水中氯代烃单体碳同位素分析中预富集方法进展

高精度准确测定氯代烃单体碳同位素对示踪污染物来源,了解污染物的生物降解过程具有重要意义。在环境转化过程中,有机污染物的同位素组成可能是稳定不变的,也有可能发生改变。若污染物的同位素组成在迁移转化过程中不变,根据其同位素组成可以示踪污染物的来源;若同位素组成变化,根据同位素分馏结果,可以评价环境中有机污染物降解发生的可能性和程度。本文综述了固相微萃取、静态顶空进样、吹扫-捕集、多级串联技术等前处理方法与气相色谱-燃烧-同位素比值质谱仪(GC-C-IRMS)联用分析水中氯代烃单体碳同位素的研究进展,比较了分析方法的优缺点。液-液萃取较少用于水中氯代烃的单体同位素分析。静态顶空进样、固相微萃取、吹扫-捕集都是无溶剂富集技术,与GC-C-IRMS联用分析水中氯代烃单体同位素过程中不存在或存在小且恒定的可校正的同位素分馏,分析精度一般优于1‰,没有二次污染,降低了杂质干扰,提高了GC-C-IRMS的分辨率和分析精度,降低了检测限。从静态顶空进样、固相微萃取、吹扫-捕集,到多级串联等技术与GC-C-IRMS联用分析水中氯代烃单体同位素比值,检测限逐渐降低。目前,吹扫-捕集-GC-C-IRMS在分析水中氯代烃中应用最广泛,重现性好、检测限低。针内微萃取、管内微萃取、搅动棒吸附萃取和顶空进样吸附萃取等前处理方法与GC-C-IRMS仪联用具有一定的应用前景。     

柴达木盆地西部地区咸化湖盆天然气地球化学特征及成因类型判识指标——以古近系—新近系为例

根据天然气地球化学基本理论,对柴达木盆地西部（柴西）地区天然气的地球化学特征进行分析。测试和收集该地区18个油气田及含油气构造的83个天然气样品,分析其组分和C同位素数据,结果显示,该区天然气以烃类气体为主,烃类含量介于79.24%~99.81%之间,天然气比重介于0.72~1.36之间,天然气干燥系数（C1/C2+）介于1.04~617.8之间,甲烷C同位素值介于-51.4‰~-24.2‰之间,乙烷C同位素值介于-34.2‰~-17.4‰之间。在此基础上,对该区不同构造带的天然气成因类型进行研究。研究结果表明,柴达木盆地西部地区天然气类型可划分为腐泥型气、腐殖型气、混合气3类,柴西北部天然气主要为腐泥型气和混合气,少量腐殖型气;柴西南部主要为腐泥型气,少量混合气。同时,建立了天然气成因类型的判识指标,对该区的天然气地球化学特征有了较为深入的认识,对今后的天然气勘探具有指导意义。     

2021年6月10日双柏MS5.1地震序列精定位及发震构造分析

1 地震背景 据中国地震台网( CENC)测定,2021年6月10日19时46分07秒,在云南省楚雄州双柏县发生MS5.1地震,震中(24.34°N,101.91°E),震源深度8 km.本次地震共造成楚雄州双柏县、玉溪市峨山县和易门县3个县5个乡镇不同程度受灾,2人受伤,直接经济总损失3440万元(引自云南省地震局关于双柏MS5.1地震灾害直接经济损失评估工作报告).     

A Metallogenic Model of Gold Deposits of the Jiaodong Granite-Greenstone Belt

An analysis of trace elements and isotopic geochemistry suggest that the ore-forming materials of gold deposits in the Jiaodong granite-greenstone belt have multiple sources, especially the mantle source. Seismic wave, magnetic and gravity fields show that the crust-mantle structure and its coupling mechanism are the fundamental dynamic causes for the exchange and accumulation of materials and energy in the metallogenic system. Considering the evolution history of the structural setting, the tectono-metallogenic dynamics model of the area can be summarized as follows: (1) occurrence of the greenstone belt during the Archean-Proterozoic-the embryonic form of Au-source system; (2) stable tectonic setting in the Paleozoic-an intermittence in gold mineralization; (3) intensive activation and reformation of the greenstone belt in the Mesozoic-tectono-mineralization and tectono-diagensis; (4) posthumous structural activity in the Cenozoic-destruction of orebodies in the later stage. In the middle and late Ind     

Uncertainty analysis of CO_2 flux components in subtropical evergreen coniferous plantation

We present an uncertainty analysis of ecological process parameters and CO2 flux components (Reco, NEE and gross ecosystem exchange (GEE)) derived from 3 years’ continuous eddy covariance meas-urements of CO2 fluxes at subtropical evergreen coniferous plantation, Qianyanzhou of ChinaFlux. Daily-differencing approach was used to analyze the random error of CO2 fluxes measurements and bootstrapping method was used to quantify the uncertainties of three CO2 flux components. In addition, we evaluated different ...     

