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711.
Although carbonate-associated sulfate (CAS) is used widely as a proxy for the sulfur isotope composition of ancient seawater, little is known about the effects of diagenesis on retention of primary δ34S signals. Our case study of the Key Largo Limestone, Pleistocene, Florida, is the first systematic assessment of the impact of meteoric diagenesis on CAS properties. Geochemical and petrographic data show that meteoric diagenesis has affected the exposed coralline facies to varying degrees, yielding differences now expressed as sharp reaction fronts between primary and secondary carbonate minerals within individual coral heads. Specifically, analyses across high-resolution transects in the Key Largo Limestone show that concentrations of strontium and sodium decrease across the recrystallization front from original aragonite to meteoric low-magnesium calcite by factors of roughly 5 and 10, respectively. Predictably, δ18O values decrease across these same fronts. The δ13C relationships are more complex, with the most depleted values observed in the latest-formed calcite. Such trends likely reflect carbon isotope buffering capacity that decreased as reaction progressed, as well as protracted development of soil profiles and the associated terrestrial biomass and thus depleted δ13C during sea-level lowstand. Conversely, δ34S values of CAS vary within a narrow ‘buffered’ range from 20.6 to 22.6‰ (compared to 20.8-22.0‰ of coeval Pleistocene seawater) across the same mineralogical transition, despite sulfate concentrations that drop in the diagenetic calcite by an average factor of 12. Collectively, these data point to robust preservation of primary δ34S for carbonates that have experienced intense meteoric diagenesis, which is encouraging news for those using the isotopic composition of CAS as a paleoceanographic proxy. At the same time, the vulnerability of CAS concentrations to diagenetic resetting is clear. 相似文献
712.
Jennifer J. Follstad Shah Ryan Bares Brenda B. Bowen Gabriel J. Bowen David R. Bowling David P. Eiriksson Benjamin Fasoli Richard P. Fiorella Anna Gannet Hallar Sarah J. Hinners John D. Horel Alexander A. Jacques Logan R. Jamison John C. Lin Daniel L. Mendoza Logan E. Mitchell Diane E. Pataki Sarah McKenzie Skiles Rose M. Smith Margaret A. Wolf Paul D. Brooks 《水文研究》2021,35(9):e14352
The 2085 km2 Jordan River Basin, and its seven sub-catchments draining the Central Wasatch Range immediately east of Salt Lake City, UT, are home to an array of hydrologic, atmospheric, climatic and chemical research infrastructure that collectively forms the Wasatch Environmental Observatory (WEO). WEO is geographically nested within a wildland to urban land-use gradient and built upon a strong foundation of over a century of discharge and climate records. A 2200 m gradient in elevation results in variable precipitation, temperature and vegetation patterns. Soil and subsurface structure reflect systematic variation in geology from granitic, intrusive to mixed sedimentary clastic across headwater catchments, all draining to the alluvial or colluvial sediments of the former Lake Bonneville. Winter snowfall and spring snowmelt control annual hydroclimate, rapid population growth dominates geographic change in lower elevations and urban gas and particle emissions contribute to episodes of severe air pollution in this closed-basin. Long-term hydroclimate observations across this diverse landscape provide the foundation for an expanding network of infrastructure in both montane and urban landscapes. Current infrastructure supports both basic and applied research in atmospheric chemistry, biogeochemistry, climate, ecology, hydrology, meteorology, resource management and urban redesign that is augmented through strong partnerships with cooperating agencies. These features allow WEO to serve as a unique natural laboratory for addressing research questions facing seasonally snow-covered, semi-arid regions in a rapidly changing world and an excellent facility for providing student education and research training. 相似文献
713.
Benjamin Brigaud Simon Andrieu Thomas Blaise Frdric Haurine Jocelyn Barbarand 《Sedimentology》2021,68(1):168-195
Hardground discontinuities within carbonate platforms form important stratigraphic surfaces which can be used at basin scale to correlate sequence boundaries. Although these surfaces are commonly used in sequence strati‐graphy, the timing and duration of hardground lithification and the crystallization of early cements remain unexplored. Here, early calcite cements were dated by U‐Pb geochronology for five Jurassic hardgrounds, interpreted as third‐order sequence boundaries, situated within a well‐constrained petrographic, sedimentological and stratigraphic framework. The consistency or the slight deviation between the age of the cements and the stratigraphic age of deposition of the formations illustrate that cementation occurred early in the diagenetic history. The ages obtained on dogtooth cements, replacing aragonite in gastropod shells and pendant cements in intergranular spaces, match those of the standard Jurassic biostratigraphic ammonite Zones, making calcite U‐Pb geochronology a promising method for dating third‐order sequence boundaries of depositional sequences and refining the Jurassic time scale in the future. 相似文献
714.
