SARAL/AltiKa Global Statistical Assessment and Cross-Calibration with Jason-2

The CNES/ISRO mission SARAL/AltiKa was successfully launched on 25 February 2013. It reached its nominal orbit on 13 March 2013. AltiKa is the first altimeter using the Ka-band frequency. This article presents the results of the calibration and validation activities perfromed on the first year of the SARAL/AltiKa mission. The main objective of the article is to assess the SARAL/AltiKa data quality and to estimate the altimeter system performance using GDR products. To achieve this goal, we present mono-mission metrics and compare them with Jason-2 over the same period. Even if these missions do not have the same ground track, precise comparisons are still possible. They allow assessing parameter discrepancies and SSH consistency between both missions in order to detect geographically correlated biases, jumps or drifts. These results show that SARAL/AltiKa data quality is excellent: ocean data coverage is greater than 99.5%, standard deviation at cross-overs is 5.4 cm. The mission therefore fulfills the requirements of high precision altimetry and can be used (in conjunction with Jason-2) to monitor the global mean sea level, ensuring the continuity of the record over ERS/Envisat historical ground track. Possible improvements and open issues are also identified, foreseeing an even better mission performance.     

Improving estuarine net flux estimates for dissolved cadmium export at the annual timescale: Application to the Gironde Estuary

Dissolved Cd (Cd_D) concentrations along the salinity gradient were measured in surface water of the Gironde Estuary during 15 cruises (2001–2007), covering a wide range of contrasting situations in terms of hydrology, turbidity and season. During all situations dissolved Cd concentrations displayed maximum values in the mid-salinity range, reflecting Cd addition by chloride-induced desorption and complexation. The daily net Cd_D fluxes from the Gironde Estuary to the coastal ocean were estimated using Boyle's method. Extrapolating Cd_D concentrations in the high salinity range to the freshwater end member using a theoretical dilution line produced 15 theoretical Cd concentrations (Cd_D⁰), each representative of one distinct situation. The obtained Cd_D⁰ concentrations were relatively similar (201 ± 28 ng L⁻¹) when freshwater discharge Q was >500 m³ s⁻¹ (508 ≤ Q ≤ 2600 m³ s⁻¹), but were highly variable (340 ± 80 ng L⁻¹; 247–490 ng L⁻¹) for low discharge situations (169 ≤ Q ≤ 368 m³ s⁻¹). The respective daily Cd_D net fluxes were 5–39 kg day⁻¹, mainly depending on freshwater discharge. As this observation invalidates the existing method of estimating annual Cd_D net fluxes, we proposed an empirical model, using representative Cd_D⁰ values and daily freshwater discharges for the 2001–2007 period. Subsequent integration produced reliable Cd_D net flux estimates for the Gironde Estuary at the annual timescale that ranged between 3.8–5.0 t a⁻¹ in 2005 and 6.0–7.2 t a⁻¹ in 2004, depending on freshwater discharge. Comparing Cd_D net fluxes with the incoming Cd_D fluxes suggested that the annual net Cd_D addition in the Gironde Estuary ranged from 3.5 to 6.7 t a⁻¹, without any clear temporal trend during the past seven years. The annual Cd_D net fluxes did not show a clearly decreasing trend in spite of an overall decrease by a factor 6 in Cd gross fluxes during the past decade. Furthermore, in six years out of seven (except 2003), the annual Cd_D net fluxes even exceeded river borne total (dissolved + particulate) gross Cd fluxes into the estuary. These observations were attributed to progressive Cd desorption from both suspended particles and bottom sediment during various sedimentation–resuspension cycles induced by tidal currents and/or continuous dredging (navigation channel) and diverse intra-estuarine sources (wet deposition, urban sources, and agriculture). Provided that gross fluxes remain stable over time, dissolved Cd exportation from the Gironde Estuary to the coastal ocean may remain at the present level for the coming decade and the estuarine sedimentary Cd stock is forecast to decrease slowly.     

