detergents are malformed.     

The Boreholes of the Sea Urchin Genus Echinometra (Echinodermata: Echinoidea: Echinometridae) as a Microhabitat in Tropical South America*

Abstract. Members of the genus Echinometru (Echinoideu: Echinometridue) inhabit hard substrata in shallow waters where they live in self-excavated dwellings. Boring by Echinometru spp. causes a secondary structure of the surface, thus forming additional microhabitats. In this study the effects of boring activities of Echinometru lucunter (L.) along the Caribbean coast of Colombia and of Echinometra vunbrunri A. Agassu in the Colombian Pacific is examined. Several species inhabit the boreholes occupied by these urchins. The associates live underneath the echinoid on the bottom of the borehole, where they find shelter from exposure and predators. The co-inhabitants of E. lucunter include the porcellanid Clusroroechus vunderhorsri (Schmitt ), the recently described brit-tlestar Ophiorhrix synoecim (Schoppe ), and the clingfish Acyrrus rubiginosus (Poey ). The species co-occumng with E. vunbrunti include the porcellanid crab Clusroroechus gorgonensis Werding amp; Haig and the clingfish Arcos decoris Briggs . With the exception of A. decoris, all of these species are obligatorily associated with the Echinomerra host.