Vicky Chelangat Cheruiyot Daniel Gebregiorgis Benjamin Opiyo Lawrence Morara Kiage 《第四纪科学杂志》2020,35(6):737-742
Fungi are highly sensitive to environmental and climatic changes. Palaeoecological reconstructions utilising tropical African fungal spores, however, are rare and patchy. Here, we show that fossil fungal spores preserved in core KAP-01 from the Cherangani Hills in Kenya tracks critical environmental changes in the African tropics since the Last Glacial Maximum (LGM), largely synchronous with observations in the pollen record from the same site. Consistent with the pollen record, the presence of fungal taxa in the record, albeit meagre, during the LGM point to an intermittent wetter Cherangani that allowed for the presence of the observed taxa and the prevalence of cool, dry conditions during the last deglaciation. The elevated fungal spore activity during the Late Holocene is evidence for warm, moist environmental conditions and broadly consistent with the pollen record. These different fungal spore taxa, which can be employed to track distinct environmental conditions and processes, provide a dimension that can be overlooked if the reconstruction of the palaeoenvironment were to rely solely on pollen. Thus the fungal spore record enables us to affirm the interpretation of the prevalence of warm, moist conditions evident from such as the Holocene pollen record. 相似文献
715.
Guilhem Amin Douillet Benjamin Bernard Mlanie Bouysson Quentin Chaffaut Donald Bruce Dingwell Lukas Gegg Inga Hoelscher Ulrich Kueppers Clia Mato Vanille Ariane Ritz Fritz Schlunegger Patrick Witting 《Sedimentology》2019,66(5):1531-1559
Pyroclastic currents are catastrophic flows of gas and particles triggered by explosive volcanic eruptions. For much of their dynamics, they behave as particulate density currents and share similarities with turbidity currents. Pyroclastic currents occasionally deposit dune bedforms with peculiar lamination patterns, from what is thought to represent the dilute low concentration and fluid‐turbulence supported end member of the pyroclastic currents. This article presents a high resolution dataset of sediment plates (lacquer peels) with several closely spaced lateral profiles representing sections through single pyroclastic bedforms from the August 2006 eruption of Tungurahua (Ecuador). Most of the sedimentary features contain backset bedding and preferential stoss‐face deposition. From the ripple scale (a few centimetres) to the largest dune bedform scale (several metres in length), similar patterns of erosive‐based backset beds are evidenced. Recurrent trains of sub‐vertical truncations on the stoss side of structures reshape and steepen the bedforms. In contrast, sporadic coarse‐grained lenses and lensoidal layers flatten bedforms by filling troughs. The coarsest (clasts up to 10 cm), least sorted and massive structures still exhibit lineation patterns that follow the general backset bedding trend. The stratal architecture exhibits strong lateral variations within tens of centimetres, with very local truncations both in flow‐perpendicular and flow‐parallel directions. This study infers that the sedimentary patterns of bedforms result from four formation mechanisms: (i) differential draping; (ii) slope‐influenced saltation; (iii) truncative bursts; and (iv) granular‐based events. Whereas most of the literature makes a straightforward link between backset bedding and Froude‐supercritical flows, this interpretation is reconsidered here. Indeed, features that would be diagnostic of subcritical dunes, antidunes and ‘chute and pools’ can be found on the same horizon and in a single bedform, only laterally separated by short distances (tens of centimetres). These data stress the influence of the pulsating and highly turbulent nature of the currents and the possible role of coherent flow structures such as Görtler vortices. Backset bedding is interpreted here as a consequence of a very high sedimentation environment of weak and waning currents that interact with the pre‐existing morphology. Quantification of near‐bed flow velocities is made via comparison with wind tunnel experiments. It is estimated that shear velocities of ca 0·30 m.s?1 (equivalent to pure wind velocity of 6 to 8 m.s?1 at 10 cm above the bed) could emplace the constructive bedsets, whereas the truncative phases would result from bursts with impacting wind velocities of at least 30 to 40 m.s?1. 相似文献
716.