Petroleum degradation and associated microbial signatures at the Chapopote asphalt volcano, Southern Gulf of Mexico

At the Chapopote Knoll in the Southern Gulf of Mexico, deposits of asphalt provide the substrate for a prolific cold seep ecosystem extensively colonized by chemosynthetic communities. This study investigates microbial life and associated biological processes within the asphalts and surrounding oil-impregnated sediments by analysis of intact polar membrane lipids (IPLs), petroleum hydrocarbons and stable carbon isotopic compositions (δ¹³C) of hydrocarbon gases. Asphalt samples are lightly to heavily biodegraded suggesting that petroleum-derived hydrocarbons serve as substrates for the chemosynthetic communities. Accordingly, detection of bacterial diester and diether phospholipids in asphalt samples containing finely dispersed gas hydrate suggests the presence of hydrocarbon-degrading bacteria. Biological methanogenesis contributes a substantial fraction to the methane captured as hydrate in the shallow asphalt deposits evidenced by significant depletion in ¹³C relative to background thermogenic methane. In sediments, petroleum migrating from the subsurface stimulates both methanogenesis and methanotrophy at a sulfate-methane transition zone 6-7 m below the seafloor. In this zone, microbial IPLs are dominated by archaeal phosphohydroxyarchaeols and archaeal diglycosidic diethers and tetraethers. Bacterial IPLs dominate surface sediments that are impregnated by severely biodegraded oil. In the sulfate-reduction zone, diagnostic IPLs indicate that sulfate-reducing bacteria (SRB) play an important role in petroleum degradation. A diverse mixture of phosphohydroxyarchaeols and mixed phospho- and diglycosidic archaeal tetraethers in shallow oil-impregnated sediments point to the presence of anaerobic methane-oxidizing ANME-2 and ANME-1 archaea, respectively, or methanogens. Archaeal IPLs increase in relative abundance with increasing sediment depth and decreasing sulfate concentrations, accompanied by a shift of archaeol-based to tetraether-based archaeal IPLs. The latter shift is suggested to be indicative of a community shift from ANME-2 and/or methanogenic archaea in shallower sediments to ANME-1/methanogenic archaea and possibly benthic archaea in deeper sediments.     

Human impact on Holocene sediment dynamics in the Eastern Mediterranean – the example of the Roman harbour of Ephesus

During the past millennia, many erosion and accumulation processes have been modified by anthropogenic impact. This holds especially true for the environs of ancient settlements and their harbours along the Mediterranean coasts. Our multi‐proxy investigations in the Roman harbour and the harbour canal of Ephesus (western Turkey) reveals that humans have significantly triggered soil erosion during the last three millennia. Since the eighth century bc , and especially since the Hellenistic period, a high sedimentation rate indicates fast alluviation and delta progradation of the Küçük Menderes. Deforestation, agriculture (especially ploughing) and grazing (especially goats) were the main reasons for erosion of the river catchment area. One consequence was significant siltation of the Hellenistic/Roman harbour basin. This sediment trap archives the human impact, which was strongly enhanced from Hellenistic/Roman to Byzantine times (second/first centuries bc to the sixth/seventh centuries ad ), evidenced by high sedimentation rates, raised values of heavy metal contaminations [lead (Pb), copper (Cu)], the occurrence of fruit tree pollen and of intestinal parasites. From the middle to the end of the first millennium ad , the influence of Ephesus declined, which resulted in a decrease of human impact. Studies of several ancient settlements around the Mediterranean Sea tell a comparable story. They also confirm that during their most flourishing periods the human impact totally overprinted the climatic one. To detect the latter, geo‐bio‐archives of relatively pristine areas have to be investigated in detail. Copyright © 2016 John Wiley & Sons, Ltd.     

The role of climate in the spread of modern humans into Europe

The spread of anatomically modern humans (AMH) into Europe occurred when shifts in the North Atlantic meridional overturning circulation triggered a series of large and abrupt climate changes during the last glacial. However, the role of climate forcing in this process has remained unclear. Here we present a last glacial record that provides insight into climate-related environmental shifts in the eastern Mediterranean region, i.e. the gateway for the colonisation of Europe by AMH. We show that the environmental impact of the Heinrich Event H5 climatic deterioration c. 48 kyr ago was as extreme as that of the glacial maximum of Marine Isotope Stage (MIS) 4 when most of Europe was deserted by Neanderthals. We argue that Heinrich H5 resulted in a similar demographic vacuum so that invasive AMH populations had the opportunity to spread into Europe and occupy large parts before the Neanderthals were able to reoccupy this territory. This spread followed the resumption of the Atlantic meridional overturning circulation at the beginning of Greenland Interstadial (GIS) 12 c. 47 kyr ago that triggered an extreme and rapid shift from desert-steppe to open woodland biomes in the gateway to Europe. We conclude that the extreme environmental impact of Heinrich H5 within a situation of competitive exclusion between two closely related hominids species shifted the balance in favour of modern humans.     

