Geochemical characteristics of waters in mineralised area of Peloritani Mountains (Sicily,Italy)

This paper presents the results of a study on the geochemistry of waters circulating in the mineralised area of the south-eastern sector of Mt. Peloritani (north-eastern Sicily, Italy), aimed at basic understanding of the geochemical processes influencing their chemical composition. Chemico-physical parameters and data on 26 major and minor chemical elements are reported for 103 water samples. Water chemistry is mainly dominated by dissolution of carbonates and hydrolysis of aluminosilicate minerals. Total dissolved salts (TDS) range from 80 to 1398 mg/L. All the waters exhibit E_H characteristic of an oxygenated environment. Excluding two samples, which show very high H⁺ activity (pH = 3.0 and 2.7), all the waters have pH values in the range 6.2–8.6. Cluster analysis based on major ion contents defined three main chemical water types, reflecting different hydrochemical processes. The first, group I, has low salinity (average TDS = 118 ± 30 mg/L) and abundance orders (meq/L) Na > Ca ≈ Mg > K and Cl ≈ HCO₃ > SO₄. With increased water–rock interaction, waters in groups II and III become more saline, changing composition towards SO₄–Cl-alkaline earth and HCO₃-alkaline earth types. Weathering of carbonate minerals causes waters to become saturated with respect to calcite and dolomite, whereas the incongruent dissolution of aluminosilicate minerals causes the solution to reach equilibrium with kaolinite and to form smectites. Trace element geochemistry in the analysed waters reflects interactions between waters and existing mineralisation, with elemental concentrations showing highly variable values, and higher concentrations of As, Pb, Sb and Zn near known mineralisation. Lead–Zn and As–Sb statistical associations, probably distinguishing interactions with different mineralogical phase paragenesis, were revealed by factor analysis. The main aqueous chemical forms of trace elements predicted by chemical speciation calculations are also reported. As most of the analysed spring waters provide the main source of freshwater for domestic purposes, attention should be given to As and Sb, whose concentrations exceed the recommended limits.     

Convective flows around sunspot-like objects

Results are given for calculations of convective flows around objects in the outer layers of the Sun that have similar characteristics to small sunspots. These objects are allowed to radiatively (diffusively) exchange heat with their surroundings, but convective motions and exchange are absent. This assumption is based on the simple presumption that a sunspot magnetic field maintains pressure equilibrium with the surrounding medium and prevents convective exchange with that medium.The flow structure around the object, and the question of the overall balance or redistribution of the emerging heat flux as suggested by earlier empirical models, are studied and discussed.After a period of adjustment, shortly after the sunspot-like object is placed into the domain, the layer readjusts itself so that most of the heat flux actually reappears at the surface, although some fraction of the flux is carried horizontally far from the object. There is no indication of long term storage of the heat flux that would normally appear in the place where the object resides. Finally, when the object is removed, the surrounding medium responds very quickly and soon returns to the undisturbed state before the object was in place.The present numerical treatment includes restrictions that may influence aspects of the heat redistribution, convective flows and time scales. In particular, the shape of the object and its size (somewhat smaller than a sunspot) are important, as is the number of spatial dimensions and the treatment of some boundary conditions. Since all of these issues require further investigation, some discussion is presented regarding the applicability of our results to real sunspots.     

Did multiple sediment-associated stressors contribute to the 1999 lobster mass mortality event in Western Long Island Sound, USA?

Near-bottom hypoxia during summer months has been a documented recurring phenomenon for decades in western Long Island Sound (WLIS); this temperate estuary has also supported, until 1999, a substantial American lobster (Homarus americanus) fishery. In response to a dramatic mass die-off of lobsters that began in WLIS in the late summer of 1999, a benthic habitat survey using a sediment-profile imaging (SPI) camera was conducted in October 1999. Follow-up surveys involving SPI and simultaneous measurements of dissolved oxygen (DO), hydrogen sulfide and ammonia within 10 cm of the bottom were conducted in August, September and November 2000. The SPI images revealed black sediments at or just below the sediment-water interface at a high proportion of stations in both 1999 and 2000, suggesting strongly reducing conditions and elevated levels of sulfides and other reduced end-products in sediment pore-water. Visual redox depths were relatively shallow (less than 2 cm) and spatially variable, and benthic communities appeared to be dominated by small, surface-dwelling opportunists. In August 2000, near-bottom DO concentrations < 2 mg I⁻¹ coincided with shallow redox depths at stations in the Western Narrows region. As DO levels increased from August to November 2000, visual redox depths remained shallow. Both sulfide and ammonia were detected in samples of bottom water taken within about 10 cm of the seafloor in all three 2000 surveys. The results suggest that anaerobic decomposition processes within the organic-rich sediments of WLIS strongly influence conditions at the sediment-water interface during late summer-early fall, the time of year that the lobster mortality event of 1999 began. Releases of reduced end-products (e.g., sulfide and ammonia) into overlying waters, combined with low DO levels and abnormally high water temperatures, represent multiple environmental stressors that may have physiologically weakened the lobsters and increased their susceptibility to deadly pathogens.     

A self-sufficient approach for GERB cloudy radiance detection

Geostationary Earth Radiation Budget (GERB) is the broadband radiometer onboard the Meteosat Second Generation (MSG) platform, launched at the end of August 2002 and still in commissioning phase. GERB data is planned to be used in many applications concerning Earth Radiation Budget (ERB) calculation. In order to evaluate the impact of clouds on ERB, a cloud detection is required and, at present, a cloud mask based on higher spatial and spectral resolution data acquired by Spinning Enhanced Visible and Infrared Imager (SEVIRI), the imager onboard the same MSG platform, is planned to be used in order to identify cloudy GERB soundings.As an alternative, a self-sufficient (only based on GERB data) method (OCA, the One-channel Cloudy-radiance-detection Approach) is proposed, as a time-saving and, probably, more suitable solution than the planned co-location approach.In this paper, preliminary results obtained by using several years of Meteosat data as well as GERB synthetic radiances (produced from Meteosat-7 observations) are presented. It is shown how results obtained by using GERB data alone can be comparable (and better in terms of number and spatial distribution of clear-sky GERB soundings identified) to the ones achieved if the co-location of a higher resolution cloud mask is used.     

A Simple Model for Spatially-averaged Wind Profiles Within and Above an Urban Canopy

This paper deals with the modelling of the flow in the urban canopy layer. It critically reviews a well-known formula for the spatially-averaged wind profile, originally proposed by Cionco in 1965, and provides a new interpretation for it. This opens up a number of new applications for modelling mean wind flow over the neighbourhood scale. The model is based on a balance equation between the obstacle drag force and the local shear stress as proposed by Cionco for a vegetative canopy. The buildings within the canopy are represented as a canopy element drag formulated in terms of morphological parameters such as λ _f and λ _p (the ratios of plan area and frontal area of buildings to the lot area). These parameters can be obtained from the analysis of urban digital elevation models. The shear stress is parameterised using a mixing length approach. Spatially-averaged velocity profiles for different values of building packing density corresponding to different flow regimes are obtained and analysed. The computed solutions are compared with published data from wind-tunnel and water-tunnel experiments over arrays of cubes. The model is used to estimate the spatially-averaged velocity profile within and above neighbourhood areas of real cities by using vertical profiles of λ _f .