Gary Kocurek Rowan C. Martindale Mackenzie Day Timothy A. Goudge Charles Kerans Hima J. Hassenruck‐Gudipati Jasmine Mason Benjamin T. Cardenas Eric I. Petersen David Mohrig Daniel S. Aylward Cory M. Hughes Caroline M. Nazworth 《Sedimentology》2019,66(3):808-837
The Middle Jurassic Todilto Member of the Wanakah Formation is a carbonate and gypsum unit inset into the underlying aeolian Entrada Sandstone in the San Juan Basin. Field and thin section study of the uppermost Entrada and Todilto at Ghost Ranch, New Mexico, identified Todilto facies and their relationship to remnant Entrada dune topography. Results support the previous interpretation that the Entrada dunes, housed in a basin below sea level, were rapidly flooded by marine waters. Mass wasting of the dunes gave rise to sediment‐gravity flows that largely buried remnant dune topography, leaving ca 12 m of relief that defined the antecedent condition for Todilto deposition. Previously interpreted as seasonal varves deposited in a stratified water body, the Todilto is reinterpreted as a microbial biolaminite. Most diagnostic are organic‐rich laminae with structures characteristic of filamentous microbes and containing trapped aeolian silt, and clotted‐texture laminae with a fabric associated with calcification of extracellular polymeric substances. The spatial arrangement of Todilto facies is controlled by the dune palaeotopography. A continuous basal laminated mudstone thickens over the dune crest, reflecting the optimum conditions for microbial mat development, and is interpreted to have been deposited when marine waters submerged the topography. Subsequent drying caused emergence of the crestal area, and formation of tepee structures and a dissolution breccia. Gypsiferous mudflats and periodic ponds occupied the dune flanks and interdune area, with gypsum concentrated within the interdune area. Entrada sands remained unstable during Todilto deposition with common injection structures into the Todilto, and a remnant slope caused the downslope movement and folding of Todilto strata on the upper lee face. Although some expansion of the gypsum occurred in the subsurface, facies architecture fostered development of a dissolution front adjacent to the interdune gypsum body with section collapse of gypsiferous limestone on the dune flanks. 相似文献
717.
Benjamin R. Fosu Prosenjit Ghosh David M. Chew Shrinivas G. Viladkar 《Geological Journal》2019,54(6):3438-3454
The Amba Dongar carbonatite‐alkaline complex is regarded as a late phase intrusion (ca. 65 Ma) associated with Deccan volcanism. Existing age constraints on the Amba Dongar carbonatite are based on phlogopite 40Ar–39Ar plateau ages derived from carbonatite and associated alkaline rocks within the complex. We explore the utility of apatite, a common accessory mineral in Amba Dongar carbonatites, as a petrogenetic and geochronological tool to constrain further the evolution of the carbonatites. Apatite exhibits different crystal forms—from hexagonal stubby prisms to ovoid and elongate grains. Apatite occurs as cumulate and disseminated grains that are either primary, fractured, or recrystallized. SrO content is high in primary apatite (3.17 wt%) but less in recrystallized (1.90 wt%) and disseminated grains (0.47 wt%). MnO and Cl are negligible while FeO is typically low in all samples. SiO2 content is low except for a few primary grains which measure up to 1.35 wt%, correlating with high REE content. LREEs dominate the total REE budget of Amba Dongar apatite, with HREEs below EPMA detection limit in most samples. Total REE content is generally low, though some primary apatite contains up to 3.19 wt% REEs. We also report U Pb apatite ages from the carbonatites analysed in situ by LA‐ICP‐MS. The data from all samples combined on a U Pb Tera–Wasserburg concordia yield a lower intercept age of 65.4 ± 2.5 Ma (MSWD = 2.8, 207Pb/206Pbi = 0.8272 ± 0.0028), and the Amba Dongar carbonatites are thus interpreted to represent a phase of coeval magmatic activity with Deccan volcanism. 相似文献
718.
Jose Luis Carballo Humberto Ovalle‐Beltrán Benjamin Yáñez Eric Bautista‐Guerrero Héctor Nava‐Bravo 《Marine Ecology》2017,38(1)
Sponges are one of the principal agents of bioerosion and sediment production in coral reefs. They generate small carbonate chips that can be found in the sediments, and we investigated whether these could provide a means for assessment of bioerosion applicable to reef monitoring. We tested this hypothesis on samples from 12 Mexican coral reefs distributed along the Pacific coast, where boring sponges were particularly abundant, and quantified the amount of chips in samples of superficial sediment in three grain‐size fractions: fine (<44 μm), medium (44–210 μm) and coarse (>210 μm). The grain‐size distribution varied among reefs, with the majority of the sediment of most reefs being composed of coarse sands, and the medium and fine fractions dominating only at La Entrega and Playa Blanca. All the reefs presented clear evidence of bioerosion by sponges, with the characteristic chips present in the sediment, although at most sites the percentage of chips was very low (from 1% to 3% of the total sediment). Only at La Entrega and Playa Blanca did they constitute a significant fraction of the total sediment (18% and 16%, respectively). While not statistically significant, there was an interesting trend between sponge chips versus sponge abundance that suggests that quantification of the chips in the sediment could be used as a proxy for sponge erosion of the entire community, which cannot be estimated in by laboratory experiments. However, while this methodology could provide an integrated approach to monitor sponge bioerosion, more studies are necessary due to the influence of environmental factors on the transport and deposition of these chips. 相似文献
719.
