This is a first foray into the historical start and early years of chemometrics from about 1972 onwards.We have gathered interviews with three originators(Kowalski,Wold and Massart)as well as with aselected group of six other well-known chemometricians who gradually became active in the 1970s(Christie,Clementi,Hopke,Martens,Brown and Deming).The interviews include amongst a host ofsubjective recollections a succinct record of the key historical literature as highlighted by the interviewees'own rankings of‘earliest’and‘best’.A discussion of the most general commonalities in these interviews together with other historicalmaterial is presented in the second part of the paper. 相似文献
For the calibration of chromatographic systems,different methods can be used.One class of methodsutilizes three-way approaches.The calibration problem is stated in such a way that the decompositionof a three-way array can serve for the prediction of retention on new stationary phases.Two three-way approaches are presented:the Unfold-PCA and PARAFAC models.The theory ofboth methods is presented and the differences are highlighted,the main difference being that PARAFACis a trilinear decomposition whereas Unfold-PCA is not.Both three-way methods are evaluated on asmall data set consisting of retention measurements of eight solutes at six mobile phase compositions onsix stationary phases.The differences in performance of the two models are minor,For calibration purposes,two variants of the methods are discussed:three-way PLS and an extensionof PARAFAC.Again the theory and differences between the two methods are explained.The predictiveperformance of the two methods is compared using the same data set as earlier.The differences inpredictive performance,however,are minor.Both methods are capable of predicting 98% of thevariation in the test sets.Yet,there are other considerations when comparing methods than predictiveperformance,e.g.the quality of the predictions. 相似文献
In this study, we examine the lunar mare dome Mee 1 situated near the craters Mee H and Drebbel F in a region showing evidence of ancient (pre-Orientale) mare volcanism and cryptomare deposits. Regional stratigraphic relations indicate that Mee 1 was formed prior to the Orientale impact at the beginning of the Imbrian period. Based on a combined photoclinometry and shape from shading technique applied to telescopic CCD images of the dome acquired under oblique illumination, we determined a diameter of Mee 1 of 25 km, a height of 250 m, a flank slope of 1.15°, and a volume of . Based on rheologic modelling of the dome and a viscoelastic model of the feeder dike, we obtained a magma viscosity of , an effusion rate of , a duration of the effusion process of 1.6 years, a magma rise speed of , a width of the feeder dike of 32 m, and a horizontal dike length of 144 km. A comparison of Mee 1 with domes with similar morphometric properties, which are located near Milichius and inside the crater Petavius, reveals strong similarities with respect to the viscosity of the dome-forming magma and the feeder dike geometry, while the effusion rate and magma rise speed of Mee 1 are somewhat higher. The pronounced morphometric differences between Mee 1 and a smaller dome situated close to the crater Doppelmayer and characterised by a similar magma viscosity suggest that the growth of that dome was limited by exhaustion of the magma reservoir, while Mee 1 and the other larger domes display morphometric properties presumably coming closer to the cooling limit. The comparison of the ancient dome Mee 1 with the younger (Eratosthenian) edifices near Milichius and Doppelmayer suggests that the conditions in the upper mantle and the crust favoured high eruption volumes, effusion rates, and magma rise speeds, implying the occurrence of large magma reservoirs preventing the limitation of dome growth by magma exhaustion. On the other hand, we observe similar general morphometric, rheologic, and feeder dike characteristics and, thus, conclude that the formation conditions of lunar mare domes did not change fundamentally during the Imbrian period. 相似文献