Late Paleozoic Fluid Systems and Their Ore-forming Effects in the Yuebei Basin, Northern Guangdong, China

Based on detailed and systematic researches of the geology of ore deposits, fluid inclusions and isotope geochemistry etc., and regarding the Late Paleozoic fluid system of the Yuebei Basin as an integrated object in this paper, we have revealed the temporo-spatial evolution law of the basin＇s fluid system and discussed its ore-forming effects by simulating and analyzing the distribution of ore-forming elements, the fluid thermodynamics and dynamics of evolution processes of this basin. The results show that Late Paleozoic ore-forming fluid systems of the Yuebei Basin include four basic types as follows. （1） The sea floor volcanic-exhalation system developed during the rapid basin slip-extension stage in the Mid-Late Devonian, which affected the Dabaoshan region. It thus formed the Dabaoshan-type Cu-Pb-Zn-Fe sea floor volcanic-exhalation sedimentary deposits. （2） The compaction fluid system developed during the stable spreading and thermal subsidence-compression stage of the basin in the Mid-Late Devonian. The range of its effects extended all over the whole basin. It resulted in filling-metasomatic deposits, such as the Hongyan-type pyrite deposits and pyrite sheet within the Fankou-type Cu-Pb-Zn-S deposits. （3） The hot water circulation system of sea floor developed during the stage of basin uplifting and micro-aulacogen from the late Late Carboniferous to Middle Carboniferous. The range of its effects covered the Fankou region. It thus formed MVT deposits, such as the main orebody of the Fankou-type Pb-Zn-S deposits. （4） The gravity fluid system developed during the stage of fold uplifting and the basin closed from Middle Triassic to Jurassic, forming groundwater hydrothermal deposits, e.g. the veinlet Pb-Zn-calcite orebodies of the Fankou-type Pb-Zn- S deposits. Migration and concentration of the ore-forming fluids were constrained by the state of temporo-spatial distribution of its fluid potential. Growth faults not only converged the fluids and drove them to move upwards, but also the fluids often crossed the faults to the edges of the basin at the bottom of these faults and the lithologic interfaces, and even migrated to the basin＇s edges from top to bottom along the faults, which may be one of the basic reasons for the stratabound deposits to cluster mainly along the contemporaneous faults on the inner border of the basin. The superposed mineralization resulting from the multi-stage activity of contemporaneous faults and ore-forming fluid systems in the basin may be one of the key factors for forming superlarge ore deposits.     

赞比亚西北省索卢韦齐县铜钴多金属矿地质特征

赞比亚西北省索卢韦齐县铜钴多金属矿主要存在三种矿化类型,第一种是层控型铜矿,矿石矿物为黄铜矿、黝铜矿、辉铜矿,多呈条带状、透镜状等形态,平行黑云石英片岩和二云石英片岩的片理展布;第二种为沉积型铜矿,受到背斜和穹窿的控制,含矿岩系主要为加丹加超群(Katanga)下部罗安组(Roan)页岩、砂岩,金属矿物主要为水胆石、孔雀石、蓝铜矿,多呈星点状、浸染状、斑杂状、团块状等分布在含矿页岩、砂岩中;第三种是热液型铜矿,充填在加丹加超群及其更老的地层中,矿化类型为黄铜矿黄铁矿石英脉型,一般为小型脉状矿床。该类型矿床可与前两类矿床叠加,使矿石品位提高。     

西太平洋副热带高压对华北地区降水蒸发差的影响

采用小波相关和交叉小波变换等方法, 分析了西太平洋副热带高压脊线和北界位置变化对华北地区降水蒸发差的影响。结果表明, 2000年以来华北区南部的水资源短缺问题有所缓解, 但以北京为中心的华北区东北部仍处于持续缺水期; 华北地区降水蒸发差与副热带高压脊线及北界位置变化相关密切, 存在年际和年代际尺度的显著相关振荡, 与副热带高压脊线的年代际尺度相关凝聚性最强; 时域中年际尺度相关存在局部化特征, 年代际尺度相关具有阶段性。分析认为, 2000年以来副热带高压脊线和北界位置偏北并维持反气旋型环流, 有利于水汽向华北输送, 使得华北降水增多, 是近年来华北中南部降水蒸发差增大的主要原因; 而东亚季风减弱不利于西南气流的水汽输送, 以及蒙古高原显著增暖导致蒸发增大等因素, 使得华北东北部仍处于持续缺水期。     

Vertical Observations and Analysis of PM2.5, O3, and NOx at Beijing and Tianjin from Towers during Summer and Autumn 2006

During the period between 18 August and 22 September 2006, an ultraviolet photometric O3 analyzer, a NO-NO2-NOx chemiluminescence analyzer, and a quartz micro-oscillating-scale particle concentration analyzer were simultaneously used for monitoring at three different heights each at Beijing (325-m tower) and Tianjin (255-m tower). These towers belong to the Institute of Atmospheric Physics (IAP) of the Chinese Academy of Sciences (CAS) and to the Tianjin Municipal Meteorological Bureau, respectively. These measurements were used to continuously measure the atmospheric O3 and NOx volume-by-volume concentrations and the PM2.5 mass concentration within a vertical gradient. When combined with meteorological data and information on the variation of vertical characteristics of the various atmospheric pollutants in the two cities, analysis shows that these two cities were seriously polluted by both PM2.5 and O3 during summer and autumn. The highest daily-average concentrations of PM2.5 near the ground in Beijing and Tianjin reached 183 μg m-3 and 165 μg m-3, respectively, while the O3 concentrations reached 52 ppb and 77 ppb, and NOx concentrations reached 48 ppb and 62 ppb for these two cities, respectively. The variations in the daily-average concentrations of PM2.5 between Beijing and Tianjin were demonstrated to be consistent over time. The concentrations of PM2.5 measured in Beijing were found to be higher than those in Tianjin. However, the overall O3 concentrations near the ground in Tianjin were higher than in Beijing. NOx concentrations in Tianjin were consistently lower than in Beijing. It was also found that PM2.5 pollution in Beijings atmosphere may also be affected by the pollutants originating in and delivered from Tianjin, and that Ti