Josefine Lenz Sebastian Wetterich Benjamin M. Jones Hanno Meyer Anatoly Bobrov Guido Grosse 《Boreas: An International Journal of Quaternary Research》2016,45(4):584-603
Permafrost degradation influences the morphology, biogeochemical cycling and hydrology of Arctic landscapes over a range of time scales. To reconstruct temporal patterns of early to late Holocene permafrost and thermokarst dynamics, site‐specific palaeo‐records are needed. Here we present a multi‐proxy study of a 350‐cm‐long permafrost core from a drained lake basin on the northern Seward Peninsula, Alaska, revealing Lateglacial to Holocene thermokarst lake dynamics in a central location of Beringia. Use of radiocarbon dating, micropalaeontology (ostracods and testaceans), sedimentology (grain‐size analyses, magnetic susceptibility, tephra analyses), geochemistry (total nitrogen and carbon, total organic carbon, δ13Corg) and stable water isotopes (δ18O, δD, d excess) of ground ice allowed the reconstruction of several distinct thermokarst lake phases. These include a pre‐lacustrine environment at the base of the core characterized by the Devil Mountain Maar tephra (22 800±280 cal. a BP, Unit A), which has vertically subsided in places due to subsequent development of a deep thermokarst lake that initiated around 11 800 cal. a BP (Unit B). At about 9000 cal. a BP this lake transitioned from a stable depositional environment to a very dynamic lake system (Unit C) characterized by fluctuating lake levels, potentially intermediate wetland development, and expansion and erosion of shore deposits. Complete drainage of this lake occurred at 1060 cal. a BP, including post‐drainage sediment freezing from the top down to 154 cm and gradual accumulation of terrestrial peat (Unit D), as well as uniform upward talik refreezing. This core‐based reconstruction of multiple thermokarst lake generations since 11 800 cal. a BP improves our understanding of the temporal scales of thermokarst lake development from initiation to drainage, demonstrates complex landscape evolution in the ice‐rich permafrost regions of Central Beringia during the Lateglacial and Holocene, and enhances our understanding of biogeochemical cycles in thermokarst‐affected regions of the Arctic. 相似文献
720.
Armine Avagyan Benjamin R. K. Runkle Nina Hennings Hannes Haupt Tarmo Virtanen Lars Kutzbach 《水文研究》2016,30(11):1727-1741
Boreal mire landscapes are rich in soil carbon and significantly contribute to the carbon input of aquatic ecosystems. They are composed of different mesoscale ecohydrological subunits, whose individual contributions to the water and carbon export of mire catchments are not well understood. The spring snowmelt period is the major hydrological event in the annual water cycle of the boreal regions and strongly influences the carbon flux between the terrestrial and aquatic systems. The aim of this study was (1) to provide a conceptual understanding of the spatial and temporal dynamics of the surface water chemistry along a swamp forest‐fen‐bog gradient during the snowmelt period, (2) to quantify the exported dissolved organic carbon (DOC) content in the runoff and (3) to identify the ecohydrological landscape unit that contributes most to DOC export during the snowmelt period in a heterogeneous mire complex in Northwest Russia. The highest DOC concentrations were detected in the swamp forest, and the lowest concentrations were observed at the treeless bog by the end of the snowmelt period (swamp forest: 37–43 mg l?1, bog: 13–17 mg l?1). During the spring snowmelt period, a significant amount (~1.7 g C m?2) of DOC was transferred by the ~74 mm of runoff from the catchment into the river. Variability in the thawing periods led to differences in the relative contributions of each ecohydrological zone to the carbon export measured at a stream channel draining the studied part of the mire complex. An increased understanding of the variation in DOC concentrations and contributions from the mesoscale ecohydrological subunits to carbon export can help to predict the potential regional loss of DOC based on land cover type under climate change. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献