This study examines a set of lunar domes with very low flank slopes which differ in several respects from the frequently occurring lunar effusive domes. Some of these domes are exceptionally large, and most of them are associated with faults or linear rilles of presumably tensional origin. Accordingly, they might be interpreted as surface manifestations of laccolithic intrusions formed by flexure-induced vertical uplift of the lunar crust (or, alternatively, as low effusive edifices due to lava mantling of highland terrain, or kipukas, or structural features). All of them are situated near the borders of mare regions or in regions characterised by extensive effusive volcanic activity. Clementine multispectral UVVIS imagery indicates that they do not preferentially occur in specific types of mare basalt. Our determination of their morphometric properties, involving a combined photoclinometry and shape from shading technique applied to telescopic CCD images acquired at oblique illumination, reveals large dome diameters between 10 and more than 30 km, flank slopes below 0.9°, and volumes ranging from 0.5 to 50 km3. We establish three morphometric classes. The first class, In1, comprises large domes with diameters above 25 km and flank slopes of 0.2°-0.6°, class In2 is made up by smaller and slightly steeper domes with diameters of 10-15 km and flank slopes between 0.4° and 0.9°, and domes of class In3 have diameters of 13-20 km and flank slopes below 0.3°. While the morphometric properties of several candidate intrusive domes overlap with those of some classes of effusive domes, we show that a possible distinction criterion are the characteristic elongated outlines of the candidate intrusive domes. We examine how they differ from typical effusive domes of classes 5 and 6 defined by Head and Gifford [Head, J.W., Gifford, A., 1980. Lunar mare domes: classification and modes of origin. Moon Planets 22, 235-257], and show that they are likely no highland kipukas due to the absence of spectral contrast to their surrounding. These considerations serve as a motivation for an analysis of the candidate intrusive domes in terms of the laccolith model by Kerr and Pollard [Kerr, A.D., Pollard, D.D., 1998. Toward more realistic formulations for the analysis of laccoliths. J. Struct. Geol. 20(12), 1783-1793], to estimate the geophysical parameters, especially the intrusion depth and the magma pressure, which would result from the observed morphometric properties. Accordingly, domes of class In1 are characterised by intrusion depths of 2.3-3.5 km and magma pressures between 18 and 29 MPa. For the smaller and steeper domes of class In2 the magma intruded to shallow depths between 0.4 and 1.0 km while the inferred magma pressures range from 3 to 8 MPa. Class In3 domes are similar to those of class In1 with intrusion depths of 1.8-2.7 km and magma pressures of 15-23 MPa. As an extraordinary feature, we describe in some detail the concentric crater Archytas G associated with the intrusive dome Ar1 and discuss possible modes of origin. In comparison to the candidate intrusive domes, terrestrial laccoliths tend to be smaller, but it remains unclear if this observation is merely a selection effect due to the limited resolution of our telescopic CCD images. An elongated outline is common to many terrestrial laccoliths and the putative lunar laccoliths, while the thickness values measured for terrestrial laccoliths are typically higher than those inferred for lunar laccoliths, but the typical intrusion depths are comparable. 相似文献
The Swedish Deep Drilling Program (SDDP) has been initiated to study fundamental problems of the dynamic Earth system, its natural history and evolution. Many key scientific questions can be addressed through in situ investigations only, requiring deep continental drilling. Some are unique to Scandinavia, most are of international interest and significance. At present, five core projects ( Fig. 1 ) with international teams are integrating scientific problems with societal and industrial applications. If SDDP succeeds to attract the funding required, Sweden will have a number of world‐class boreholes at key locations by 2020. Figure 1 Open in figure viewer PowerPoint Locations of SDDP drilling project proposals. PFDP—Postglacial Fault Drilling Project; PaMVAS—Palaeoproterozoic mineralized volcanic arc systems: the Skellefte District; COSC—Collisional Orogeny in the Scandinavian Caledonides; DRL—The Dellen Impact Crater, a geoscientific deep rock laboratory; SELHO—Svecofennian accretion, an example of the early structural evolution in a large hot orogen; CISP—Concentric Impact Structures in the Palaeozoic: the Lockne and Siljan craters. Background and inset image from Blue Marble Next Generation data set (NASA Earth Observatory, http://earthobservatory.nasa.gov/Features/BlueMarble/ ). 相似文献