Future climate resources for tourism in Europe based on the daily Tourism Climatic Index

Climate is an important resource for many types of tourism. One of several metrics for the suitability of climate for sightseeing is Mieczkowski’s “Tourism Climatic Index” (TCI), which summarizes and combines seven climate variables. By means of the TCI, we analyse the present climate resources for tourism in Europe and projected changes under future climate change. We use daily data from five regional climate models and compare the reference period 1961–1990 to the A2 scenario in 2071–2100. A comparison of the TCI based on reanalysis data and model simulations for the reference period shows that current regional climate models capture the important climatic patterns. Currently, climate resources are best in Southern Europe and deteriorate with increasing latitude and altitude. With climate change the latitudinal band of favourable climate is projected to shift northward improving climate resources in Northern and Central Europe in most seasons. Southern Europe’s suitability for sightseeing tourism drops strikingly in the summer holiday months but is partially compensated by considerable improvements between October and April.     

Effect of Pumice and Sand on the Sustainability of Granular Iron Beds for the Aqueous Removal of CuII,NiII, and ZnII

Current knowledge of the basic principles underlying the design of Fe⁰ beds is weak. The volumetric expansive nature of iron corrosion was identified as the major factor determining the sustainability of Fe⁰ beds. This work attempts to systematically verify developed concepts. Pumice and sand were admixed to 200 g of Fe⁰ in column studies (50:50 volumetric proportion). Reference systems containing 100% of each material have been also investigated. The mean grain size of the used materials (in mm) were 0.28 (sand), 0.30 (pumice), and 0.50 (Fe⁰). The five studied systems were characterized (i) by the time dependent evolution of their hydraulic conductivity (permeability) and (ii) for their efficiency for aqueous removal of Cu^II, Ni^II, and Zn^II (about 0.3 mM of each). Results showed unequivocally that (i) quantitative contaminant removal was coupled to the presence of Fe⁰, (ii) additive admixture lengthened the service life of Fe⁰ beds, and (iii) pumice was the best admixing agent for sustaining permeability while the Fe⁰/sand column was the most efficient for contaminant removal. The evolution of the permeability was well‐fitted by the approach that the inflowing solution contained dissolved O₂. The achieved results are regarded as starting point for a systematic research to optimize/support Fe⁰ filter design.     

Species-dependent sensitivity to contaminants: an approach using primary hepatocyte cultures with three marine fish species

There is limited knowledge about the sensitivity of different fish species to environmental pollutants. Such information is pivotal in risk assessment and to understand why some species appear to be more tolerant to contaminants than others. The aim of the current study was to evaluate whether primary hepatocyte cultures of three marine fish species could be established in the field and whether their sensitivity to selected contaminants would differ. Primary hepatocyte cultures of three marine fish species (plaice, long rough dab, Atlantic cod) were established and exposed for 24 h to copper (20-2500 mg L?1) and statins (1-200 mg L?1). Endpoints were esterase activity, metabolic activity and reduced glutathione (GSH) content, all using fluorescent probes. Flatfish hepatocytes were more susceptible to copper and statin exposure than hepatocytes from cod. This study has shown that species-dependent differences in contaminant sensitivity can be investigated using primary hepatocyte cultures.     

Thermal maturity in the Central European Basin system (Schleswig-Holstein area): results of 1D basin modelling and new maturity maps

Thermal maturity information has been compiled for one of the deepest parts of the Central European Basin system, the Schleswig-Holstein area in northern Germany. New vitrinite reflectance data were obtained and old data were evaluated from a total of 31 wells. Furthermore, numerical 1D basin modelling was performed in order to interpolate/extrapolate vitrinite reflectance data to base Zechstein and base Keuper. For these two horizons, maturity maps were finally compiled revealing large differences in present-day thermal maturity within the basin. For example, vitrinite reflectance at base Zechstein ranges from greater than 4.5% in the Glueckstadt Graben to less than 1% in the northern part of the study area. Highest thermal maturity of base Keuper occurs in the West Holstein Trough and in the northern part of the Glueckstadt Graben. The timing of maturation is greatly affected by the complex tectonic evolution of the area. For six key wells distributed over the entire study area, burial and temperature histories as well as evolution of maturity were evaluated using 1D basin modelling. Deepest burial and maximum temperatures occurred either during Jurassic, Upper Cretaceous or Neogene times in these wells. Only some parts of the sedimentary package in Schleswig-Holstein show a significant increase in maturity during the Tertiary leading to additional hydrocarbon generation and entrapment.